Catalytic microwave pyrolysis of waste engine oil using metallic pyrolysis char

Microwave pyrolysis was performed on waste engine oil pre-mixed with different amounts of metallic-char catalyst produced previously from a similar microwave pyrolysis process. The metallic-char catalyst was first prepared by pretreatment with calcination followed by analyses to determine its various properties. The heating characteristics of the mixture of waste oil and metallic-char during the pyrolysis were investigated, and the catalytic influence of the metallic-char on the yield and characteristics of the pyrolysis products are discussed with emphasis on the composition of oil and gaseous products. The metallic-char, detected to have a porous structure and high surface area (124 m2/g), showed high thermal stability in a N2 atmosphere and it was also found to have phases of metals and metal oxides attached or adsorbed onto the char, representing a potentially suitable catalyst to be used in pyrolysis cracking process. The metallic-char initially acted as an adsorptive-support to adsorb metals, metal oxides and waste oil. Then, the char became a microwave absorbent that absorbed microwave energy and heated up to a high temperature in a short time and it was found to generate arcing and sparks during microwave pyrolysis of the waste oil, resulting in the formation of hot spots (high temperature sites with temperature up to 650 °C) within the reactor under the influence of microwave heating. The presence of this high temperature metallic-char, the amounts of which are likely to increase when increasing amounts of metallic-char were added to the waste oil (5, 10, and 20 wt% of the amount of waste oil added to the reactor), had provided a reducing chemical environment in which the metallic-char acted as an intermediate reductant to reduce the adsorbed metals or metal oxides into metallic states, which then functioned as a catalyst to provide more reaction sites that enhanced the cracking and heterogeneous reactions that occurred during the pyrolysis to convert the waste oil to produce higher yields of light hydrocarbons, H2 and CO gases in the pyrolysis products, recording a yield of up to 74 wt% of light C5–C10 hydrocarbons and 42 vol% of H2 and CO gases. The catalytic microwave pyrolysis produced 65–85 wt% yield of pyrolysis-oil containing C5–C20 hydrocarbons that can potentially be upgraded to produce transport-grade fuels. In addition, the recovered pyrolysis-gases (up to 33 wt%) were dominated by aliphatic hydrocarbons (up to 78 vol% of C1–C6 hydrocarbons) and significant amounts of valuable syngas (up to 42 vol% of H2 and CO in total) with low heating values (LHV) ranging from 4.7 to 5.5 MJ/m3, indicating that the pyrolysis-gases could also be used as a gaseous fuel or upgraded to produce more hydrogen as a second-generation fuel. The results indicate that the metallic-char shows advantages for use as a catalyst in microwave pyrolysis treatment of problematic waste oils. [Graphical abstract - see article]The authors acknowledges the financial support by the Ministry of Science, Technology, and Innovation Malaysia (MOSTI), Ministry of Higher Education Malaysia (MOHE), and University Malaysia Terengganu for the conduct of the research under the E-Science fund (UMT/RMC/SF/13/52072(5), Vot No: 52072), the Fundamental Research Grant Scheme (Project No: FRGS/1/2013/TK05/UMT/02/2, Vot No: 59296), and the Research Acculturation Grant Scheme (Project No: RAGS/2012/UMT/TK07/3, Vot No: 57085).This is the author accepted manuscript. The final version is available from [publisher] via http://dx.doi.org/10.1016/j.apcatb.2015.04.01

Polynomials, Riemann surfaces, and reconstructing missing-energy events

We consider the problem of reconstructing energies, momenta, and masses in collider events with missing energy, along with the complications introduced by combinatorial ambiguities and measurement errors. Typically, one reconstructs more than one value and we show how the wrong values may be correlated with the right ones. The problem has a natural formulation in terms of the theory of Riemann surfaces. We discuss examples including top quark decays in the Standard Model (relevant for top quark mass measurements and tests of spin correlation), cascade decays in models of new physics containing dark matter candidates, decays of third-generation leptoquarks in composite models of electroweak symmetry breaking, and Higgs boson decay into two tau leptons.Comment: 28 pages, 6 figures; version accepted for publication, with discussion of Higgs to tau tau deca

Factors associated with crisis pregnancies in Ireland: Findings from three nationally representative sexual health surveys

Background: Findings on the demographic and sexual health characteristics associated with the experience of a crisis pregnancy is important to inform the public health policy of a country, including Ireland. Findings from other jurisdictions have suggested that certain demographic groups are at risk for unintended pregnancies and the disparity between the groups have been growing in recent years. Ireland is a country which experienced much economic and societal change in the first decade of the 21st century, changes which are likely to have affected demographic variables pertaining to sexual health. The current study had two aims: to investigate changes in the socioeconomic characteristics associated with crisis pregnancies over a seven year period [2003 to 2010], and to investigate the recent [2010] socioeconomic risk factors associated with crisis pregnancies in Ireland. Methods: The study compared the results from 18-45 year old women using data from three broadly similar nationally representative Irish sexual health surveys carried out in 2003, 2004-2006 and 2010. Chi square analysis compared of the socioeconomic characteristics across the seven year period and found that a higher proportion of women with two or more children and women for whom religion was not important reported a crisis pregnancy in 2010 compared with earlier years. A logistic regression then investigated the sexual health history and socioeconomic factors associated with the experience of a recent crisis pregnancy using the most recent 2010 data. Results: Receipt of sex education and contraception use at first sex significantly predicted the experiencing of a recent crisis pregnancy. Younger women and those with a lower level of education were more likely to report having experienced a recent crisis pregnancy. Conclusion: Similar demographic groups are at risk for experiencing a crisis pregnancy in Ireland compared with international research, yet the disparities between demographic groups who have experienced a crisis pregnancy appear to be decreasing rather than increasing over a seven year period. Recommendations are made with regard to the provision of continued sex education throughout the lifespan, particularly for those women who are at an increased risk of experiencing a crisis pregnancy

On the Numerical Evaluation of Loop Integrals With Mellin-Barnes Representations

An improved method is presented for the numerical evaluation of multi-loop integrals in dimensional regularization. The technique is based on Mellin-Barnes representations, which have been used earlier to develop algorithms for the extraction of ultraviolet and infrared divergencies. The coefficients of these singularities and the non-singular part can be integrated numerically. However, the numerical integration often does not converge for diagrams with massive propagators and physical branch cuts. In this work, several steps are proposed which substantially improve the behavior of the numerical integrals. The efficacy of the method is demonstrated by calculating several two-loop examples, some of which have not been known before.Comment: 13 pp. LaTe

Paradoxical roles of antioxidant enzymes:Basic mechanisms and health implications

Reactive oxygen species (ROS) and reactive nitrogen species (RNS) are generated from aerobic metabolism, as a result of accidental electron leakage as well as regulated enzymatic processes. Because ROS/RNS can induce oxidative injury and act in redox signaling, enzymes metabolizing them will inherently promote either health or disease, depending on the physiological context. It is thus misleading to consider conventionally called antioxidant enzymes to be largely, if not exclusively, health protective. Because such a notion is nonetheless common, we herein attempt to rationalize why this simplistic view should be avoided. First we give an updated summary of physiological phenotypes triggered in mouse models of overexpression or knockout of major antioxidant enzymes. Subsequently, we focus on a series of striking cases that demonstrate “paradoxical” outcomes, i.e., increased fitness upon deletion of antioxidant enzymes or disease triggered by their overexpression. We elaborate mechanisms by which these phenotypes are mediated via chemical, biological, and metabolic interactions of the antioxidant enzymes with their substrates, downstream events, and cellular context. Furthermore, we propose that novel treatments of antioxidant enzyme-related human diseases may be enabled by deliberate targeting of dual roles of the pertaining enzymes. We also discuss the potential of “antioxidant” nutrients and phytochemicals, via regulating the expression or function of antioxidant enzymes, in preventing, treating, or aggravating chronic diseases. We conclude that “paradoxical” roles of antioxidant enzymes in physiology, health, and disease derive from sophisticated molecular mechanisms of redox biology and metabolic homeostasis. Simply viewing antioxidant enzymes as always being beneficial is not only conceptually misleading but also clinically hazardous if such notions underpin medical treatment protocols based on modulation of redox pathways

Logarithmic Corrections to Extremal Black Hole Entropy from Quantum Entropy Function

We evaluate the one loop determinant of matter multiplet fields of N=4 supergravity in the near horizon geometry of quarter BPS black holes, and use it to calculate logarithmic corrections to the entropy of these black holes using the quantum entropy function formalism. We show that even though individual fields give non-vanishing logarithmic contribution to the entropy, the net contribution from all the fields in the matter multiplet vanishes. Thus logarithmic corrections to the entropy of quarter BPS black holes, if present, must be independent of the number of matter multiplet fields in the theory. This is consistent with the microscopic results. During our analysis we also determine the complete spectrum of small fluctuations of matter multiplet fields in the near horizon geometry.Comment: LaTeX file, 52 pages; v2: minor corrections, references adde

Slepton pair production in the POWHEG BOX

We present an implementation for slepton pair production at hadron colliders in the POWHEG BOX, a framework for combining next-to-leading order QCD calculations with parton-shower Monte-Carlo programs. Our code provides a SUSY Les Houches Accord interface for setting the supersymmetric input parameters. Decays of the sleptons and parton-shower effects are simulated with PYTHIA. Focussing on a representative point in the supersymmetric parameter space we show results for kinematic distributions that can be observed experimentally. While next-to-leading order QCD corrections are sizable for all distributions, the parton shower affects the color-neutral particles only marginally. Pronounced parton-shower effects are found for jet distributions.Comment: 10 pages, 4 figure

Initial psychological responses to influenza A, H1N1 ("Swine flu")

Background The outbreak of the pandemic flu, Influenza A H1N1 (Swine Flu) in early 2009, provided a major challenge to health services around the world. Previous pandemics have led to stockpiling of goods, the victimisation of particular population groups, and the cancellation of travel and the boycotting of particular foods (e.g. pork). We examined initial behavioural and attitudinal responses towards Influenza A, H1N1 ("Swine flu") in the six days following the WHO pandemic alert level 5, and regional differences in these responses. Methods 328 respondents completed a cross-sectional Internet or paper-based questionnaire study in Malaysia (N = 180) or Europe (N = 148). Measures assessed changes in transport usage, purchase of preparatory goods for a pandemic, perceived risk groups, indicators of anxiety, assessed estimated mortality rates for seasonal flu, effectiveness of seasonal flu vaccination, and changes in pork consumption Results 26% of the respondents were 'very concerned' about being a flu victim (42% Malaysians, 5% Europeans, p < .001). 36% reported reduced public transport use (48% Malaysia, 22% Europe, p < .001), 39% flight cancellations (56% Malaysia, 17% Europe, p < .001). 8% had purchased preparatory materials (e.g. face masks: 8% Malaysia, 7% Europe), 41% Malaysia (15% Europe) intended to do so (p < .001). 63% of Europeans, 19% of Malaysians had discussed the pandemic with friends (p < .001). Groups seen as at 'high risk' of infection included the immune compromised (mentioned by 87% respondents), pig farmers (70%), elderly (57%), prostitutes/highly sexually active (53%), and the homeless (53%). In data collected only in Europe, 64% greatly underestimated the mortality rates of seasonal flu, 26% believed seasonal flu vaccination gave protection against swine flu. 7% had reduced/stopped eating pork. 3% had purchased anti-viral drugs for use at home, while 32% intended to do so if the pandemic worsened. Conclusion Initial responses to Influenza A show large regional differences in anxiety, with Malaysians more anxious and more likely to reduce travel and to buy masks and food. Discussions with family and friends may reinforce existing anxiety levels. Particular groups (homosexuals, prostitutes, the homeless) are perceived as at greater risk, potentially leading to increased prejudice during a pandemic. Europeans underestimated mortality of seasonal flu, and require more information about the protection given by seasonal flu inoculation

Structural analysis of MDM2 RING separates degradation from regulation of p53 transcription activity

MDM2–MDMX complexes bind the p53 tumor-suppressor protein, inhibiting p53's transcriptional activity and targeting p53 for proteasomal degradation. Inhibitors that disrupt binding between p53 and MDM2 efficiently activate a p53 response, but their use in the treatment of cancers that retain wild-type p53 may be limited by on-target toxicities due to p53 activation in normal tissue. Guided by a novel crystal structure of the MDM2–MDMX–E2(UbcH5B)–ubiquitin complex, we designed MDM2 mutants that prevent E2–ubiquitin binding without altering the RING-domain structure. These mutants lack MDM2's E3 activity but retain the ability to limit p53′s transcriptional activity and allow cell proliferation. Cells expressing these mutants respond more quickly to cellular stress than cells expressing wild-type MDM2, but basal p53 control is maintained. Targeting the MDM2 E3-ligase activity could therefore widen the therapeutic window of p53 activation in tumors