Impact of the physico-chemistry of the wine on membrane filtration performance

During the process of wine making, operation of cross-flow microfiltration allows a one-step clarification and sterilization of wine, with lower waste compared to the conventional processes of clarification and sterilization. Indeed, these processes are sources of voluminous waste (earth, Kieselguhr, additives), when discharges are becoming more and more restricted by environmental and health rules. Nevertheless, cross-flow microfiltration of wine presents a major drawback: membrane fouling causes a significant decrease in the flow rates, due to excessive retention of some wine components which could lead ultimately to the alteration of the quality of wine. The aim of this work was to study the impact of some specific wine components (phenolic compounds and yeast extract), as well as some physico-chemical parameters (pH) in regard to membrane fouling. Studies were performed using one red wine and synthetic wines, using cellulose acetate membranes (0.2 μm) operated in the dead-end mode under 2 bar pressure. The simultaneous presence of the both species of phenolic compounds (anthocyanins and tannins) in the synthetic wine was shown to be the main cause of fouling, whereas the presence of one specie leads only to standard blocking type behavior. An important decrease in the flow rates was also observed when yeast extract was added to the liquid. This yeast extract was shown to contain 300 mg/g of proteins and to be free of mannoproteins. The influence of these proteins on fouling was demonstrated while pre-treating the synthetic wine with bentonite, which was able to adsorb proteins, and in this case, no fouling was observed. It was also shown that, when decreasing the pH, the flow rate was enhanced. For all experiments, a fouling index or cake specific resistance, according to the type of fouling, was calculated in order to be used as a reference to estimate the filterability of a given wine, according to its composition in some targeted molecules. Finally, the experiments of the actual red wine exhibited complete rapid fouling of the membrane, probably due to the presence of high concentration of phenolic compounds

Comederos

El alimento sólido es un ingrediente básico en la producción de leche, de ahí que dediquemos un capítulo al diseño y al manejo de la zona de alimentación. El comedero debe permitir una distribución adecuada de la ración, proporcionar espacio suficiente a las vacas para que éstas puedan consumir la cantidad que necesitan, estar limpio y libre de residuos de comidas anteriores y ser fácil de limpiar. La ingestión de alimentos se ve afectada por una serie de factores ambientales y de manejo. Sobre los primeros (clima y entorno) no se puede actuar o resulta caro y difícil, pero sobre las segundas (diseño y dimensionamiento adecuado, espacio disponible, etc.) sí podemos influir. De esta forma, un comedero correctamente diseñado da lugar a un acercamiento del animal más frecuente, más duradero y a una mayor ingestión. Asimismo, evitará numerosas lesiones debidas a una presión excesiva de las vacas sobre él. También nos referiremos a su mantenimiento y limpieza, para lo que es esencial una buena elección de materiales

Analysis of membrane fouling during cross-flow microfiltration of wine

The aim of this study was to investigate the individual impact on wine molecules as tannins, pectins and mannoproteins on multichannel ceramic membrane fouling during wine cross-flow microfiltration. The characterization of fouling mechanisms involved in the previous filtrations was realized by using the classical fouling models and the analysis of the total resistance curves. It was shown that the obtained initial fluxes are dependant of the nature of the studied molecules and their concentration. According to their increasing effect on permeate flux decline, the studied wine components could be ranked as: mannoproteins < tannins < pectins. During the filtration of wine added with tannins, it was found that the filtrations were governed by the cake layer formation mechanism. The presence of pectins caused the formation of gel-type layer which is found to be compressible under high pressures. For wines added with mannoprotein filtrations, it was shown that there is a threshold concentration above which a plateau value of permeate flux is obtained. Industrial relevance: The cross-flow microfiltration applied to wine filtration has become a legitimate alternative to conventional filtration processes. However, membrane fouling which affects the operating costs and the plant maintenance, limits the widespread application of this technique. To avoid or reduce membrane fouling, it is extremely important to identify the fouling elements and the mechanisms that govern the process. A better understanding of the mechanisms whereby fouling is formed during wine microfiltration may lead to be in position to control fouling or reduce it, to improve cleaning procedures and to adapt the process to the product to be filtered. The results presented in this paper concern the investigation and the understanding of fouling mechanisms by wine colloids (tannins, pectins and mannoproteins). We found that wine colloids had a strong impact on membrane fouling. Independently of their concentrations found in wine, they can be ranked according to their increasing effect on permeate flux as: mannoproteins b tannins b pectins. Such result provides important information and a better vision on the methods which can be used to limit membrane fouling for example the use of pectinolytic enzymes before filtration in order to hydrolyze pectin chains or precipitation of unstable tannins by finning the wine with bentonite. By elucidating fouling mechanisms such as cake layer and gel type layer, we can adapt the hydrodynamic process to control membrane fouling

Cross-flow microfiltration applied to oenology: A review

The cross-flow microfiltration applied to wine filtration has become a legitimate alternative to conventional filtration processes. However, membrane fouling which affects the operating costs and the plant maintenance, limits the widespread application of this technique. The aim of this review is to provide a better understanding of the development of the cross-flow microfiltration in wine industry, as well as the complexity of wine composition and its consequences on membrane fouling. This review covers also the impact of the operating conditions and the membrane characteristics on fouling mechanisms. Strategies to limit fouling as well as the latest innovations and commercial proposal are discussed in this paper

Wireless Channel Modeling For Networks On Chips

The advent of integrated circuit (chip) multiprocessors (CMPs) combined with the continuous reduction in device physical size (technology scaling) to the sub-nanometer regime will result in an exponential increase in the number of processing cores that can be integrated within a single chip. Today’s CMPs already support tens to low hundreds of cores and both industry and academic roadmaps project that future chips will have thousands of cores. Therefore, while there are open questions on how to harness the computing power offered by CMPs, the design of power-efficient and compact on-chip interconnection networks that connects cores, caches and memory controllers has become imperative for sustaining the performance of CMPs. As the limited scalability of bus-based networks degrades performance by reducing data rates and increasing latency, the Network-on-Chip (NoC) design paradigm has gained momentum, where a network of routers and links connects all the cores. However, power consumption of NoCs is a significant challenge that should be addressed to capitalize on the scaling advantages of multicores. Also, improvements in metal wire characteristics will no longer satisfy the power and performance requirements of on-chip communication. One approach to continue the performance improvements is to integrate new emerging technologies into the electronic design flow such as wireless/RF technologies, since they provide unique advantages that make them desirable in a NoC environment. First, wireless technologies are ubiquitous and offer a wide range of options in communication, and there exists a vast body of knowledge for the design and implementation of wireless chipsets using RF-CMOS technology. Second, wireless communication, unlike wired transmission, can be omnidirectional, which can facilitate one-hop unicast, multicast, and broadcast communication that can result in a reduction in power consumption while allowing for faster communication. Third, wireless communication can increase the communication data rate by the combination of Frequency Division Multiplexing (FDM) and Time Division Multiplexing (TDM) (and in the future, potentially spatial division multiplexing (SDM)). Therefore, Wireless NoC (WiNoC) interconnects have recently emerged as a viable solution to mitigate power concerns in the short to medium term while still providing competitive performance metrics, i.e., low power consumption, tens of Gbps data rates, and minimal circuit area (or volume) within the chip. Worth noting is that wireless links are not envisioned as replacing all wired links, but rather as augmenting the wired interconnection network. In this dissertation, we employ simulations in HFSS from Ansys® to present accurate wireless channel models for a realistic WiNoC environment. We investigate the performance of these models with different types of narrowband and wideband antennas. This entails estimation of the scattering parameters for the channels between multiple antenna elements in the WiNoC, from which we derive channel transfer functions and channel impulse responses. Using these results, we can estimate the throughput of the various WiNoC links, and this allows us to design effective multiple access (MA) schemes via FDM and TDM. For these MA schemes, we provide estimates of maximal throughput. To further the feasibility study, we investigate the performance of a simple binary transmission scheme--On-Off Keying (OOK)--through the resulting dispersive channels, which can facilitate one-hop unicast, multicast, and broadcast communication that can result in a reduction in power consumption while allowing for faster communication. Our investigation of the performance of On-Off Keying modulation (OOK) also includes an analytical expression for bit error ratio (BER) that can be evaluated numerically. This enables us to provide the equalization requirements needed to achieve our target BERs. Finally, we provide recommendations for WiNoC design and future tasks related to this research

Epistemological shifts in knowledge and education in Islam: A new perspective on the emergence of radicalization amongst Muslims

I theorize that the idea of knowledge and education has shifted in Islam from an inclusive and rational search for all knowledge to a narrowed focus on religious knowledge, void of rationality. By synthesizing literature on education and knowledge in Islam, this study identifies three shifts in the cultural history of Islamic education. I argue that those shifts in what was deemed valuable knowledge have played a significant role in the emergence of radicalization today. The study shows that once the social world of Islam destabilized, the sense of belonging and sense making became inward and less reflexive as compared to that of early Muslims. Belief became privileged over the rationality mechanisms that had previously formed Islamic endeavors. I demonstrate that a decline in intellectual and scientific production followed, allowing extremists to skew Islam’s narrative by putting forward an idealized version of the Islamic caliphate divorced from rationality

The scientific basis of climate-smart agriculture: A systematic review protocol

Background: ‘Climate-smart agriculture’ (CSA)—agriculture and food systems that sustainably increase food production, improve resilience (or adaptive capacity) of farming systems, and mitigate climate change when possible—has quickly been integrated into the global development agenda. However, the empirical evidence base for CSA has not been assembled, complicating the transition from CSA concept to concrete actions, and contributing to ideological disagreement among development practitioners. Thus, there is an urgent need to evaluate current knowledge on the effectiveness of CSA to achieve its intended benefits and inform discourse on food, agriculture, and climate change. This systematic review intends to establish the scientific evidence base of CSA practices to inform the next steps in development of agricultural programming and policy. We will evaluate the impact of 73 promising farm-level management practices across five categories (agronomy, agroforestry, livestock, postharvest management, and energy systems) to assess their contributions to the three CSA pillars: (1) agronomic and economic productivity, (2) resilience and adaptive capacity, and (3) climate change mitigation in the developing world. The resulting data will be compiled into a searchable Web-based database and analytical engine that can be used to assess the relative effectiveness and strength of evidence for CSA, as well as identify best-fit practices for specific farming and development contexts. This represents the largest meta-analysis of agricultural practices to date. Methods/Design: This protocol sets out the approach for investigating the question: How do farm-level CSA management practices and technologies affect food production and/or farmers’ incomes, resilience/adaptive capacity, and climate change mitigation in farming systems of developing countries? The objective of this ongoing systematic review is to provide a first appraisal of the evidence for CSA practices in order to inform subsequent programming. The review is based on data found in English-language peer-reviewed journals with searches using terms relevant to CSA practices and CSA outcomes. Searches were conducted via Web of Science (WoS) and Scopus. Articles located were screened first by abstract and then full text according to predefined eligibility criteria for inclusion in the review. Data capturing the context of the study (e.g., geographic location, environmental context), management practices, and impacts (e.g., indicators of CSA outcomes) will be compiled from those studies that meet the predetermined criteria. Statistical relationships between practices and impacts will be evaluated via meta-analytical approaches including response ratios and effect sizes. Mechanisms to identify bias and maintain consistency continue to be applied throughout the review process. These analyses will be complemented with an analysis of determinants of/barriers to adoption of promising CSA practices covered in the meta-analysis. Results of the review will be incorporated into a publicly available Web-based database. Data will be publicly available under Creative Commons License in 2016

Microfiltration tangentielle appliquée à l'oenologie : compréhension et maîtrise des phénomènes de colmatage

La clarification des vins par procédés membranaires en particulier la microfiltration tangentielle a toujours été limitée par le colmatage, générant des flux de perméation faibles incompatibles avec la rentabilité économique. La compréhension, la maîtrise, ainsi que l'anticipation des phénomènes de colmatage font l'objet de ce travail. Dans un premier temps, la contribution individuelle puis en mélange des composés du vin (tannins, pectines, mannoprotéines et levures) au colmatage d'une membrane céramique multicanaux a été évaluée. Une approche fondamentale a permis de proposer des mécanismes de colmatage : la présence des pectines induit les flux de perméation les plus faibles en formant un gel à la surface de la membrane tandis que les levures semblent au contraire avoir un effet protecteur dans le cas d'un vin brut. Parce qu'il représente le flux au-delà duquel un colmatage irréversible apparaît à la surface de la membrane, le flux critique pour l'irréversibilité est un paramètre clef pour contrôler le colmatage. Dans le cas de la filtration de vin, aucun flux critique n'a pu être déterminé ce qui a conduit à définir un critère identifiant une zone de travail où le degré de colmatage reste acceptable. La dernière partie de cette thèse est consacrée à l'étude de la filtration dynamique (RVF) pour une éventuelle application dans le secteur vinicole. Cette technique est testée en présence de deux membranes organiques différentes: PES (hydrophile) et PTFE (hydrophobe). Les observations ont permis de mettre en évidence l'efficacité du système contre le colmatage des membranes PES induite par l'action de l'agitateur. Le colmatage des membranes PTFE est énormément affecté par les interactions molécules/membrane rendant la filtration dynamique inefficace pour lutter contre le colmatage de ces membranes

Microfiltration tangentielle appliquée à l'oenologie : compréhension et maîtrise des phénomènes de colmatage

La clarification des vins par procédés membranaires en particulier la microfiltration tangentielle a toujours été limitée par le colmatage, générant des flux de perméation faibles incompatibles avec la rentabilité économique. La compréhension, la maîtrise, ainsi que l'anticipation des phénomènes de colmatage font l'objet de ce travail. Dans un premier temps, la contribution individuelle puis en mélange des composés du vin (tannins, pectines, mannoprotéines et levures) au colmatage d'une membrane céramique multicanaux a été évaluée. Une approche fondamentale a permis de proposer des mécanismes de colmatage : la présence des pectines induit les flux de perméation les plus faibles en formant un gel à la surface de la membrane tandis que les levures semblent au contraire avoir un effet protecteur dans le cas d'un vin brut. Parce qu'il représente le flux au-delà duquel un colmatage irréversible apparaît à la surface de la membrane, le flux critique pour l'irréversibilité est un paramètre clef pour contrôler le colmatage. Dans le cas de la filtration de vin, aucun flux critique n'a pu être déterminé ce qui a conduit à définir un critère identifiant une zone de travail où le degré de colmatage reste acceptable. La dernière partie de cette thèse est consacrée à l'étude de la filtration dynamique (RVF) pour une éventuelle application dans le secteur vinicole. Cette technique est testée en présence de deux membranes organiques différentes: PES (hydrophile) et PTFE (hydrophobe). Les observations ont permis de mettre en évidence l'efficacité du système contre le colmatage des membranes PES induite par l'action de l'agitateur. Le colmatage des membranes PTFE est énormément affecté par les interactions molécules/membrane rendant la filtration dynamique inefficace pour lutter contre le colmatage de ces membranes. ABSTRACT : Wine clarification by membrane processes mainly cross-flow microfiltration has been limited by membrane fouling generating low permeate fluxes with economic efficiency. Understanding, controlling and anticipation of fouling are the main goals of this work. In a first time, the individual contribution of wine compounds (tannins, pectins, mannoproteins and yeasts) to a multichannel ceramic membrane fouling was evaluated. The fouling mechanisms were analyzed using a fundamental approach. The presence of pectins induce the lowest fluxes by a gel-type formation at the membrane surface while yeasts presence tends to reduce fouling in the case of crude wine (case of mixed components). Because it represents the flux beyond which irreversible fouling appears on the membrane surface, the critical flux for irreversibility is a key parameter to control fouling. No critical flux for irreversibility could be measured, hence a criterion that identifies a range of operating conditions where the degree of fouling remains acceptable was proposed. The last part of this work was devoted to the study of dynamic filtration (RVF) for further application in wine sector. This technique was tested with two different membranes: hydrophilic PES and hydrophobic PTFE. Results have allowed to demonstrate the efficiency of the system to reduce fouling in the case of PES membrane. Fouling of PTFE membrane is greatly influenced by molecules / membrane interaction making dynamic filtration ineffective in reducing of membrane fouling

The Violence of Representation: James, Sargent and the Suffragette

In May 1914 suffragist Mary Aldham, alias Mary Wood, slashed John Singer Sargent’s portrait of Henry James with a meat cleaver. Contemporaries responded to the attack with anger and bafflement, and more recent commentators have also encountered interpretative difficulties. However, when read alongside other suffragist acts of militancy and reactions to these acts, the incident reflects tellingly on a significant web of ideas in James’s work. Focusing on four stories from different stages in James’s career – ‘The Story of a Masterpiece’ (1868), ‘The Liar’ (1888), ‘Glasses’ (1896) and ‘The Beldonald Holbein’ (1901) – this article explores the author’s conception of the particular form of violence involved in portraiture, a violence linked with women’s exclusion from the fields of political and artistic representation. In James’s writing and other cultural sources, women’s infiltration into these privileged spheres is associated with crude commerciality and the debasement of culture; but James’s exploration of the overlap between advertising and artistic representation betrays his deep ambivalence on the subject