GCOM-W AMSR2 Soil Moisture Product Validation Using Core Validation Sites

The Advanced Microwave Scanning Radiometer 2 (AMSR2) is part of the Global Change Observation Mission-Water (GCOM-W). AMSR2 has filled the gap in passive microwave observations left by the loss of the Advanced Microwave Scanning RadiometerEarth Observing System (AMSR-E) after almost 10 years of observations. Both missions provide brightness temperature observations that are used to retrieve soil moisture estimates at the near surface. A merged AMSR-E and AMSR2 data product will help build a consistent long-term dataset; however, before this can be done, it is necessary to conduct a thorough validation and assessment of the AMSR2 soil moisture products. This study focuses on the validation of the AMSR2 soil moisture products by comparison with in situ reference data from a set of core validation sites around the world. A total of three soil moisture products that rely on different algorithms were evaluated; the Japan Aerospace Exploration Agency (JAXA) soil moisture algorithm, the Land Parameter Retrieval Model (LPRM), and the Single Channel Algorithm (SCA). JAXA, SCA and LPRM soil moisture estimates capture the overall climatological features. The spatial features of the three products have similar overall spatial structure. The JAXA soil moisture product shows a lower dynamic range in the retrieved soil moisture with a satisfactory performance matrix when compared to in situ observations (ubRMSE0.059 m3m3, Bias-0.083 m3m3, R0.465). The SCA performs well over low and moderately vegetated areas (ubRMSE0.053 m3m3, Bias-0.039 m3m3, R0.549). The LPRM product has a large dynamic range compared to in situ observations with a wet bias (ubRMSE0.094 m3m3, Bias0.091 m3m3, R0.577). Some of the error is due to the difference in observation depth between the in situ sensors (5 cm) and satellite estimates (1 cm). Results indicate that overall the JAXA and SCA have the best performance based upon the metrics considered

Researching Memory in Early Modern Studies

This essay pursues the study of early modern memory across a chronologically, conceptually and thematically broad canvas in order to address key questions about the historicity of memory and the methodologies of memory studies. First, what is the value for our understanding of early modern memory practices of transporting the methodologies of contemporary memory studies backwards, using them to study the memorial culture of a time before living memory? Second, what happens to the cross-disciplinary project of memory studies when it is taken to a distant period, one that had its own highly self-conscious and much debated cultures of remembering? Drawing on evidence and debates from a range of disciplinary locations, but primarily focusing on literary and historical studies, the essay interrogates crucial differences and commonalities between memory studies and early modern studies

Assessment of Version 4 of the SMAP Passive Soil Moisture Standard Product

NASAs Soil Moisture Active Passive (SMAP) mission launched on January 31, 2015 into a sun-synchronous 6 am6 pm orbit with an objective to produce global mapping of high-resolution soil moisture and freeze-thaw state every 2-3 days. The SMAP radiometer began acquiring routine science data on March 31, 2015 and continues to operate nominally. SMAPs radiometer-derived standard soil moisture product (L2SMP) provides soil moisture estimates posted on a 36-km fixed Earth grid using brightness temperature observations and ancillary data. A beta quality version of L2SMP was released to the public in October, 2015, Version 3 validated L2SMP soil moisture data were released in May, 2016, and Version 4 L2SMP data were released in December, 2016. Version 4 data are processed using the same soil moisture retrieval algorithms as previous versions, but now include retrieved soil moisture from both the 6 am descending orbits and the 6 pm ascending orbits. Validation of 19 months of the standard L2SMP product was done for both AM and PM retrievals using in situ measurements from global core calval sites. Accuracy of the soil moisture retrievals averaged over the core sites showed that SMAP accuracy requirements are being met

Development and Validation of The SMAP Enhanced Passive Soil Moisture Product

Since the beginning of its routine science operation in March 2015, the NASA SMAP observatory has been returning interference-mitigated brightness temperature observations at L-band (1.41 GHz) frequency from space. The resulting data enable frequent global mapping of soil moisture with a retrieval uncertainty below 0.040 cu m/cu m at a 36 km spatial scale. This paper describes the development and validation of an enhanced version of the current standard soil moisture product. Compared with the standard product that is posted on a 36 km grid, the new enhanced product is posted on a 9 km grid. Derived from the same time-ordered brightness temperature observations that feed the current standard passive soil moisture product, the enhanced passive soil moisture product leverages on the Backus-Gilbert optimal interpolation technique that more fully utilizes the additional information from the original radiometer observations to achieve global mapping of soil moisture with enhanced clarity. The resulting enhanced soil moisture product was assessed using long-term in situ soil moisture observations from core validation sites located in diverse biomes and was found to exhibit an average retrieval uncertainty below 0.040 cu m/cu m. As of December 2016, the enhanced soil moisture product has been made available to the public from the NASA Distributed Active Archive Center at the National Snow and Ice Data Center

The effects of integrated care: a systematic review of UK and international evidence

BACKGROUND: Healthcare systems around the world have been responding to the demand for better integrated models of service delivery. However, there is a need for further clarity regarding the effects of these new models of integration, and exploration regarding whether models introduced in other care systems may achieve similar outcomes in a UK national health service context. METHODS: The study aimed to carry out a systematic review of the effects of integration or co-ordination between healthcare services, or between health and social care on service delivery outcomes including effectiveness, efficiency and quality of care. Electronic databases including MEDLINE; Embase; PsycINFO; CINAHL; Science and Social Science Citation Indices; and the Cochrane Library were searched for relevant literature published between 2006 to March 2017. Online sources were searched for UK grey literature, and citation searching, and manual reference list screening were also carried out. Quantitative primary studies and systematic reviews, reporting actual or perceived effects on service delivery following the introduction of models of integration or co-ordination, in healthcare or health and social care settings in developed countries were eligible for inclusion. Strength of evidence for each outcome reported was analysed and synthesised using a four point comparative rating system of stronger, weaker, inconsistent or limited evidence. RESULTS: One hundred sixty seven studies were eligible for inclusion. Analysis indicated evidence of perceived improved quality of care, evidence of increased patient satisfaction, and evidence of improved access to care. Evidence was rated as either inconsistent or limited regarding all other outcomes reported, including system-wide impacts on primary care, secondary care, and health care costs. There were limited differences between outcomes reported by UK and international studies, and overall the literature had a limited consideration of effects on service users. CONCLUSIONS: Models of integrated care may enhance patient satisfaction, increase perceived quality of care, and enable access to services, although the evidence for other outcomes including service costs remains unclear. Indications of improved access may have important implications for services struggling to cope with increasing demand. TRIAL REGISTRATION: Prospero registration number: 42016037725

Fuel Gas Storage:The Challenge of Hydrogen

Among today’s societal challenges, arguably some of the most important are the safe, sustainable and affordable supply of clean water, food and energy. Energy is certainly a crucial challenge as demand is likely to increase greatly, due to the economic development of poorer nations and an increase in world population. This will put enormous pressure on the future exploration and production of energy sources. Perhaps an even more important aspect are current and predicted environmental problems associated with fossil fuels, the most notorious being climate change, which demands that we decarbonise our economies or risk catastrophic consequences. A solution for this problem would be to use a clean, sustainable energy system; one which converts, transports and uses energy safely, with no harmful emissions to the atmosphere and at an affordable cost.This clean and sustainable energy system would almost certainly require a great share in conversion of energy from renewable energy sources, and probably a clean energy vector, along with electricity, to decarbonise the transport sector and to balance supply and demand in the electric grid. Hydrogen is the one of the best alternatives for a clean and sustainable energy vector as it presents obvious advantages, among those the fact that it has the highest energy per unit mass of any chemical fuel, can be efficiently used in a fuel cell with no emissions, and can be produced, stored, distributed and used through a variety of different sustainable pathways.One of the biggest problems with hydrogen energy is its storage. Hydrogen is a very low density gas and methods of increasing its density, usually compression at 35 or 70 MPa or liquefaction at 20 K, carry high materials and energy penalties. Some proposed alternatives include chemical storage, which consists of reacting hydrogen with another element and storing it as a hydride or using highly porous materials to enhance the density of hydrogen on its surface. Adsorptive storage of hydrogen can be an attractive solution to the storage problem, as it can store equal amounts of hydrogen in the same volume at much milder conditions of pressure and temperature. Experiments on different adsorbent materials, including the metal-organic framework MIL-101 and activated carbons AX-21 and TE7, were done to identify and possibly tailor optimal materials for hydrogen storage. The results were analysed taking into account a number of different requirements for a hydrogen storage system, including capacity of the material, gravimetric and volumetric density, optimal operating conditions for storage, thermal management of the system and optimum kinetics and diffusion in adsorbent systems. These results were analysed in a systems approach context and used as input into the design of an improved adsorbent storage system

How Reproducible are Surface Areas Calculated from the BET Equation?

Porosity and surface area analysis play a prominent role in modern materials science. At the heart of this sits the Brunauer-Emmett-Teller (BET) theory, which has been a remarkably successful contribution to the field of materials science. The BET method was developed in the 1930s for open surfaces but is now the most widely used metric for the estimation of surface areas of micro- and mesoporous materials. Despite its widespread use, the calculation of BET surface areas causes a spread in reported areas, resulting in reproducibility problems in both academia and industry. To prove this, for this analysis, 18 already-measured raw adsorption isotherms were provided to sixty-one labs, who were asked to calculate the corresponding BET areas. This round-robin exercise resulted in a wide range of values. Here, the reproducibility of BET area determination from identical isotherms is demonstrated to be a largely ignored issue, raising critical concerns over the reliability of reported BET areas. To solve this major issue, a new computational approach to accurately and systematically determine the BET area of nanoporous materials is developed. The software, called "BET surface identification" (BETSI), expands on the well-known Rouquerol criteria and makes an unambiguous BET area assignment possible.fals

Dairying, diseases and the evolution of lactase persistence in Europe

Update notice Author Correction: Dairying, diseases and the evolution of lactase persistence in Europe (Nature, (2022), 608, 7922, (336-345), 10.1038/s41586-022-05010-7) Nature, Volume 609, Issue 7927, Pages E9, 15 September 2022In European and many African, Middle Eastern and southern Asian populations, lactase persistence (LP) is the most strongly selected monogenic trait to have evolved over the past 10,000 years(1). Although the selection of LP and the consumption of prehistoric milk must be linked, considerable uncertainty remains concerning their spatiotemporal configuration and specific interactions(2,3). Here we provide detailed distributions of milk exploitation across Europe over the past 9,000 years using around 7,000 pottery fat residues from more than 550 archaeological sites. European milk use was widespread from the Neolithic period onwards but varied spatially and temporally in intensity. Notably, LP selection varying with levels of prehistoric milk exploitation is no better at explaining LP allele frequency trajectoriesthan uniform selection since the Neolithic period. In the UK Biobank(4,5) cohort of 500,000 contemporary Europeans, LP genotype was only weakly associated with milk consumption and did not show consistent associations with improved fitness or health indicators. This suggests that other reasons for the beneficial effects of LP should be considered for its rapid frequency increase. We propose that lactase non-persistent individuals consumed milk when it became available but, under conditions of famine and/or increased pathogen exposure, this was disadvantageous, driving LP selection in prehistoric Europe. Comparison of model likelihoods indicates that population fluctuations, settlement density and wild animal exploitation-proxies for these drivers-provide better explanations of LP selection than the extent of milk exploitation. These findings offer new perspectives on prehistoric milk exploitation and LP evolution.Peer reviewe

How reproducible are surface areas calculated from the BET equation?

Porosity and surface area analysis play a prominent role in modern materials science. At the heart of this sits the Brunauer-Emmett-Teller (BET) theory, which has been a remarkably successful contribution to the field of materials science. The BET method was developed in the 1930s for open surfaces but is now the most widely used metric for the estimation of surface areas of micro- and mesoporous materials. Despite its widespread use, the calculation of BET surface areas causes a spread in reported areas, resulting in reproducibility problems in both academia and industry. To prove this, for this analysis, 18 already-measured raw adsorption isotherms were provided to sixty-one labs, who were asked to calculate the corresponding BET areas. This round-robin exercise resulted in a wide range of values. Here, the reproducibility of BET area determination from identical isotherms is demonstrated to be a largely ignored issue, raising critical concerns over the reliability of reported BET areas. To solve this major issue, a new computational approach to accurately and systematically determine the BET area of nanoporous materials is developed. The software, called "BET surface identification" (BETSI), expands on the well-known Rouquerol criteria and makes an unambiguous BET area assignment possible