Sources and characteristics of summertime organic aerosol in the Colorado Front Range: perspective from measurements and WRF-Chem modeling

Abstract. The evolution of organic aerosols (OAs) and their precursors in the boundary layer (BL) of the Colorado Front Range during the Front Range Air Pollution and Photochemistry Éxperiment (FRAPPÉ, July–August 2014) was analyzed by in situ measurements and chemical transport modeling. Measurements indicated significant production of secondary OA (SOA), with enhancement ratio of OA with respect to carbon monoxide (CO) reaching 0.085±0.003 µg m−3 ppbv−1. At background mixing ratios of CO, up to  ∼  1.8 µg m−3 background OA was observed, suggesting significant non-combustion contribution to OA in the Front Range. The mean concentration of OA in plumes with a high influence of oil and natural gas (O&G) emissions was  ∼  40 % higher than in urban-influenced plumes. Positive matrix factorization (PMF) confirmed a dominant contribution of secondary, oxygenated OA (OOA) in the boundary layer instead of fresh, hydrocarbon-like OA (HOA). Combinations of primary OA (POA) volatility assumptions, aging of semi-volatile species, and different emission estimates from the O&G sector were used in the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) simulation scenarios. The assumption of semi-volatile POA resulted in greater than a factor of 10 lower POA concentrations compared to PMF-resolved HOA. Including top-down modified O&G emissions resulted in substantially better agreements in modeled ethane, toluene, hydroxyl radical, and ozone compared to measurements in the high-O&G-influenced plumes. By including emissions from the O&G sector using the top-down approach, it was estimated that the O&G sector contributed to  <  5 % of total OA, but up to 38 % of anthropogenic SOA (aSOA) in the region. The best agreement between the measured and simulated median OA was achieved by limiting the extent of biogenic hydrocarbon aging and consequently biogenic SOA (bSOA) production. Despite a lower production of bSOA in this scenario, contribution of bSOA to total SOA remained high at 40–54 %. Future studies aiming at a better emissions characterization of POA and intermediate-volatility organic compounds (IVOCs) from the O&G sector are valuable

Fault current compensations in resonant grounded distribution systems to mitigate powerline bushfires using a nonsingular terminal sliding model controller

A fault current compensation technique is proposed in this paper for resonant grounded power distribution systems in bushfire prone areas. Arc suppression devices with residual current compensation inverters are used to compensate fault currents due to single line-to-ground faults in order to mitigate powerline bushfires. The main contribution of this paper is the design of a compensation technique for the T-type residual current compensation inverter using a non-singular terminal sliding mode control scheme. The main objective of the proposed scheme is to reduce the fault current and bring its value to a level so that it cannot ignite fires. The proposed controller is designed based on the selection of a sliding surface in a way the singularity problem can be avoided and chattering effects in existing sliding mode controllers can be eliminated. The desired current injection through the residual current compensation inverter is ensured by enforcing the control law into the terminal sliding surface where the control law is determined by satisfying the Lyapunov stability criteria. The performance of the non-singular terminal sliding mode controller is compared with an integral sliding mode controller by considering different values of fault currents where these values are varied by changing fault resistances. Results for simulation in the software and processor-in-loop simulations are verified against operational standards which are essential for mitigating powerline bushfires. This work focuses to design a non-singular terminal sliding mode controller for the residual current compensation inverter which is used in an arc suppression device to compensate both active and reactive components of the fault current and keeps its value below 0.5 A within 2 s after activating the residual current compensation inverter which is a requirement as per the operational standard. This controller is designed based on the selection of a terminal sliding surface while satisfying the condition for avoiding the singularity problem

Constraints from observations and modeling on atmosphere-surface exchange of mercury in eastern North America

Atmosphere-surface exchange of mercury, although a critical component of its global cycle, is currently poorly constrained. Here we use the GEOS-Chem chemical transport model to interpret atmospheric Hg-0 (gaseous elemental mercury) data collected during the 2013 summer Nitrogen, Oxidants, Mercury and Aerosol Distributions, Sources and Sinks (NOMADSS) aircraft campaign as well as ground-and ship-based observations in terms of their constraints on the atmosphere-surface exchange of Hg-0 over eastern North America. Model-observation comparison suggests that the Northwest Atlantic may be a net source of Hg-0, with high evasion fluxes in summer (our best sensitivity simulation shows an average oceanic Hg-0 flux of 3.3 ng m(-2) h(-1) over the Northwest Atlantic), while the terrestrial ecosystem in the summer of the eastern United States is likely a net sink of Hg-0 (our best sensitivity simulation shows an average terrestrial Hg-0 flux of -0.6 ng m(-2) h(-1) over the eastern United States). The inferred high Hg-0 fluxes from the Northwest Atlantic may result from high wet deposition fluxes of oxidized Hg, which are in turn related to high precipitation rates in this region. We also find that increasing simulated terrestrial fluxes of Hg-0 in spring compared to other seasons can better reproduce observed seasonal variability of Hg-0 concentration at ground-based sites in eastern North America.Peer reviewe

A non‐linear adaptive excitation control scheme for feedback linearized synchronous generations in multimachine power systems

A new adaptive scheme is proposed in this paper to design excitation controllers for feedback linearized models of synchronous generators in multimachine power systems in order to ensure the stability during large disturbances. The proposed scheme uses speed deviations of synchronous generators, readily available measured physical properties of multimachine power systems, to make all generators within a power network as partially linearized as well as to provide more damping. An adaptive scheme is then used to estimate all unknown parameters which appear in the partial feedback linearizing excitation controllers in order to avoid parameter sensitivities of existing feedback linearization techniques. The overall stability of multimachine power systems is ensured through the excitation control and parameter adaptation laws. The Lyapunov stability theory is used to theoretically analyse the stability of multimachine power systems with the proposed scheme. Simulation studies are presented to evaluate the performance of the proposed excitation control scheme for two different test systems by different operating conditions including short-circuit faults on key locations along with variations in parameters for a large duration. Furthermore, comparative results are presented to highlight the superiority of the proposed adaptive partial feedback linearizing excitation control scheme over an existing partial feedback linearizing excitation controllers

Design of Nonlinear Backstepping Double-Integral Sliding Mode Controllers to Stabilize the DC-Bus Voltage for DC–DC Converters Feeding CPLs

This paper proposes a composite nonlinear controller combining backstepping and double-integral sliding mode controllers for DC–DC boost converter (DDBC) feeding by constant power loads (CPLs) to improve the DC-bus voltage stability under large disturbances in DC distribution systems. In this regard, an exact feedback linearization approach is first used to transform the nonlinear dynamical model into a simplified linear system with canonical form so that it becomes suitable for designing the proposed controller. Another important feature of applying the exact feedback linearization approach in this work is to utilize its capability to cancel nonlinearities appearing due to the incremental negative-impedance of CPLs and the non-minimum phase problem related to the DDBC. Second, the proposed backstepping double integral-sliding mode controller (BDI-SMC) is employed on the feedback linearized system to determine the control law. Afterwards, the Lyapunov stability theory is used to analyze the closed-loop stability of the overall system. Finally, a simulation study is conducted under various operating conditions of the system to validate the theoretical analysis of the proposed controller. The simulation results are also compared with existing sliding mode controller (ESMC) and proportional-integral (PI) control schemes to demonstrate the superiority of the proposed BDI-SMC

A nonlinear double‐integral sliding mode controller design for hybrid energy storage systems and solar photovoltaic units to enhance the power management in DC microgrids

In this paper, a nonlinear decentralized double‐integral sliding mode controller (DI‐SMC) is designed along with an energy management system (EMS) for the DC microgrid (DCMG). This DCMG includes having a hybrid energy storage system (HESS) that incorporates a battery energy storage system (BESS) and supercapacitor energy storage system (SCESS) while the load demand is met through the power generated from solar photovoltaic (SPV) units. First, dynamical models of each subsystem of DCMGs such as the SPV system, BESS, and SCESS are developed to capture highly nonlinear behaviors of DCMGs under various operating conditions. The proposed nonlinear DI‐SMC is then designed for each power unit in DCMGs to ensure the desired voltage level at the common DC‐bus and appropriate power dispatch of different components to fulfill the load requirement of the DCMG. On the other hand, an energy management system (EMS) is designed to determine the set point for the controller with an aim of ensuring the power balance within DCMGs under various operating conditions where the overall stability is assessed using the Lyapunov theory. Simulation studies along with the processor‐in‐loop validation, including a comparative study with a proportional‐integral (PI) controller, verify the applicability and effectiveness of the EMS‐based DI‐SMC under different operating conditions of the DCMG

Analysis of Steady-State Characteristics for a Newly Designed High Voltage Gain Switched Inductor Z-Source Inverter

This paper aims to develop a new switched inductor assisted strong boost Z-source inverter (SL-SBZSI) topology with high voltage gain and analyze the steady-state characteristics of the proposed topology. In the proposed topology, two switched inductors are used within the series impedance structure of the Z-source inverter (ZSI) in order to achieve the high voltage gain. The steady-state characteristics of the proposed topology are analyzed to disseminate its several advantages as compared to traditional ZSIs. The key advantages include the higher boost factor with lower shoot-through duty ratio and lower voltage stresses on capacitors as well as on switches of the inverter bridge. Furthermore, the proposed topology has the soft-start ability which significantly reduces the inrush start-up current while comparing with the traditional ZSI. In the proposed topology, a common ground is shared between the output AC voltage and the input DC voltage source which categorizes this topology to the doubly grounded inverter. The characteristics of the proposed SL-SBZSI are analyzed by considering two operating condition where the simple boost pulse width modulation (PWM) scheme is used to extract the shoot-through pulses. The characteristics of the proposed topology are also compared with different existing topologies along with the conventional modified capacitor assisted Z-source inverter (MCA-ZSI), whose boost factor is much closer to the proposed topology. Rigorous mathematical analyses are presented to clearly demonstrate the benefits of the proposed topology while simulation studies are carried out to demonstrate its distinct features as compared to the existing topology. Finally, experimental studies are conducted to further validate the theoretical and simulation results

Energy dependence of the differences between the quark and gluon jet fragmentation

Three jet events arising from decays of the Z boson, collected by the DELPHI detector, were used to measure differences in quark and gluon fragmentation. Gluon jets were anti-tagged by identifying b quark jets. Unbiased quark jets came from events with two jets plus one photon. Quark and gluon jet properties in different energy ranges were compared for the first time within the same detector. Quark and gluon jets of nearly the same energy in symmetric three jet event topologies were also compared. Using three independent methods, the average value of the ratio of the mean charged multiplicities of gluon and quark jets is $$=1.241\pm 0.015\ (stat.) \pm 0.025\ (syst.).$$ Gluon jets are broader and produce fragments with a softer energy spectrum than quark jets of equivalent energy. The string effect has been observed in fully symmetric three jet events. The measured ratio R_{\gamma} of the charged particle flow in the q\overline{q} inter-jet region of the q\bar{q}g and q\bar{q}\gamma samples agrees with the perturbative QCD expectation. The dependence of the mean charged multiplicity on the hadronic center-of-mass energy was analysed in photon plus n-jet events. The value for \alpha_s(M_Z) determined from these data using a QCD prediction with corrections at leading and next-to-leading order is \[ \alpha_s(M_Z)=0.116 \pm 0.003\ (stat.) \pm 0.009\ (syst.). \

An Energy Management System-Based Control Strategy for DC Microgrids with Dual Energy Storage Systems

In this work, a control strategy is developed for different components in DC microgrids where set points for all controllers are determined from an energy management system (EMS). The proposed EMS-based control scheme is developed for DC microgrids with solar photovoltaic (PV) systems as the primary generation units along with energy storage systems. In this work, the concept of dual energy storage systems (DESSs) is used, which includes a battery energy storage system (BESS) and supercapacitor (SC). The main feature of this DESS is to improve the dynamic performance of DC microgrids during severe transients appearing from changes in load demands as well as in the output power from solar PV units. Furthermore, the proposed EMS-based control scheme aims to enhance the lifetime of the BESS in DC microgrids with DESSs and voltage stability as compared to the same without SCs. The proposed EMS-based control strategy uses proportional-integral (PI) controllers to regulate the switching control actions for different converters within the DC microgrid based on the decision obtained from the EMS in order to achieve the desired control objectives. The performance of the proposed scheme was analyzed through simulation results in terms of improving the voltage stability, maintaining the power balance, and enhancing the lifetime of BESSs within a DC microgrid framework incorporated with the DESS. The simulations are carried out in the MATLAB/SIMULINK simulation platform and compared with a similar approach having only a single energy storage system, i.e., the BESS