3,309 research outputs found
Benz[4,5]Isoquino[1,2-\u3cem\u3eb\u3c/em\u3e]Quinazoline-7,9-Dione and a Rearrangement Product of its Hydrolysis, 2-(1,8-Naphthalenedicarboximido)benzamide
Conceptual aspects of line tensions
We analyze two representative systems containing a three-phase-contact line:
a liquid lens at a fluid--fluid interface and a liquid drop in contact with a
gas phase residing on a solid substrate. We discuss to which extent the
decomposition of the grand canonical free energy of such systems into volume,
surface, and line contributions is unique in spite of the freedom one has in
positioning the Gibbs dividing interfaces. In the case of a lens it is found
that the line tension is independent of arbitrary choices of the Gibbs dividing
interfaces. In the case of a drop, however, one arrives at two different
possible definitions of the line tension. One of them corresponds seamlessly to
that applicable to the lens. The line tension defined this way turns out to be
independent of choices of the Gibbs dividing interfaces. In the case of the
second definition,however, the line tension does depend on the choice of the
Gibbs dividing interfaces. We provide equations for the equilibrium contact
angles which are form-invariant with respect to notional shifts of dividing
interfaces which only change the description of the system. Conceptual
consistency requires to introduce additional stiffness constants attributed to
the line. We show how these constants transform as a function of the relative
displacements of the dividing interfaces. The dependences of the contact angles
on lens or drop volumes do not render the line tension alone but a combination
of the line tension, the Tolman length, and the stiffness constants of the
line.Comment: 34 pages, 9 figure
Plasma flow past a two-dimensional magnetic dipole
Plasma flow past a two dimensional magnetic dipol
All speed scheme for the low mach number limit of the Isentropic Euler equation
An all speed scheme for the Isentropic Euler equation is presented in this
paper. When the Mach number tends to zero, the compressible Euler equation
converges to its incompressible counterpart, in which the density becomes a
constant. Increasing approximation errors and severe stability constraints are
the main difficulty in the low Mach regime. The key idea of our all speed
scheme is the special semi-implicit time discretization, in which the low Mach
number stiff term is divided into two parts, one being treated explicitly and
the other one implicitly. Moreover, the flux of the density equation is also
treated implicitly and an elliptic type equation is derived to obtain the
density. In this way, the correct limit can be captured without requesting the
mesh size and time step to be smaller than the Mach number. Compared with
previous semi-implicit methods, nonphysical oscillations can be suppressed. We
develop this semi-implicit time discretization in the framework of a first
order local Lax-Friedrich (LLF) scheme and numerical tests are displayed to
demonstrate its performances
Grand potential in thermodynamics of solid bodies and surfaces
Using the chemical potential of a solid in a dissolved state or the
corresponding component of the chemical potential tensor at equilibrium with
the solution, a new concept of grand thermodynamic potential for solids has
been suggested. This allows generalizing the definition of Gibbs' quantity
(surface work often called the solid-fluid interfacial free energy) at
a planar surface as an excess grand thermodynamic potential per unit surface
area that (1) does not depend on the dividing surface location and (2) is
common for fluids and solids.Comment: 6 page
Enhancement of the superconducting transition temperature in Nb/Permalloy bilayers by controlling the domain state of the ferromagnet
In (S/F) hybrids the suppression of superconductivity by the exchange field
h_ex of the ferromagnet can be partially lifted when different directions of
h_ex are sampled simultaneously by the Cooper pair. In F/S/F trilayer
geometries where the magnetization directions of the two F-layers can be
controlled separately, this leads to the so-called spin switch. Here we show
that domain walls in a single F-layer yield a similar effect. We study the
transport properties of Ni_0.8Fe_0.2/Nb bilayers structured in strips of
different sizes. For large samples a clear enhancement of superconductivity
takes place in the resistive transition, in the very narrow field range (order
of 0.5 mT) where the magnetization of the Py layer switches and many domains
are present. This effect is absent in microstructured samples. Comparison of
domain wall width \delta_w to the temperature dependent superconductor
coherence length \xi_S(T) shows that \delta_w ~ \xi_S(T), which means that the
Cooper pairs sample a large range of different magnetization directions.Comment: 4 pages, 5 figure
Capillary pressure of van der Waals liquid nanodrops
The dependence of the surface tension on a nanodrop radius is important for
the new-phase formation process. It is demonstrated that the famous Tolman
formula is not unique and the size-dependence of the surface tension can
distinct for different systems. The analysis is based on a relationship between
the surface tension and disjoining pressure in nanodrops. It is shown that the
van der Waals interactions do not affect the new-phase formation thermodynamics
since the effect of the disjoining pressure and size-dependent component of the
surface tension cancel each other.Comment: The paper is dedicated to the 80th anniversary of A.I. Rusano
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