An elasto-visco-plastic model for immortal foams or emulsions

A variety of complex fluids consist in soft, round objects (foams, emulsions, assemblies of copolymer micelles or of multilamellar vesicles -- also known as onions). Their dense packing induces a slight deviation from their prefered circular or spherical shape. As a frustrated assembly of interacting bodies, such a material evolves from one conformation to another through a succession of discrete, topological events driven by finite external forces. As a result, the material exhibits a finite yield threshold. The individual objects usually evolve spontaneously (colloidal diffusion, object coalescence, molecular diffusion), and the material properties under low or vanishing stress may alter with time, a phenomenon known as aging. We neglect such effects to address the simpler behaviour of (uncommon) immortal fluids: we construct a minimal, fully tensorial, rheological model, equivalent to the (scalar) Bingham model. Importantly, the model consistently describes the ability of such soft materials to deform substantially in the elastic regime (be it compressible or not) before they undergo (incompressible) plastic creep -- or viscous flow under even higher stresses.Comment: 69 pages, 29 figure

Non-Equilibrium in Adsorbed Polymer Layers

High molecular weight polymer solutions have a powerful tendency to deposit adsorbed layers when exposed to even mildly attractive surfaces. The equilibrium properties of these dense interfacial layers have been extensively studied theoretically. A large body of experimental evidence, however, indicates that non-equilibrium effects are dominant whenever monomer-surface sticking energies are somewhat larger than kT, a common case. Polymer relaxation kinetics within the layer are then severely retarded, leading to non-equilibrium layers whose structure and dynamics depend on adsorption kinetics and layer ageing. Here we review experimental and theoretical work exploring these non-equilibrium effects, with emphasis on recent developments. The discussion addresses the structure and dynamics in non-equilibrium polymer layers adsorbed from dilute polymer solutions and from polymer melts and more concentrated solutions. Two distinct classes of behaviour arise, depending on whether physisorption or chemisorption is involved. A given adsorbed chain belonging to the layer has a certain fraction of its monomers bound to the surface, f, and the remainder belonging to loops making bulk excursions. A natural classification scheme for layers adsorbed from solution is the distribution of single chain f values, P(f), which may hold the key to quantifying the degree of irreversibility in adsorbed polymer layers. Here we calculate P(f) for equilibrium layers; we find its form is very different to the theoretical P(f) for non-equilibrium layers which are predicted to have infinitely many statistical classes of chain. Experimental measurements of P(f) are compared to these theoretical predictions.Comment: 29 pages, Submitted to J. Phys.: Condens. Matte

On Complexity of 1-Center in Various Metrics

We consider the classic 1-center problem: Given a set P of n points in a metric space find the point in P that minimizes the maximum distance to the other points of P. We study the complexity of this problem in d-dimensional $\ell_p$-metrics and in edit and Ulam metrics over strings of length d. Our results for the 1-center problem may be classified based on d as follows. $\bullet$ Small d: We provide the first linear-time algorithm for 1-center problem in fixed-dimensional $\ell_1$ metrics. On the other hand, assuming the hitting set conjecture (HSC), we show that when $d=\omega(\log n)$, no subquadratic algorithm can solve 1-center problem in any of the $\ell_p$-metrics, or in edit or Ulam metrics. $\bullet$ Large d. When $d=\Omega(n)$, we extend our conditional lower bound to rule out sub quartic algorithms for 1-center problem in edit metric (assuming Quantified SETH). On the other hand, we give a $(1+\epsilon)$-approximation for 1-center in Ulam metric with running time $\tilde{O_{\epsilon}}(nd+n^2\sqrt{d})$. We also strengthen some of the above lower bounds by allowing approximations or by reducing the dimension d, but only against a weaker class of algorithms which list all requisite solutions. Moreover, we extend one of our hardness results to rule out subquartic algorithms for the well-studied 1-median problem in the edit metric, where given a set of n strings each of length n, the goal is to find a string in the set that minimizes the sum of the edit distances to the rest of the strings in the set

Slow viscoelastic relaxation and aging in aqueous foam

Like emulsions, pastes and many other forms of soft condensed matter, aqueous foams present slow mechanical relaxations when subjected to a stress too small to induce any plastic flow. To identify the physical origin of this viscoelastic behaviour, we have simulated how dry disordered coarsening 2D foams respond to a small applied stress. We show that the mechanism of long time relaxation is driven by coarsening induced rearrangements of small bubble clusters. These findings are in full agreement with a scaling law previously derived from experimental creep data for 3D foams. Moreover, we find that the temporal statistics of coarsening induced bubble rearrangements are described by a Poisson process.Comment: 7 pages, 3 figure

A high rate flow-focusing foam generator

We use a rigid axisymetric microfluidic flow focusing device to produce monodisperse bubbles, dispersed in a surfactant solution. The gas volume fraction of the dispersion collected out of this device can be as large as 90%, demonstrating that foam with solid-like viscoelastic properties can be produced in this way. The polydispersity of the bubbles is so low that we observe crystallization of our foam. We measure the diameter of the bubbles and compare these data to recent theoretical predictions. The good control over bubble size and foam gas volume fraction shows that our device is a flexible and promising tool to produce calibrated foam at a high flow rate

Soft Dynamics simulation: 2. Elastic spheres undergoing a T1 process in a viscous fluid

Robust empirical constitutive laws for granular materials in air or in a viscous fluid have been expressed in terms of timescales based on the dynamics of a single particle. However, some behaviours such as viscosity bifurcation or shear localization, observed also in foams, emulsions, and block copolymer cubic phases, seem to involve other micro-timescales which may be related to the dynamics of local particle reorganizations. In the present work, we consider a T1 process as an example of a rearrangement. Using the Soft dynamics simulation method introduced in the first paper of this series, we describe theoretically and numerically the motion of four elastic spheres in a viscous fluid. Hydrodynamic interactions are described at the level of lubrication (Poiseuille squeezing and Couette shear flow) and the elastic deflection of the particle surface is modeled as Hertzian. The duration of the simulated T1 process can vary substantially as a consequence of minute changes in the initial separations, consistently with predictions. For the first time, a collective behaviour is thus found to depend on another parameter than the typical volume fraction in particles.Comment: 11 pages - 5 figure