Large Magnetoresistance and Jahn Teller effect in Sr2_2FeCoO6_6

Neutron diffraction measurement on the spin glass double perovskite Sr$_2$FeCoO$_6$ reveals site disorder as well as Co$^{3+}$ intermediate spin state. In addition, multiple valence states of Fe and Co are confirmed through M\"{o}ssbauer and X-ray photoelectron spectroscopy. The structural disorder and multiple valence lead to competing ferromagnetic and antiferromagnetic interactions and subsequently to a spin glass state, which is reflected in the form of an additional $T$-linear contribution at low temperatures in specific heat. A clear evidence of Jahn-Teller distortion at the Co$^{3+}$-O$_6$ complex is observed and incorporating the physics of Jahn-Teller effect, the presence of localized magnetic moment is shown. A large, negative and anomalous magnetoresistance of $\approx$ 63% at 14K in 12T applied field is observed for Sr$_2$FeCoO$_6$. The observed magnetoresistance could be explained by applying a semi-empirical fit consisting of a negative and a positive contribution and show that the negative magnetoresistance is due to spin scattering of carriers by localized magnetic moments in the spin glass phase

Linking ventilation heterogeneity quantified via hyperpolarized He-3 MRI to dynamic lung mechanics and airway hyperresponsiveness

Advancements in hyperpolarized helium-3 MRI (HP 3He-MRI) have introduced the ability to render and quantify ventilation patterns throughout the anatomic regions of the lung. The goal of this study was to establish how ventilation heterogeneity relates to the dynamic changes in mechanical lung function and airway hyperresponsiveness in asthmatic subjects. In four healthy and nine mild-to-moderate asthmatic subjects, we measured dynamic lung resistance and lung elastance from 0.1 to 8 Hz via a broadband ventilation waveform technique. We quantified ventilation heterogeneity using a recently developed coefficient of variation method from HP 3He-MRI imaging. Dynamic lung mechanics and imaging were performed at baseline, post-challenge, and after a series of five deep inspirations. AHR was measured via the concentration of agonist that elicits a 20% decrease in the subject’s forced expiratory volume in one second compared to baseline (PC20) dose. The ventilation coefficient of variation was correlated to low-frequency lung resistance (R = 0.647, P < 0.0001), the difference between high and low frequency lung resistance (R = 0.668, P < 0.0001), and low-frequency lung elastance (R = 0.547, P = 0.0003). In asthmatic subjects with PC20 values <25 mg/mL, the coefficient of variation at baseline exhibited a strong negative trend (R = -0.798, P = 0.02) to PC20 dose. Our findings were consistent with the notion of peripheral rather than central involvement of ventilation heterogeneity. Also, the degree of AHR appears to be dependent on the degree to which baseline airway constriction creates baseline ventilation heterogeneity. HP 3He-MRI imaging may be a powerful predictor of the degree of AHR and in tracking the efficacy of therapy.This work was funded by the National Heart, Lung, and Blood Institute Grants R01 HL62269-04 and R01 HL-096797

Antisite Disorder-induced Exchange Bias Effect in Multiferroic Y2CoMnO6

Exchange bias effect in the ferromagnetic double perovskite compound Y$_2$CoMnO$_6$, which is also a multiferroic, is reported. The exchange bias, observed below 8~K, is explained as arising due to the interface effect between the ferromagnetic and antiferromagnetic clusters created by {\it antisite} disorder in this material. Below 8~K, prominent ferromagnetic hysteresis with metamagnetic "steps" and significant coercive field, $H_c \approx$ 10~kOe are observed in this compound which has a $T_c \approx$ 75~K. A model based on growth of ferromagnetic domains overcoming the elastic energy of structurally pinned magnetic interfaces, which closely resembles martensitic-like transitions, is adapted to explain the observed effects. The role of {\it antisite} disorder in creating the domain structure leading to exchange bias effect is highlighted in the present work.Comment: 4 pages two-column, 4 figures, accepted to Appl. Phys. Let

Structural domain and spin ordering induced glassy magnetic phase in single layered manganite Pr0.22_{0.22}Sr1.78_{1.78}MnO4_4

The single layered manganite Pr$_{0.22}$Sr$_{1.78}$MnO$_4$ undergoes structural transition from high temperature tetragonal phase to low temperature orthorhombic phase below room temperature. The orthorhombic phase was reported to have two structural variants with slightly different lattice parameters and Mn-3$d$ levels show orbital ordering within both the variants, albeit having mutually perpendicular ordering axis. In addition to orbital ordering, the orthorhombic variants also order antiferromagnetically with different N\'eel temperatures. Our magnetic investigation on the polycrystalline sample of Pr$_{0.22}$Sr$_{1.78}$MnO$_4$ shows large thermal hysteresis indicating the first order nature of the tetragonal to orthorhombic transition. We observe magnetic memory, large relaxation, frequency dependent ac susceptbility and aging effects at low temperature, which indicate spin glass like magnetic ground state in the sample. The glassy magnetic state presumably arises from the interfacial frustration of orthorhombic domains with orbital and spin orderings playing crucial role toward the competing magnetic interactions.Comment: 6 pages, 4 figures, Accepted in Europhysics Letter

Spin Freezing in the Spin Liquid Compound FeAl2O4

Spin freezing in the $A$-site spinel FeAl$_2$O$_4$ which is a spin liquid candidate is studied using remnant magnetization and nonlinear magnetic susceptibility and isofield cooling and heating protocols. The remnant magnetization behavior of FeAl$_2$O$_4$ differs significantly from that of a canonical spin glass which is also supported by analysis of the nonlinear magnetic susceptibility term $\chi_3 (T)$. Through the power-law analysis of $\chi_3 (T)$, a spin-freezing temperature, $T_g$ = 11.4$\pm$0.9~K and critical exponent, $\gamma$ = 1.48$\pm$0.59 are obtained. Cole-Cole analysis of magnetic susceptibility shows the presence of broad spin relaxation times in FeAl$_2$O$_4$, however, the irreversible dc susceptibility plot discourages an interpretation based on conventional spin glass features. The magnetization measured using the cooling-and-heating-in-unequal-fields protocol brings more insight to the magnetic nature of this frustrated magnet and reveals unconventional glassy behaviour. Combining our results, we arrive at the conclusion that the present sample of FeAl$_2$O$_4$ consists of a majority spin liquid phase with "glassy" regions embedded.Comment: 5 pages, 6 figs, 2-column, Accepted to Phys. Rev.

Ferromagnetism and the Effect of Free Charge Carriers on Electric Polarization in Y_2NiMnO_6 Double Perovskite

The double perovskite Y_2NiMnO_6 displays ferromagnetic transition at Tc = 81 K. The ferromagnetic order at low temperature is confirmed by the saturation value of magnetization (M_s) and also, validated by the refined ordered magnetic moment values extracted from neutron powder diffraction data at 10 K. This way, the dominant Mn4+ and Ni2+ cationic ordering is confirmed. The cation-ordered P 21/n nuclear structure is revealed by neutron powder diffraction studies at 300 and 10 K. Analysis of frequency dependent dielectric constant and equivalent circuit analysis of impedance data takes into account the bulk contribution to total dielectric constant. This reveals an anomaly which coincides with the ferromagnetic transition temperature (T_c). Pyrocurrent measurements register a current flow with onset near Tc and a peak at 57 K that shifts with temperature ramp rate. The extrinsic nature of the observed pyrocurrent is established by employing a special protocol measurement. It is realized that the origin is due to re-orientation of electric dipoles created by the free charge carriers and not by spontaneous electric polarization at variance with recently reported magnetism-driven ferroelectricity in this materialComment: Published in Physical Review

Glassy Dielectric Response in Tb_2NiMnO_6 Double Perovskite with Similarities to a Griffiths Phase

Frequency-dependent and temperature-dependent dielectric measurements are performed on double perovskite Tb$_2$NiMnO$_6$. The real ($\epsilon_1$) and imaginary ($\epsilon_2$) parts of dielectric permittivity show three plateaus suggesting dielectric relaxation originating from bulk, grain boundaries and the sample-electrode interfaces respectively. The temperature and frequency variation of $\epsilon_1$ and $\epsilon_2$ are successfully simulated by a $RC$ circuit model. The complex plane of impedance, $Z'$-$Z"$, is simulated using a series network with a resistor $R$ and a constant phase element. Through the analysis of frequency-dependent dielectric constant using modified-Debye model, different relaxation regimes are identified. Temperature dependence of dc conductivity also presents a clear change in slope at, $T^*$. Interestingly, $T^*$ compares with the temperature at which an anomaly occurs in the phonon modes and the Griffiths temperature for this compound. The components $R$ and $C$ corresponding to the bulk and the parameter $\alpha$ from modified-Debye fit tend support to this hypothesis. Though these results cannot be interpreted as magnetoelectric coupling, the relationship between lattice and magnetism is marked.Comment: Accepted in Europhysics Letter