A Functionalized 8 nm Long Aryleneethynylene Molecular Wire with Alkyne Termini.

The synthesis of new conjugated aryleneethynylene derivatives of up to ca. 8 nm molecular length (compound 16) with terminal alkyne substituents and 9,9-dihexylfluorene units in the backbone is described. Key synthetic steps are Pd-mediated Sonogashira coupling methodology combined with regioselective removal from the terminal alkyne units of 2-hydroxy-2-propyl protecting groups in the presence of trimethylsilyl groups. The structural and electronic properties of 16 were obtained from DFT calculations: the intramolecular terminal C···C distance in its relaxed conformation was found to be 7.8 nm. The calculated distribution of HOMO and LUMO orbitals and the strong blue fluorescence observed for 16 (max = 420, 443 nm in CHCl3 solution) are consistent with a highly conjugated penta[(9,9-dihexyl-2,7-fluorenylene)ethynylene] structure. Molecule 16 possesses multifunctionality and is of interest for future molecular electronic device applications

Effects of asymmetric contacts on single molecule conductances of HS(CH2)nCOOH in nano-electrical junctions

A scanning tunnelling microscope has been used to determine the conductance of single molecular wires with the configuration X-bridge-X, X-bridge-Y and Y-bridge-Y (X = thiol terminus and Y = COOH). We find that for molecular wires with mixed functional groups (X-bridge-Y) the single molecule conductance decreases with respect to the comparable symmetric molecules. These differences are confirmed by theoretical computations based on a combination of density functional theory and the non-equilibrium Green functions formalism. This study demonstrates that the apparent contact resistance, as well as being highly sensitive to the type of the anchoring group is also strongly influenced by contact-asymmetry of the single molecular junction which in this case decreases the transmission. This highlights that contact asymmetry is a significant factor to be considered when evaluating nano-electrical junctions incorporating single molecules

Estimating above ground net biomass change in tropical and subtropical forests: refinement of IPCC default values using forest plot data

As countries advance in greenhouse gas (GHG) accounting for climate change mitigation, consistent estimates of above ground biomass (AGB) net change are needed for the tropics and subtropics. Countries with limited forest monitoring capabilities rely on 2006 IPCC default AGB net change values, which are averages per ecological zone, per continent. These previous defaults come from single studies, provide no uncertainty indications, and aggregate old secondary forests and old-growth forests. In this study, we update these default values using forest plot data. In comparison with previous estimates, new values include data published from 2006 onwards, are derived from multiple sites per global ecological zone, provide measures of variation, and divide forests >20 years old into older secondary forests and old-growth forests. We compiled 176 AGB chronosequences in secondary forests and AGB net change rates from 536 permanent plots in old-growth and managed or logged forests. In this dataset, across all continents and ecozones, AGB net change rates in younger secondary forests (go years) are higher than rates in older secondary (>20 years and ≤100 years) forests and managed or logged forests, which in turn are higher than rates in old-growth forests (> 100 years). Data availability is highest for North and South America, followed by Asia then Africa. We provide a rigorous and traceable refinement of the IPCC 2006 AGB net change default rates, identify which areas in the tropics and subtropics require more research on AGB change, and reflect on possibilities for improvement as more data becomes available

A systematic review on health resilience to economic crises

Background The health effects of recent economic crises differ markedly by population group. The objective of this systematic review is to examine evidence from longitudinal studies on factors influencing resilience for any health outcome or health behaviour among the general population living in countries exposed to financial crises. Methods We systematically reviewed studies from six electronic databases (EMBASE, Global Health, MEDLINE, PsycINFO, Scopus, Web of Science) which used quantitative longitudinal study designs and included: (i) exposure to an economic crisis; (ii) changes in health outcomes/behaviours over time; (iii) statistical tests of associations of health risk and/or protective factors with health outcomes/behaviours. The quality of the selected studies was appraised using the Quality Assessment Tool for Quantitative Studies. PRISMA reporting guidelines were followed. Results From 14,584 retrieved records, 22 studies met the eligibility criteria. These studies were conducted across 10 countries in Asia, Europe and North America over the past two decades. Ten socio-demographic factors that increased or protected against health risk were identified: gender, age, education, marital status, household size, employment/occupation, income/ financial constraints, personal beliefs, health status, area of residence, and social relations. These studies addressed physical health, mortality, suicide and suicide attempts, mental health, and health behaviours. Women’s mental health appeared more susceptible to crises than men’s. Lower income levels were associated with greater increases in cardiovascular disease, mortality and worse mental health. Employment status was associated with changes in mental health. Associations with age, marital status, and education were less consistent, although higher education was associated with healthier behaviours. Conclusions Despite widespread rhetoric about the importance of resilience, there was a dearth of studies which operationalised resilience factors. Future conceptual and empirical research is needed to develop the epidemiology of resilience

Strangelet Search in AuAu Collisions at 200 GeV

We have searched for strangelets in a triggered sample of 61 million central (top 4%) Au+Au collisions at \sNN = 200 GeV near beam rapidities at the STAR detector. We have sensitivity to metastable strangelets with lifetimes of order $\geq 0.1 ns$, in contrast to limits over ten times longer in AGS studies and longer still at the SPS. Upper limits of a few 10^{-6} to 10^{-7} per central Au+Au collision are set for strangelets with mass ${}^{>}_{\sim}30$ GeV/c^{2}.Comment: As publishe

Search for the standard model Higgs boson in the H to ZZ to 2l 2nu channel in pp collisions at sqrt(s) = 7 TeV

A search for the standard model Higgs boson in the H to ZZ to 2l 2nu decay channel, where l = e or mu, in pp collisions at a center-of-mass energy of 7 TeV is presented. The data were collected at the LHC, with the CMS detector, and correspond to an integrated luminosity of 4.6 inverse femtobarns. No significant excess is observed above the background expectation, and upper limits are set on the Higgs boson production cross section. The presence of the standard model Higgs boson with a mass in the 270-440 GeV range is excluded at 95% confidence level.Comment: Submitted to JHE

Longitudinal double-spin asymmetry for inclusive jet production in p+p collisions at sqrt(s)=200 GeV

We report a new STAR measurement of the longitudinal double-spin asymmetry A_LL for inclusive jet production at mid-rapidity in polarized p+p collisions at a center-of-mass energy of sqrt(s) = 200 GeV. The data, which cover jet transverse momenta 5 < p_T < 30 GeV/c, are substantially more precise than previous measurements. They provide significant new constraints on the gluon spin contribution to the nucleon spin through the comparison to predictions derived from one global fit of polarized deep-inelastic scattering measurements.Comment: 7 pages, 4 figures + 1 tabl