Superconductivity in Tetragonal LaPt_{2-x}Ge_{2+x}

We find that a tetragonal CaBe_2Ge_2-type structure can be stabilized in non-stoichiometric LaPt_{2-x}Ge_{2+x}. We further discovered that tetragonal LaPt_{2-x}Ge_{2+x} with x=0.15 and 0.2 respectively superconduct at Tc=1.85 K and 1.95 K, which is about four time higher than that in monoclinic LaPt_2Ge_2.Comment: 6 pages, 4 figure

Anisotropic spin fluctuations and multiple superconducting gaps in hole-doped Ba_0.7K_0.3Fe_2As_2: NMR in a single crystal

We report the first ^{75}As-NMR study on a single crystal of the hole-doped iron-pnictide superconductor Ba_{0.7}K_{0.3}Fe_2As_{2} (T_c = 31.5 K). We find that the Fe antiferromagnetic spin fluctuations are anisotropic and are weaker compared to underdoped copper-oxides or cobalt-oxide superconductors. The spin lattice relaxation rate 1/T_1 decreases below T_c with no coherence peak and shows a step-wise variation at low temperatures, which is indicative of multiple superconducting gaps, as in the electron-doped Pr(La)FeAsO$_{1-x}$F$_{x}$. Furthermore, no evidence was obtained for a microscopic coexistence of a long-range magnetic and superconductivity

Spin-singlet superconductivity with a full gap in locally non-centrosymmetric SrPtAs

We report $^{195}$Pt-NMR and $^{75}$As-NQR measurements for the locally non-centrosymmetric superconductor SrPtAs where the As-Pt layer breaks inversion symmetry while globally the compound is centrosymmetric. The nuclear spin lattice relaxation rate $1/T_1$ shows a well-defined coherence peak below $T_c$ and decreases exponentially at low temperatures. The spin susceptibility measured by the Knight shift also decreases below $T_c$ down to $T<T_c/6$. These data together with the penetration depth obtained from the NMR spectra can be consistently explained by assuming a spin-singlet superconducting state with a full gap. Our results suggest that the spin-orbit coupling due to the local inversion-breaking is not large enough to bring about an exotic superconducting state, or the inter-layer hopping interaction is larger than the spin-orbit coupling.Comment: 10 pages, 6 figures. Accepted in Phys. Rev. B (Rapid Commun.

Pressure-induced unconventional superconductivity near a quantum critical point in CaFe2As2

75As-zero-field nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements are performed on CaFe2As2 under pressure. At P = 4.7 and 10.8 kbar, the temperature dependences of nuclear-spin-lattice relaxation rate (1/T1) measured in the tetragonal phase show no coherence peak just below Tc(P) and decrease with decreasing temperature. The superconductivity is gapless at P = 4.7 kbar but evolves to that with multiple gaps at P = 10.8 kbar. We find that the superconductivity appears near a quantum critical point under pressures in the range 4.7 kbar < P < 10.8 kbar. Both electron correlation and superconductivity disappear in the collapsed tetragonal phase. A systematic study under pressure indicates that electron correlations play a vital role in forming Cooper pairs in this compound.Comment: 5pages, 5figure

Hydration-induced anisotropic spin fluctuations in Na_{x}CoO_{2}\cdot1.3H_{2}O superconductor

We report ^{59}Co NMR studies in single crystals of cobalt oxide superconductor Na_{0.42}CoO_{2}\cdot1.3H_{2}O (T_c=4.25K) and its parent compound Na_{0.42}CoO_{2}. We find that both the magnitude and the temperature (T) dependence of the Knight shifts are identical in the two compounds above T_c. The spin-lattice relaxation rate (1/T_1) is also identical above T_0 \sim60 K for both compounds. Below T_0, the unhydrated sample is found to be a non-correlated metal that well conforms to Fermi liquid theory, while spin fluctuations develop in the superconductor. These results indicate that water intercalation does not change the density of states but its primary role is to bring about spin fluctuations. Our result shows that, in the hydrated superconducting compound, the in-plane spin fluctuation around finite wave vector is much stronger than that along the c-axis, which indicates that the spin correlation is quasi-two-dimensional.Comment: 4 pages, 5 figure

Pressure dependence of the superconducting transition and electron correlations in Na_xCoO_2 \cdot 1.3H_2O

We report T_c and ^{59}Co nuclear quadrupole resonance (NQR) measurements on the cobalt oxide superconductor Na_{x}CoO_{2}\cdot 1.3H_{2}O (T_c=4.8 K) under hydrostatic pressure (P) up to 2.36 GPa. T_c decreases with increasing pressure at an average rate of -0.49\pm0.09 K/GPa. At low pressures P\leq0.49 GPa, the decrease of T_c is accompanied by a weakening of the spin correlations at a finite wave vector and a reduction of the density of states (DOS) at the Fermi level. At high pressures above 1.93 GPa, however, the decrease of T_c is mainly due to a reduction of the DOS. These results indicate that the electronic/magnetic state of Co is primarily responsible for the superconductivity. The spin-lattice relaxation rate 1/T_1 at P=0.49 GPa shows a T^3 variation below T_c down to T\sim 0.12T_c, which provides compelling evidence for the presence of line nodes in the superconducting gap function.Comment: published on 19, Sept. 2007 on Phys. Rev.

59-Co and 75-As NMR Investigation of Electron-Doped High Tc Superconductor BaFe(1.8)Co(0.2)As(2) (Tc = 22K)

We report an NMR investigation of the superconductivity in BaFe(2)As(2) induced by Co doping (Tc=22K). We demonstrate that Co atoms form an alloy with Fe atoms and donate carriers without creating localized moments. Our finding strongly suggests that the underlying physics of iron-pnictide superconductors is quite different from the widely accepted physical picture of high Tc cuprates as doped Mott insulators. We also show a crossover of electronic properties into a low temperature pseudo-gap phase with a pseudo-gap Delta 560K, where chi(spin) constant and resisitivty T. The NMR Knight shift below Tc decreases for both along the c-axis and ab-plane, and is consistent with the singlet pairing scenario.Comment: Accepted for publication in J. Phys. Soc. Jpn. (4 pages

Multiple superconducting gap and anisotropic spin fluctuations in iron arsenides: Comparison with nickel analog

We present extensive 75As NMR and NQR data on the superconducting arsenides PrFeAs0.89F0.11 (Tc=45 K), LaFeAsO0.92F0.08 (Tc=27 K), LiFeAs (Tc = 17 K) and Ba0.72K0.28Fe2As2 (Tc = 31.5 K) single crystal, and compare with the nickel analog LaNiAsO0.9F0.1 (Tc=4.0 K) . In contrast to LaNiAsO0.9F0.1 where the superconducting gap is shown to be isotropic, the spin lattice relaxation rate 1/T1 in the Fe-arsenides decreases below Tc with no coherence peak and shows a step-wise variation at low temperatures. The Knight shift decreases below Tc and shows a step-wise T variation as well. These results indicate spinsinglet superconductivity with multiple gaps in the Fe-arsenides. The Fe antiferromagnetic spin fluctuations are anisotropic and weaker compared to underdoped copper-oxides or cobalt-oxide superconductors, while there is no significant electron correlations in LaNiAsO0.9F0.1. We will discuss the implications of these results and highlight the importance of the Fermi surface topology.Comment: 6 pages, 11 figure