4-Benzyl-6-bromo-2-(4-methoxy­phen­yl)-4H-imidazo[4,5-b]pyridine monohydrate

The imidazopyridine fused ring in the title compound, C20H16BrN3O·H2O, is coplanar with the aromatic ring at the 2-position [dihedral angle = 5.2 (1)°]. In the five-membered imidazo portion, the C—N bond whose C atom is also connected to the pyridine N atom has predominantly double-bond character [1.334 (2) Å] whereas the C—N bond whose atom is connected to the pyridine C atom has predominantly single-bond character [1.371 (2) Å]. The water mol­ecule engages in hydrogen bonding with the latter N atom; it is also connected to a symmetry-related water mol­ecule, generating a linear chain structure

From ∞1[(UO2)2O(MoO4)4]6− to ∞1[(UO2)2(MoO4)3(MoO5)]6− infinite chains in A6U2Mo4O21 (A=Na, K, Rb, Cs) compounds: Synthesis and crystal structure of Cs6[(UO2)2(MoO4)3(MoO5)]

A new caesium uranyl molybdate belonging to the M6U2Mo4O21 family has been synthesized by solid-state reaction and its structure determined from single-crystal X-ray diffraction data. Contrary to the other alkali uranyl molybdates of this family (A=Na, K, Rb) where molybdenum atoms adopt only tetrahedral coordination and which can be formulated A6[(UO2)2O(MoO4)4], the caesium compound Cs6U2Mo4O21 should be written Cs6[(UO2)2(MoO4)3(MoO5)] with molybdenum atoms in tetrahedral and square pyramidal environments. Cs6[(UO2)2(MoO4)3(MoO5)] crystallizes in the triclinic symmetry with space group P1̄ and a=10.4275(14) Å, b=15.075(2) Å, c=17.806(2) Å, α=70.72(1)°, β=80.38(1)° and γ=86.39(1)°, V=2604.7(6) Å3, Z=4, ρmes=5.02(2) g/cm3 and ρcal=5.08(3) g/cm3. A full-matrix least-squares refinement on the basis of F2 yielded R1=0.0464 and wR2=0.0950 for 596 parameters with 6964 independent reflections with I≥2σ(I) collected on a BRUKER AXS diffractometer with Mo(Kα) radiation and a CCD detector. The crystal structure of Cs compound is characterized by ∞1[(UO2)2(MoO4)3(MoO5)]6− parallels chains built from U2O13 dimeric units, MoO4 tetrahedra and MoO5 square pyramids, whereas, Na, K and Rb compounds are characterized by ∞1[(UO2)2O(MoO4)4]6− parallel chains formulated simply of U2O13 units and MoO4 tetrahedra. Infrared spectroscopy measurements using powdered samples synthesized by solid-state reaction, confirm the structural results. The thermal stability and the electrical conductivity are also studied. The four compounds decompose at low temperature (between 540 and 61

Molten salt flux synthesis and crystal structure of a new open-framework uranyl phosphate Cs3(UO2)2(PO4)O2: Spectroscopic characterization and cationic mobility studies

International audienc