A Search For Supernova Remnants in The Nearby Spiral Galaxy M74 (NGC 628)

We have identified nine new SNR candidates in M74 with [S II]/H$\alpha$ $\geq$ 0.4 as the basic criterion. We obtain [S II]/H$\alpha$ ratio in the range from 0.40 to 0.91 and H$\alpha$ intensities from 2.8 $\times$ $10^{-15}$ erg cm$^{-2}$ s$^{-1}$ to 1.7 $\times$ $10^{-14}$ erg cm$^{-2}$ s$^{-1}$. We also present spectral follow-up observations of the SNR candidates and can confirm only three of them (SNR2, SNR3, and SNR5). The lack of confirmation for the rest might be due to the contamination by the nearby H II emission regions as well as due to the inaccurate positioning of the long slit on these objects. In addition, we search the $Chandra$ Observatory archival data for the X-ray counterparts to the optically identified candidates. We find positional coincidence with only three SNR candidates, SNR1, SNR2, and SNR8. The spectrum of SNR2 yields a shock temperature of 10.8 keV with an ionization timescale of 1.6 $\times$ 10$^{10}$ s cm$^{-3}$ indicating a relatively young remnant in an early Sedov phase which is not supported by our optical wavelength analysis. Given the high luminosity of 10$^{39}$ erg s$^{-1}$ and the characteristics of the X-ray spectrum, we favor an Ultra Luminous X-ray Source interpretation for this source associated with an SNR. We calculate an X-ray flux upper limit of 9.0 $\times$ $10^{-15}$ erg cm$^{-2}$ s$^{-1}$ for the rest of the SNRs including spectroscopically identified SNR3 and SNR5.Comment: 10 pages, 8 figures, accepted to be published in A&

Peptide-Mediated Constructs of Quantum Dot Nanocomposites for Enzymatic Control of Nonradiative Energy Transfer

Cataloged from PDF version of article.A bottom-up approach for constructing colloidal semiconductor quantum dot (QDot) nanocomposites that facilitate nonradiative Forster-type resonance energy transfer (FRET) using polyelectrolyte peptides was proposed and realized. The electrostatic interaction of these polypeptides with altering chain lengths was probed for thermodynamic, structural, and morphological aspects. The resulting nanocomposite film was successfully cut with the protease by digesting the biomimetic peptide layer upon which the QDot assembly was constructed. The ability to control photoluminescence decay lifetime was demonstrated by proteolytic enzyme activity, opening up new possibilities for biosensor applications

White emitting polyfluorene functionalized with azide hybridized on near-UV light emitting diode for high color rendering index

Cataloged from PDF version of article.We develop and demonstrate high-quality white light generation that relies on the use of a single-type simple conjugated polymer of polyfluorene functionalized with azide groups (PFA) integrated on a near-UV LED platform. The high-quality white emission from the polyfluorene is achieved by using the azide functionalization to facilitate cross-linking intentionally when cast into solid-state form. Hybridized on n-UV InGaN/GaN LED at 378 nm, the PFA emitters collectively generate a very broad down-converting photoluminescence at longer wavelengths across the entirety of the visible spectrum, yielding high color rendering indices up to 91. (c) 2008 Optical Society of America

The not-so-massive black hole in the microquasar GRS1915+105

We present a new dynamical study of the black hole X-ray transient GRS1915+105 making use of near-infrared spectroscopy obtained with X-shooter at the VLT. We detect a large number of donor star absorption features across a wide range of wavelengths spanning the H and K bands. Our 24 epochs covering a baseline of over 1 year permit us to determine a new binary ephemeris including a refined orbital period of P=33.85 +/- 0.16 d. The donor star radial velocity curves deliver a significantly improved determination of the donor semi-amplitude which is both accurate (K_2=126 +/- 1 km/s) and robust against choice of donor star template and spectral features used. We furthermore constrain the donor star's rotational broadening to vsini=21 +/-4 km/s, delivering a binary mass ratio of q=0.042 +/- 0.024. If we combine these new constraints with distance and inclination estimates derived from modelling the radio emission, a black hole mass of M_BH=10.1 +/- 0.6 M_sun is inferred, paired with an evolved mass donor of M_2=0.47 +/- 0.27 M_sun. Our analysis suggests a more typical black hole mass for GRS1915+105 rather than the unusually high values derived in the pioneering dynamical study by Greiner et al. (2001). Our data demonstrate that high-resolution infrared spectroscopy of obscured accreting binaries can deliver dynamical mass determinations with a precision on par with optical studies

Observation of Selective Plasmon-Exciton Coupling in Nonradiative Energy Transfer: Donor-Selective versus Acceptor-Selective

Cataloged from PDF version of article.We report selectively plasmon-mediated nonradiative energy transfer between quantum dot (QD) emitters interacting with each other via Forster-type resonance energy transfer (FRET) under controlled plasmon coupling either to only the donor QDs (i.e., donor-selective) or to only the acceptor QDs (i.e., acceptor-selective). Using layer-by-layer assembled colloidal QD nanocrystal solids with metal nanoparticles integrated at carefully designed spacing, we demonstrate the ability to enable/disable the coupled plasmon-exciton (plexciton) formation distinctly at the donor (exciton departing) site or at the acceptor (exciton feeding) site of our choice, while not hindering the donor exciton-acceptor exciton interaction but refraining from simultaneous coupling to both sites of the donor and the acceptor in the FRET process.. In the case of donor-selective plexciton, we observed a substantial shortening in the donor QD lifetime from 1.33 to 0.29 ns as a result of plasmon-coupling to the donors and the FRET-assisted exciton transfer from the donors to the acceptors, both of which shorten the donor lifetime. This consequently enhanced the acceptor emission by a factor of 1.93. On the other hand, in the complimentary case of acceptor-selective plexciton, we observed a 2.70-fold emission enhancement in the acceptor QDs, larger than the acceptor emission enhancement of the donor-selective plexciton, as a result of the combined effects of the acceptor plasmon coupling and the FRET-assisted exciton feeding. Here we present the comparative results of theoretical modeling of the donor- and acceptor-selective plexcitons of nonradiative energy transfer developed here for the first time, which are in excellent agreement with the systematic experimental characterization. Such an ability to modify and control energy transfer through mastering plexcitons is of fundamental importance, opening up new applications for quantum dot embedded plexciton devices along with the development of new techniques in FRET-based fluorescence microscopy

Anisotropic Emission from Multilayered Plasmon Resonator Nanocomposites of Isotropic Semiconductor Quantum Dots

Cataloged from PDF version of article.We propose and demonstrate a nanocomposite localized surface plasmon resonator embedded into an artificial three-dimensional construction. Colloidal semiconductor quantum dots are assembled between layers of metal nanoparticles to create a highly strong plasmon-exciton interaction in the plasmonic cavity. In such a multilayered plasmonic resonator architecture of isotropic CdTe quantum dots, we observed polarized light emission of 80% in the vertical polarization with an enhancement factor of 4.4, resulting in a steady-state anisotropy value of 0.26 and reaching the highest quantum efficiency level of 30% ever reported for such CdTe quantum dot solids. Our electromagnetic simulation results are in good agreement with the experimental characterization data showing a significant emission enhancement in the vertical polarization, for which their fluorescence decay lifetimes are substantially shortened by consecutive replication of our unit cell architecture design. Such strongly plasmon-exciton coupling nanocomposites hold great promise for future exploitation and development of quantum dot plasmonic biophotonics and quantum dot plasmonic optoelectronics

Neutron rich matter, neutron stars, and their crusts

Neutron rich matter is at the heart of many fundamental questions in Nuclear Physics and Astrophysics. What are the high density phases of QCD? Where did the chemical elements come from? What is the structure of many compact and energetic objects in the heavens, and what determines their electromagnetic, neutrino, and gravitational-wave radiations? Moreover, neutron rich matter is being studied with an extraordinary variety of new tools such as Facility for Rare Isotope Beams (FRIB) and the Laser Interferometer Gravitational Wave Observatory (LIGO). We describe the Lead Radius Experiment (PREX) that is using parity violation to measure the neutron radius in 208Pb. This has important implications for neutron stars and their crusts. Using large scale molecular dynamics, we model the formation of solids in both white dwarfs and neutron stars. We find neutron star crust to be the strongest material known, some 10 billion times stronger than steel. It can support mountains on rotating neutron stars large enough to generate detectable gravitational waves. Finally, we describe a new equation of state for supernova and neutron star merger simulations based on the Virial expansion at low densities, and large scale relativistic mean field calculations.Comment: 10 pages, 2 figures, Plenary talk International Nuclear Physics Conference 2010, Vancouver, C

Phase diagram of neutron-rich nuclear matter and its impact on astrophysics

Dense matter as it can be found in core-collapse supernovae and neutron stars is expected to exhibit different phase transitions which impact the matter composition and equation of state, with important consequences on the dynamics of core-collapse supernova explosion and on the structure of neutron stars. In this paper we will address the specific phenomenology of two of such transitions, namely the crust-core solid-liquid transition at sub-saturation density, and the possible strange transition at super-saturation density in the presence of hyperonic degrees of freedom. Concerning the neutron star crust-core phase transition at zero and finite temperature, it will be shown that, as a consequence of the presence of long-range Coulomb interactions, the equivalence of statistical ensembles is violated and a clusterized phase is expected which is not accessible in the grand-canonical ensemble. A specific quasi-particle model will be introduced to illustrate this anomalous thermodynamics and some quantitative results relevant for the supernova dynamics will be shown. The opening of hyperonic degrees of freedom at higher densities corresponding to the neutron stars core modifies the equation of state. The general characteristics and order of phase transitions in this regime will be analyzed in the framework of a self-consistent mean-field approach.Comment: Invited Talk given at the 11th International Conference on Nucleus-Nucleus Collisions (NN2012), San Antonio, Texas, USA, May 27-June 1, 2012. To appear in the NN2012 Proceedings in Journal of Physics: Conference Series (JPCS

A statistical data-based approach to instability detection and wear prediction in radial turning processes

Radial turning forces for tool-life improvements are studied, with the emphasis on predictive rather than preventive maintenance. A tool for wear prediction in various experimental settings of instability is proposed through the application of two statistical approaches to process data on tool-wear during turning processes: three sigma edit rule analysis and Principal Component Analysis (PCA). A Linear Mixed Model (LMM) is applied for wear prediction. These statistical approaches to instability detection generate results of acceptable accuracy for delivering expert opinion. They may be used for on-line monitoring to improve the processing of different materials. The LMM predicted significant differences for tool wear when turning different alloys and with different lubrication systems. It also predicted the degree to which the turning process could be extended while conserving stability. Finally, it should be mentioned that tool force in contact with the material was not considered to be an important input variable for the model.The work was performed as a part of the HIMMOVAL (Grant Agreement Number: 620134) project within the CLEAN-SKY program, linked to the SAGE2 project for geared open-rotor development and the delivery of the demonstrator part. Funding through grant IT900-16 is also acknowledged from the Basque Government Department of Education, Universities and Research

Dual-color emitting quantum-dot-quantum-well CdSe-ZnS heteronanocrystals hybridized on InGaN/GaN light emitting diodes for high-quality white light generation

Cataloged from PDF version of article.We report white light generation by hybridizing green-red emitting (CdSe)ZnS/CdSe (core)shell/shell quantum-dot-quantum-well heteronanocrystals on blue InGaN/GaN light emitting diodes with the photometric properties of tristimulus coordinates (x,y)=(0.36,0.30), luminous efficacy of optical radiation LE=278 lm/W, correlated color temperature CCT=3929 K, and color-rendering index CRI=75.1. We present the photometric analysis and the quantum mechanical design of these dual-color emitting heteronanocrystals synthesized to achieve high-quality white light when hybridized on light emitting diodes. Using such multicolor emitting heteronanocrystals facilitates simple device implementation while providing good photometric properties. (C) 2008 American Institute of Physics