Polyhedral units and network connectivity in calcium aluminosilicate glasses from high-energy x-ray diffraction

Structure factors for Cax/2AlxSi1-xO2 glasses (x=0,0.25,0.5,0.67) extended to a wave vector of magnitude Q= 40 1/A have been obtained by high-energy x-ray diffraction. For the first time, it is possible to resolve the contributions of Si-O, Al-O and Ca-O coordination polyhedra to the experimental atomic pair distribution functions (PDF). It has been found that both Si and Al are four-fold coordinated and so participate in a continuous tetrahedral network at low values of x. The number of network breaking defects in the form of non-bridging oxygens (NBO's) increases slowly with x until x=0.5 (NBO's ~ 10% at x=0.5). By x=0.67 the network breaking defects become significant as evidenced by the significant drop in the average coordination number of Si. By contrast, Al-O tetrahedra remain free of NBO's and fully integrated in the Al/Si-O network for all values of x. Calcium maintains a rather uniform coordination sphere of approximately 5 oxygen atoms for all values of x. The results suggest that not only Si/Al-O tetrahedra but Ca-O polyhedra, too, play a role in determining the glassy structure

Probability for Primordial Black Holes in Multidimensional Universe with Nonlinear Scalar Curvature Terms

We investigate multi-dimensional universe with nonlinear scalar curvature terms to evaluate the probability of creation of primordial black holes. For this we obtain Euclidean instanton solution in two different topologies: (a) $S^{D-1}$ - topology which does not accommodate primordial black holes and (b) $S^1\times S^{D-2}$-topology which accommodates a pair of black holes. The probability for quantum creation of an inflationary universe with a pair of black holes has been evaluated assuming a gravitational action which is described by a polynomial function of scalar curvature with or without a cosmological constant ($\Lambda$) using the framework of semiclassical approximation of Hartle-Hawking boundary conditions. We discuss here a class of new gravitational instantons solution in the $R^4$-theory which are relevant for cosmological model building.Comment: 18 pages, no figure. accepted in Phys. Rev.

Systematic study of deformed nuclei at the drip lines and beyond

An improved prescription for choosing a transformed harmonic oscillator (THO) basis for use in configuration-space Hartree-Fock-Bogoliubov (HFB) calculations is presented. The new HFB+THO framework that follows accurately reproduces the results of coordinate-space HFB calculations for spherical nuclei, including those that are weakly bound. Furthermore, it is fully automated, facilitating its use in systematic investigations of large sets of nuclei throughout the periodic table. As a first application, we have carried out calculations using the Skyrme Force SLy4 and volume pairing, with exact particle number projection following application of the Lipkin-Nogami prescription. Calculations were performed for all even-even nuclei from the proton drip line to the neutron drip line having proton numbers Z=2,4,...,108 and neutron numbers N=2,4,...,188. We focus on nuclei near the neutron drip line and find that there exist numerous particle-bound even-even nuclei (i.e., nuclei with negative Fermi energies) that have at the same time negative two-neutron separation energies. This phenomenon, which was earlier noted for light nuclei, is attributed to bound shape isomers beyond the drip line.Comment: 12 ReVTeX4 pages, 6 EPS figures. See also http://www.fuw.edu.pl/~dobaczew/thodri/thodri.htm

Transition rates and nuclear structure changes in mirror nuclei 47Cr and 47V

Lifetime measurements in the mirror nuclei 47Cr and 47V were performed by means of the Doppler-shift attenuation method using the multidetector array EUROBALL, in conjunction with the ancillary detectors ISIS and the Neutron Wall. The determined transition strengths in the yrast cascades are well described by full pf shell model calculations.Comment: Latex2e, 11 pages, 3 figure

Sum Rule Approach to the Isoscalar Giant Monopole Resonance in Drip Line Nuclei

Using the density-dependent Hartree-Fock approximation and Skyrme forces together with the scaling method and constrained Hartree-Fock calculations, we obtain the average energies of the isoscalar giant monopole resonance. The calculations are done along several isotopic chains from the proton to the neutron drip lines. It is found that while approaching the neutron drip line, the scaled and the constrained energies decrease and the resonance width increases. Similar but smaller effects arise near the proton drip line, although only for the lighter isotopic chains. A qualitatively good agreement is found between our sum rule description and the presently existing random phase approximation results. The ability of the semiclassical approximations of the Thomas-Fermi type, which properly describe the average energy of the isoscalar giant monopole resonance for stable nuclei, to predict average properties for nuclei near the drip lines is also analyzed. We show that when hbar corrections are included, the semiclassical estimates reproduce, on average, the quantal excitation energies of the giant monopole resonance for nuclei with extreme isospin values.Comment: 31 pages, 12 figures, revtex4; some changes in text and figure

Local structure of In_(0.5)Ga_(0.5)As from joint high-resolution and differential pair distribution function analysis

High resolution total and indium differential atomic pair distribution functions (PDFs) for In_(0.5)Ga_(0.5)As alloys have been obtained by high energy and anomalous x-ray diffraction experiments, respectively. The first peak in the total PDF is resolved as a doublet due to the presence of two distinct bond lengths, In-As and Ga-As. The In differential PDF, which involves only atomic pairs containing In, yields chemical specific information and helps ease the structure data interpretation. Both PDFs have been fit with structure models and the way in that the underlying cubic zinc-blende lattice of In_(0.5)Ga_(0.5)As semiconductor alloy distorts locally to accommodate the distinct In-As and Ga-As bond lengths present has been quantified.Comment: 9 pages, 7 figur