1,998 research outputs found

    The GL-l.u.st.\ constant and asymmetry of the Kalton-Peck twisted sum in finite dimensions

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    We prove that the Kalton-Peck twisted sum Z2nZ_2^n of nn-dimensional Hilbert spaces has GL-l.u.st.\ constant of order logn\log n and bounded GL constant. This is the first concrete example which shows different explicit orders of growth in the GL and GL-l.u.st.\ constants. We discuss also the asymmetry constants of Z2nZ_2^n

    Photoelectrochemical reduction of aqueous protons with a CuO|CuBi2O4 heterojunction under visible light irradiation.

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    A p-type heterojunction photoelectrode consisting of platinized CuBi2O4 layered on a CuO film was prepared. The CuO|CuBi2O4|Pt electrode photo-generates H2 in pH neutral aqueous solution during visible light irradiation and exhibits a substantially enhanced photocurrent compared to CuO|Pt and CuBi2O4|Pt electrodes. Reduced electron-hole recombination by the band offsets in the heterostructure is responsible for the improved photoelectrochemical performance of CuO|CuBi2O4 with a small band-gap of approximately 1.5 eV.The work at Cambridge was supported by the Christian Doppler Research Association (Austrian Federal Ministry of Economy, Family and Youth and National Foundation for Research, Technology and Development), the OMV Group the EPSRC (EP/H00338X/2) and BBSRC (BB/K010220/1).This is the accepted manuscript version. The final published version is available from the RSC at http://pubs.rsc.org/en/Content/ArticleLanding/2014/CP/C4CP03883E#!divAbstract

    Harmonically confined, semiflexible polymer in a channel: response to a stretching force and spatial distribution of the endpoints

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    We consider an inextensible, semiflexible polymer or worm-like chain which is confined in the transverse direction by a parabolic potential and subject to a longitudinal force at the ends, so that the polymer is stretched out and backfolding is negligible. Simple analytic expressions for the partition function, valid in this regime, are obtained for chains of arbitrary length with a variety of boundary conditions at the ends. The spatial distribution of the end points or radial distribution function is also analyzed.Comment: 14 pages including figure

    Minimizing magnetic fields for precision experiments

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    An increasing number of measurements in fundamental and applied physics rely on magnetically shielded environments with sub nano-Tesla residual magnetic fields. State of the art magnetically shielded rooms (MSRs) consist of up to seven layers of high permeability materials in combination with highly conductive shields. Proper magnetic equilibration is crucial to obtain such low magnetic fields with small gradients in any MSR. Here we report on a scheme to magnetically equilibrate MSRs with a 10 times reduced duration of the magnetic equilibration sequence and a significantly lower magnetic field with improved homogeneity. For the search of the neutron's electric dipole moment, our finding corresponds to a linear improvement in the systematic reach and a 40 % improvement of the statistical reach of the measurement. However, this versatile procedure can improve the performance of any MSR for any application.Comment: 5 pages, 4 figure

    A simple approach to the correlation of rotovibrational states in four-atomic molecules

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    The problem of correlation between quantum states of four-atomic molecules in different geometrical configurations is reviewed in detail. A general, still simple rule is obtained which allows one to correlate states of a linear four-atomic molecule with those of any kind of non-linear four-atomic molecule.Comment: 16 pages (+8 figures), Postscript (ready to print!

    Staying true with the help of others: doxastic self-control through interpersonal commitment

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    I explore the possibility and rationality of interpersonal mechanisms of doxastic self-control, that is, ways in which individuals can make use of other people in order to get themselves to stick to their beliefs. I look, in particular, at two ways in which people can make interpersonal epistemic commitments, and thereby willingly undertake accountability to others, in order to get themselves to maintain their beliefs in the face of anticipated “epistemic temptations”. The first way is through the avowal of belief, and the second is through the establishment of collective belief. I argue that both of these forms of interpersonal epistemic commitment can function as effective tools for doxastic self-control, and, moreover, that the control they facilitate should not be dismissed as irrational from an epistemic perspective

    Amplified stretch of bottlebrush-coated DNA in nanofluidic channels

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    The effect of a cationic-neutral diblock polypeptide on the conformation of single DNA molecules confined in rectangular nanochannels is investigated with fluorescence microscopy. An enhanced stretch along the channel is observed with increased binding of the cationic block of the polypeptide to DNA. A maximum stretch of 85% of the contour length can be achieved inside a channel with a cross-sectional diameter of 200 nm and at a 2-fold excess of polypeptide with respect to DNA charge. With site-specific fluorescence labelling, it is demonstrated that this maximum stretch is sufficient to map large-scale genomic organization. Monte Carlo computer simulation shows that the amplification of the stretch inside the nanochannels is owing to an increase in bending rigidity and thickness of bottlebrush-coated DNA. The persistence lengths and widths deduced from the nanochannel data agree with what has been estimated from the analysis of atomic force microscopy images of dried complexes on silica.Singapore-MIT Alliance for Research and TechnologyNational Science Foundation (U.S.

    The pre-WDVV ring of physics and its topology

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    We show how a simplicial complex arising from the WDVV (Witten-Dijkgraaf-Verlinde-Verlinde) equations of string theory is the Whitehouse complex. Using discrete Morse theory, we give an elementary proof that the Whitehouse complex Δn\Delta_n is homotopy equivalent to a wedge of (n2)!(n-2)! spheres of dimension n4n-4. We also verify the Cohen-Macaulay property. Additionally, recurrences are given for the face enumeration of the complex and the Hilbert series of the associated pre-WDVV ring.Comment: 13 pages, 4 figures, 2 table

    Statics and dynamics of single DNA molecules confined in nanochannels

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    The successful design of nanofluidic devices for the manipulation of biopolymers requires an understanding of how the predictions of soft condensed matter physics scale with device dimensions. Here we present measurements of DNA extended in nanochannels and show that below a critical width roughly twice the persistence length there is a crossover in the polymer physics
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