STATE TRADING ENTERPRISES AND REVENUE GAINS FROM MARKET POWER: THE CASE OF BARLEY MARKETING AND THE CANADIAN WHEAT BOARD

According to the U.S. General Accounting Office, the Canadian Wheat Board (CWB) is the largest state trading enterprise reporting to the World Trade Organization under article XVII requirements. This study estimates the market power exerted by the CWB in international barley markets. The analysis incorporates international price discrimination across markets for similar types of barley, the intertwining relationships between feed and malting barley markets, and producer behavior in the absence of the CWB. The CWB was able to capture an annual average of $72 million in additional revenue beyond the amount that would have been generated by purely competitive multiple sellers of Canadian barley during the period 1985-94.Marketing,

On the Electronic Spectroscopy of Closed Shell Cations Derived From Resonance Stabilized Radicals: Insights From Theory and Franck-Condon Analysis

Context. Recent attention has been directed on closed-shell aromatic cations as potential carriers of the diffuse interstellar bands. The spectra of mass-selected, matrix-isolated benzylium, and tropylium cations were recently reported. The visible spectrum of benzylium exhibits a large Franck-Condon (FC) envelope, inconsistent with diffuse interstellar band carriers. Aims. We perform a computational analysis of the experimentally studied benzylium spectrum before extending the methods to a range of larger, closed-shell aromatic cations to determine the potential for this class of systems as diffuse interstellar band carriers. Methods. Density functional theory (DFT), time-dependant ((TD)DFT), and multi-configurational self-consistent field second-order perturbation theory (MRPT2) methods in concert with multidimensional FC analysis is used to model the benzylium spectrum. These methods are extended to larger closed-shell aromatic hydrocarbon cations derived from resonance-stabilized radicals, which are predicted to show strong S0 → Sn transitions in the visible region. The ionization energies of a range of these systems are also calculated by DFT. Results. The simulated benzylium spectrum was found to yield excellent agreement with the experimental spectrum showing an extended progression in a low frequency (510 cm-1) ring distortion mode. The FC progression was found to be significantly quenched in the larger species: 1-indanylium, 1-naphthylmethylium, and fluorenium. Excitation and ionization energies of the closed-shell cations were found to be consistent with diffuse interstellar band carriers, with the former lying in the visible range and the latter straddling the Lyman limit in the 13−14 eV range. Conclusions. Large closed-shell polycyclic aromatic hydrocarbon cations remain viable candidate carriers of the diffuse interstellar bands

Getting to know you : "the other" in contemporary British authors : an honors thesis (HONRS 499)

There is no abstract available for this thesis.Honors CollegeThesis (B.?.

Exercise-Induced Glycogen Reduction Increases Muscle Activity

International Journal of Exercise Science 9(3): 336-346, 2016. Intramuscular glycogen stores are an important energy source during extended bouts of strenuous exercise. A substantial reduction in glycogen could influence neural muscular drive and result in a decreasing quality of exercise performance and potentially increased injury rates. The aim of this study was to examine the effect of glycogen reduction on motor drive as determined by the surface electromyogram (EMG) amplitude and median frequency during a cycling graded exercise test. Eight trained cyclists performed a discontinuous cycling graded exercise test to exhaustion under both normal and glycogen reduced conditions. EMG was collected from the vastus lateralis. Repeated measures regression models indicated that EMG amplitudes were elevated at cycling workloads higher than 196 Watts and metabolic workloads higher than 40.8 ml/kg/min, corresponding to 77% VO2max. There was no effect of increases in workload or glycogen reduction on EMG median frequency. Changes in mechanical and metabolic workload had a substantial effect on EMG amplitude (Cohen’s f2 = 0.227 and 0.247, respectively), but not median frequency (Cohen’s f2 = 0.026 and 0.033, respectively). Thus, EMG amplitude is a more effective and reliable measure to examine changes in motor drive during variable workload conditions and metabolic perturbations. The results suggest that healthy glycogen reduced humans require higher levels of muscle activity in order to attain a given mechanical and metabolic workload. This may affect the long term performance of professional and military athletes who need to be able to perform at a high level for extended periods of activity

KIC 9406652: An Unusual Cataclysmic Variable in the Kepler Field of View

KIC 9406652 is a remarkable variable star in the Kepler field of view that shows both very rapid oscillations and long term outbursts in its light curve. We present an analysis of the light curve over quarters 1 to 15 and new spectroscopy that indicates that the object is a cataclysmic variable with an orbital period of 6.108 hours. However, an even stronger signal appears in the light curve periodogram for a shorter period of 5.753 hours, and we argue that this corresponds to the modulation of flux from the hot spot region in a tilted, precessing disk surrounding the white dwarf star. We present a preliminary orbital solution from radial velocity measurements of features from the accretion disk and the photosphere of the companion. We use a Doppler tomography algorithm to reconstruct the disk and companion spectra, and we also consider how these components contribute to the object's spectral energy distribution from ultraviolet to infrared wavelengths. This target offers us a remarkable opportunity to investigate disk processes during the high mass transfer stage of evolution in cataclysmic variables.Comment: 31 pages, 13 figures, accepted for Ap

Exploring Low Internal Reorganization Energies for Silicene Nanoclusters

High-performance materials rely on small reorganization energies to facilitate both charge separation and charge transport. Here, we performed DFT calculations to predict small reorganization energies of rectangular silicene nanoclusters with hydrogen-passivated edges denoted by H-SiNC. We observe that across all geometries, H-SiNCs feature large electron affinities and highly stabilized anionic states, indicating their potential as n-type materials. Our findings suggest that fine-tuning the size of H-SiNCs along the zigzag and armchair directions may permit the design of novel n-type electronic materials and spinctronics devices that incorporate both high electron affinities and very low internal reorganization energies.Comment: 25 pages, 6 figure