The Long Period, Massive Binaries HD 37366 and HD 54662: Potential Targets for Long Baseline Optical Interferometry

We present the results from an optical spectroscopic analysis of the massive stars HD 37366 and HD 54662. We find that HD 37366 is a double-lined spectroscopic binary with a period of 31.8187 +/- 0.0004 days, and HD 54662 is also a double lined binary with a much longer period of 557.8 +/- 0.3 days. The primary of HD 37366 is classified as O9.5 V, and it contributes approximately two-thirds of the optical flux. The less luminous secondary is a broad-lined, early B-type main-sequence star. Tomographic reconstruction of the individual spectra of HD 37366 reveals absorption lines present in each component, enabling us to constrain the nature of the secondary and physical characteristics of both stars. Tomographic reconstruction was not possible for HD 54662; however, we do present mean spectra from our observations that show that the secondary component is approximately half as bright as the primary. The observed spectral energy distributions (SEDs) were fit with model SEDs and galactic reddening curves to determine the angular sizes of the stars. By assuming radii appropriate for their classifications, we determine distance ranges of 1.4 - 1.9 and 1.2 - 1.5 kpc for HD 37366 and HD 54662, respectively.Comment: 27 pages, 8 figures, Accepted for publication in Ap

Radial Velocities of Six OB Stars

We present new results from a radial velocity study of six bright OB stars with little or no prior measurements. One of these, HD 45314, may be a long-period binary, but the velocity variations of this Be star may be related to changes in its circumstellar disk. Significant velocity variations were also found for HD 60848 (possibly related to nonradial pulsations) and HD 61827 (related to wind variations). The other three targets, HD 46150, HD 54879, and HD 206183, are constant velocity objects, but we note that HD 54879 has H$\alpha$ emission that may originate from a binary companion. We illustrate the average red spectrum of each target.Comment: Accepted for publication in PASP July 2007 issu

The N Enrichment and Supernova Ejection of the Runaway Microquasar LS 5039

We present an investigation of new optical and ultraviolet spectra of the mass donor star in the massive X-ray binary LS 5039. The optical band spectral line strengths indicate that the atmosphere is N-rich and C-poor, and we classify the stellar spectrum as type ON6.5 V((f)). The N-strong and C-weak pattern is also found in the stellar wind P Cygni lines of N V 1240 and C IV 1550. We suggest that the N-enrichment may result from internal mixing if the O-star was born as a rapid rotator, or the O-star may have accreted N-rich gas prior to a common-envelope interaction with the progenitor of the supernova. We re-evaluated the orbital elements to find an orbital period of P=4.4267 +/- 0.0010 d. We compared the spectral line profiles with new non-LTE, line-blanketed model spectra, from which we derive an effective temperature T_eff = 37.5 +/- 1.7 kK, gravity log g = 4.0 +/- 0.1, and projected rotational velocity V sin i = 140 +/- 8 km/s. We fit the UV, optical, and IR flux distribution using a model spectrum and extinction law with parameters E(B-V)= 1.28 +/- 0.02 and R= 3.18 +/- 0.07. We confirm the co-variability of the observed X-ray flux and stellar wind mass loss rate derived from the H-alpha profile, which supports the wind accretion scenario for the X-ray production in LS 5039. Wind accretion models indicate that the compact companion has a mass M_X/M_sun = 1.4 +/- 0.4, consistent with its identification as a neutron star. The observed eccentricity and runaway velocity of the binary can only be reconciled if the neutron star received a modest kick velocity due to a slight asymmetry in the supernova explosion (during which >5 solar masses was ejected).Comment: 38 pages, 9 figures; 2004, ApJ, 600, Jan. 10 issue, in press Discussion revised thanks to comments from P. Podsiadlowsk

Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging

Defects and their interactions in crystalline solids often underpin material properties and functionality as they are decisive for stability, result in enhanced diffusion, and act as a reservoir of vacancies. Recently, lithium-rich layered oxides have emerged among the leading candidates for the next-generation energy storage cathode material, delivering 50 % excess capacity over commercially used compounds. Oxygen-redox reactions are believed to be responsible for the excess capacity, however, voltage fading has prevented commercialization of these new materials. Despite extensive research the understanding of the mechanisms underpinning oxygen-redox reactions and voltage fade remain incomplete. Here, using operando three-dimensional Bragg coherent diffractive imaging, we directly observe nucleation of a mobile dislocation network in nanoparticles of lithium-rich layered oxide material. Surprisingly, we find that dislocations form more readily in the lithium-rich layered oxide material as compared with a conventional layered oxide material, suggesting a link between the defects and the anomalously high capacity in lithium-rich layered oxides. The formation of a network of partial dislocations dramatically alters the local lithium environment and contributes to the voltage fade. Based on our findings we design and demonstrate a method to recover the original high voltage functionality. Our findings reveal that the voltage fade in lithium-rich layered oxides is reversible and call for new paradigms for improved design of oxygen-redox active materials

3D printing of twisting and rotational bistable structures with tuning elements

Three-dimensional (3D) printing is ideal for the fabrication of various customized 3D components with fine details and material-design complexities. However, most components fabricated so far have been static structures with fixed shapes and functions. Here we introduce bistability to 3D printing to realize highly-controlled, reconfigurable structures. Particularly, we demonstrate 3D printing of twisting and rotational bistable structures. To this end, we have introduced special joints to construct twisting and rotational structures without post-assembly. Bistability produces a well-defined energy diagram, which is important for precise motion control and reconfigurable structures. Therefore, these bistable structures can be useful for simplified motion control in actuators or for mechanical switches. Moreover, we demonstrate tunable bistable components exploiting shape memory polymers. We can readjust the bistability-energy diagram (barrier height, slope, displacement, symmetry) after printing and achieve tunable bistability. This tunability can significantly increase the use of bistable structures in various 3D-printed components