Climate change, society issues and sustainable agriculture

Despite its prediction 100 years ago by scientists studying CO2, man-made climate change has been officially recognised only in 2007 by the Nobel prize committee. Climate changes since the industrial revolution have already deeply impacted ecosystems. I report major impacts of climate change on waters, terrestrial ecosystems, agriculture, and economy in Europe. The lesson of the climate change story is that humans do not learn from scientists until it really hurts. Furthermore, all society issues cannot be solved anymore using the old, painkiller approach because all issues are now huge, linked, global and fast-developing. In that respect, actual society structures are probably outdated. Here, agronomists are the most advanced scientists to solve society issues because they master the study of complex systems, from the molecule to the global scale. Now more than ever agriculture is a central point to which all society issues are bound. Indeed, humans eat food

Deterministic continutation of stochastic metastable equilibria via Lyapunov equations and ellipsoids

Numerical continuation methods for deterministic dynamical systems have been one of the most successful tools in applied dynamical systems theory. Continuation techniques have been employed in all branches of the natural sciences as well as in engineering to analyze ordinary, partial and delay differential equations. Here we show that the deterministic continuation algorithm for equilibrium points can be extended to track information about metastable equilibrium points of stochastic differential equations (SDEs). We stress that we do not develop a new technical tool but that we combine results and methods from probability theory, dynamical systems, numerical analysis, optimization and control theory into an algorithm that augments classical equilibrium continuation methods. In particular, we use ellipsoids defining regions of high concentration of sample paths. It is shown that these ellipsoids and the distances between them can be efficiently calculated using iterative methods that take advantage of the numerical continuation framework. We apply our method to a bistable neural competition model and a classical predator-prey system. Furthermore, we show how global assumptions on the flow can be incorporated - if they are available - by relating numerical continuation, Kramers' formula and Rayleigh iteration.Comment: 29 pages, 7 figures [Fig.7 reduced in quality due to arXiv size restrictions]; v2 - added Section 9 on Kramers' formula, additional computations, corrected typos, improved explanation

On the nonlocal viscosity kernel of mixtures

In this report we investigate the multiscale hydrodynamical response of a liquid as a function of mixture composition. This is done via a series of molecular dynamics simulations where the wave vector dependent viscosity kernel is computed for three mixtures each with 7-15 different compositions. We observe that the nonlocal viscosity kernel is dependent on composition for simple atomic mixtures for all the wave vectors studied here, however, for a model polymer melt mixture the kernel is independent of composition for large wave vectors. The deviation from ideal mixing is also studied. Here it is shown that a Lennard-Jones mixture follows the ideal mixing rule surprisingly well for a large range of wave vectors, whereas for both the Kob-Andersen mixture and the polymer melt large deviations are found. Furthermore, for the polymer melt the deviation is wave vector dependent such that there exists a critical length scale at which the ideal mixing goes from under-estimating to over-estimating the viscosity

First-principles study on field evaporation for silicon atom on Si(001) surface

The simulations of field-evaporation processes for silicon atoms on various Si(001) surfaces are implemented using the first-principles calculations based on the real-space finite-difference method. We find that the atoms which locate on atomically flat Si(001) surfaces and at step edges are easily removed by applying external electric field, and the threshold value of the external electric field for evaporation of atoms on atomically flat Si(001) surfaces, which is predicted between 3.0 and 3.5 V/\AA, is in agreement with the experimental data of 3.8 V/\AA. In this situation, the local field around an evaporating atom does not play a crucial role. This result is instead interpreted in terms of the bond strength between an evaporating atom and surface.Comment: 5 pages and 4 figure

Asymmetries in the Value of Existence

According to asymmetric comparativism, it is worse for a person to exist with a miserable life than not to exist, but it is not better for a person to exist with a happy life than not to exist. My aim in this paper is to explain how asymmetric comparativism could possibly be true. My account of asymmetric comparativism begins with a different asymmetry, regarding the (dis)value of early death. I offer an account of this early death asymmetry, appealing to the idea of conditional goods, and generalize it to explain how asymmetric comparativism could possibly be true. I also address the objection that asymmetric comparativism has unacceptably antinatalist implications

Dynamics of the condensate in zero-range processes

For stochastic processes leading to condensation, the condensate, once it is formed, performs an ergodic stationary-state motion over the system. We analyse this motion, and especially its characteristic time, for zero-range processes. The characteristic time is found to grow with the system size much faster than the diffusive timescale, but not exponentially fast. This holds both in the mean-field geometry and on finite-dimensional lattices. In the generic situation where the critical mass distribution follows a power law, the characteristic time grows as a power of the system size.Comment: 27 pages, 7 figures. Minor changes and updates performe

Spectroscopy of free radicals and radical containing entrance-channel complexes in superfluid helium nano-droplets

The spectroscopy of free radicals and radical containing entrance-channel complexes embedded in superfluid helium nano-droplets is reviewed. The collection of dopants inside individual droplets in the beam represents a micro-canonical ensemble, and as such each droplet may be considered an isolated cryo-reactor. The unique properties of the droplets, namely their low temperature (0.4 K) and fast cooling rates ($\sim10^{16}$ K s$^{-1}$) provides novel opportunities for the formation and high-resolution studies of molecular complexes containing one or more free radicals. The production methods of radicals are discussed in light of their applicability for embedding the radicals in helium droplets. The spectroscopic studies performed to date on molecular radicals and on entrance / exit-channel complexes of radicals with stable molecules are detailed. The observed complexes provide new information on the potential energy surfaces of several fundamental chemical reactions and on the intermolecular interactions present in open-shell systems. Prospects of further experiments of radicals embedded in helium droplets are discussed, especially the possibilities to prepare and study high-energy structures and their controlled manipulation, as well as the possibility of fundamental physics experiments.Comment: 25 pages, 12 figures, 4 tables (RevTeX

Halfway to doubling of CO2 radiative forcing

The “double CO2” experiment has become a standard experiment in climate science, and a convenient way of comparing the sensitivity of different climate models. Double CO2 was first used by Arrhenius in the 19th century and in the classic paper by Manabe and Wetherald, published 50 years ago, which marked the start of the modern era of climate modeling. Doubling CO2 now has an iconic role in climate research. The equilibrium climate sensitivity (ECS) is defined as the global-mean surface temperature change resulting from a doubling of CO2, which is a headline result in Intergovernmental Panel on Climate Change (IPCC) assessments. In its most recent assessment IPCC concluded that the ECS “is likely in the range 1.5 to 4.5oC”. We show that we are now halfway to doubling of CO2 since pre-industrial times in terms of radiative forcing, but not in concentration

Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics

The atmospheric greenhouse effect, an idea that many authors trace back to the traditional works of Fourier (1824), Tyndall (1861), and Arrhenius (1896), and which is still supported in global climatology, essentially describes a fictitious mechanism, in which a planetary atmosphere acts as a heat pump driven by an environment that is radiatively interacting with but radiatively equilibrated to the atmospheric system. According to the second law of thermodynamics such a planetary machine can never exist. Nevertheless, in almost all texts of global climatology and in a widespread secondary literature it is taken for granted that such mechanism is real and stands on a firm scientific foundation. In this paper the popular conjecture is analyzed and the underlying physical principles are clarified. By showing that (a) there are no common physical laws between the warming phenomenon in glass houses and the fictitious atmospheric greenhouse effects, (b) there are no calculations to determine an average surface temperature of a planet, (c) the frequently mentioned difference of 33 degrees Celsius is a meaningless number calculated wrongly, (d) the formulas of cavity radiation are used inappropriately, (e) the assumption of a radiative balance is unphysical, (f) thermal conductivity and friction must not be set to zero, the atmospheric greenhouse conjecture is falsified.Comment: 115 pages, 32 figures, 13 tables (some typos corrected