Robust ultrafast currents in molecular wires through Stark shifts

A novel way to induce ultrafast currents in molecular wires using two incident laser frequencies, $\omega$ and $2\omega$, is demonstrated. The mechanism relies on Stark shifts, instead of photon absorption, to transfer population to the excited states and exploits the temporal profile of the field to generate phase controllable transport. Calculations in a \emph{trans}-polyacetylene oligomer coupled to metallic leads indicate that the mechanism is highly efficient and robust to ultrafast electronic dephasing processes induced by vibronic couplings.Comment: 4 pages, 2 figures, accepted to Physical Review Letter

Piecewise adiabatic population transfer in a molecule via a wave packet

We propose a class of schemes for robust population transfer between quantum states that utilize trains of coherent pulses and represent a generalized adiabatic passage via a wave packet. We study piecewise Stimulated Raman Adiabatic Passage with pulse-to-pulse amplitude variation, and piecewise chirped Raman passage with pulse-to-pulse phase variation, implemented with an optical frequency comb. In the context of production of ultracold ground-state molecules, we show that with almost no knowledge of the excited potential, robust high-efficiency transfer is possibleComment: 4 pages, 5 figures. Submitted to Phys. Rev. Let

First steps towards total reality of meromorphic functions

It was earlier conjectured by the second and the third authors that any rational curve $g:{\mathbb C}P^1\to {\mathbb C}P^n$ such that the inverse images of all its flattening points lie on the real line ${\mathbb R}P^1\subset {\mathbb C}P^1$ is real algebraic up to a linear fractional transformation of the image ${\mathbb C}P^n$. (By a flattening point $p$ on $g$ we mean a point at which the Frenet $n$-frame $(g',g'',...,g^{(n)})$ is degenerate.) Below we extend this conjecture to the case of meromorphic functions on real algebraic curves of higher genera and settle it for meromorphic functions of degrees $2,3$ and several other cases.Comment: 10 pages, 1 figur

Overlapping Resonances Interference-induced Transparency: The S0→S2/S1S_0 \to S_2/S_1 Photoexcitation Spectrum of Pyrazine

The phenomenon of "overlapping resonances interference-induced transparency" (ORIT) is introduced and studied in detail for the $S_0 \to S_2/S_1$ photoexcitation of cold pyrazine (C$_4$H$_4$N$_2$). In ORIT a molecule becomes transparent at specific wavelengths due to interferences between envelopes of spectral lines displaying overlapping resonances. An example is the $S_2\leftrightarrow S_1$ internal conversion in pyrazine where destructive interference between overlapping resonances causes the $S_0 \to S_2/S_1$ light absorption to disappear at certain wavelengths. ORIT may be of practical importance in multi-component mixtures where it would allow for the selective excitation of some molecules in preference to others. Interference induced cross section enhancement is also shown.Comment: 13 pages, 7 figure