Surface melting of methane and methane film on magnesium oxide

Experiments on surface melting of several organic materials have shown contradictory results. We study the Van der Waals interactions between interfaces in surface melting of the bulk CH_4 and interfacial melting of the CH_4 film on the MgO substrate. This analysis is based on the theory of Dzyaloshinskii, Lifshitz, and Pitaevskii for dispersion forces in materials characterized by the frequency dependent dielectric functions. These functions for magnesium oxide and methane are obtained from optical data using an oscillator model of the dielectric response. The results show that a repulsive interaction between the solid-liquid and liquid-vapor interfaces exists for the bulk methane. We also found that the van der Waals forces between two solid-liquid interfaces are attractive for the CH_4 film on the MgO substrate. This implies that the van der Waals forces induce the presence of complete surface melting for the bulk methane and the absence of interfacial melting for CH_4 on the MgO substrate.Comment: 11 pages, 4 ps figure

Temperature dependence of the Casimir effect between metallic mirrors

We calculate the Casimir force and free energy for plane metallic mirrors at non-zero temperature. Numerical evaluations are given with temperature and conductivity effects treated simultaneously. The results are compared with the approximation where both effects are treated independently and the corrections simply multiplied. The deviation between the exact and approximated results takes the form of a temperature dependent function for which an analytical expression is given. The knowledge of this function allows simple and accurate estimations at the % level.Comment: 8 pages, 4 figures, uses RevTe

Critical Casimir effect and wetting by helium mixtures

We have measured the contact angle of the interface of phase-separated $^{3}$He-$^{4}$He mixtures against a sapphire window. We have found that this angle is finite and does not tend to zero when the temperature approaches $T_t$, the temperature of the tri-critical point. On the contrary, it increases with temperature. This behavior is a remarkable exception to what is generally observed near critical points, i.e. "critical point wetting''. We propose that it is a consequence of the "critical Casimir effect'' which leads to an effective attraction of the $^{3}$He-$^{4}$He interface by the sapphire near $T_{t}$.Comment: submitted july 13 (2002), published march 20 (2003

Onset of Superfluidity in 4He Films Adsorbed on Disordered Substrates

We have studied 4He films adsorbed in two porous glasses, aerogel and Vycor, using high precision torsional oscillator and DC calorimetry techniques. Our investigation focused on the onset of superfluidity at low temperatures as the 4He coverage is increased. Torsional oscillator measurements of the 4He-aerogel system were used to determine the superfluid density of films with transition temperatures as low as 20 mK. Heat capacity measurements of the 4He-Vycor system probed the excitation spectrum of both non-superfluid and superfluid films for temperatures down to 10 mK. Both sets of measurements suggest that the critical coverage for the onset of superfluidity corresponds to a mobility edge in the chemical potential, so that the onset transition is the bosonic analog of a superconductor-insulator transition. The superfluid density measurements, however, are not in agreement with the scaling theory of an onset transition from a gapless, Bose glass phase to a superfluid. The heat capacity measurements show that the non-superfluid phase is better characterized as an insulator with a gap.Comment: 15 pages (RevTex), 21 figures (postscript

Observability of the Bulk Casimir Effect: Can the Dynamical Casimir Effect be Relevant to Sonoluminescence?

The experimental observation of intense light emission by acoustically driven, periodically collapsing bubbles of air in water (sonoluminescence) has yet to receive an adequate explanation. One of the most intriguing ideas is that the conversion of acoustic energy into photons occurs quantum mechanically, through a dynamical version of the Casimir effect. We have argued elsewhere that in the adiabatic approximation, which should be reliable here, Casimir or zero-point energies cannot possibly be large enough to be relevant. (About 10 MeV of energy is released per collapse.) However, there are sufficient subtleties involved that others have come to opposite conclusions. In particular, it has been suggested that bulk energy, that is, simply the naive sum of ${1\over2}\hbar\omega$, which is proportional to the volume, could be relevant. We show that this cannot be the case, based on general principles as well as specific calculations. In the process we further illuminate some of the divergence difficulties that plague Casimir calculations, with an example relevant to the bag model of hadrons.Comment: 13 pages, REVTe

Adsorption Isotherms of Hydrogen: The Role of Thermal Fluctuations

It is shown that experimentally obtained isotherms of adsorption on solid substrates may be completely reconciled with Lifshitz theory when thermal fluctuations are taken into account. This is achieved within the framework of a solid-on-solid model which is solved numerically. Analysis of the fluctuation contributions observed for hydrogen adsorption onto gold substrates allows to determine the surface tension of the free hydrogen film as a function of film thickness. It is found to decrease sharply for film thicknesses below seven atomic layers.Comment: RevTeX manuscript (3 pages output), 3 figure

Observation of the thermal Casimir force

Quantum theory predicts the existence of the Casimir force between macroscopic bodies, due to the zero-point energy of electromagnetic field modes around them. This quantum fluctuation-induced force has been experimentally observed for metallic and semiconducting bodies, although the measurements to date have been unable to clearly settle the question of the correct low-frequency form of the dielectric constant dispersion (the Drude model or the plasma model) to be used for calculating the Casimir forces. At finite temperature a thermal Casimir force, due to thermal, rather than quantum, fluctuations of the electromagnetic field, has been theoretically predicted long ago. Here we report the experimental observation of the thermal Casimir force between two gold plates. We measured the attractive force between a flat and a spherical plate for separations between 0.7 $\mu$m and 7 $\mu$m. An electrostatic force caused by potential patches on the plates' surfaces is included in the analysis. The experimental results are in excellent agreement (reduced $\chi^2$ of 1.04) with the Casimir force calculated using the Drude model, including the T=300 K thermal force, which dominates over the quantum fluctuation-induced force at separations greater than 3 $\mu$m. The plasma model result is excluded in the measured separation range.Comment: 6 page

Identity of the van der Waals Force and the Casimir Effect and the Irrelevance of these Phenomena to Sonoluminescence

We show that the Casimir, or zero-point, energy of a dilute dielectric ball, or of a spherical bubble in a dielectric medium, coincides with the sum of the van der Waals energies between the molecules that make up the medium. That energy, which is finite and repulsive when self-energy and surface effects are removed, may be unambiguously calculated by either dimensional continuation or by zeta function regularization. This physical interpretation of the Casimir energy seems unambiguous evidence that the bulk self-energy cannot be relevant to sonoluminescence.Comment: 7 pages, no figures, REVTe

Quantum vacuum fluctuations

The existence of irreducible field fluctuations in vacuum is an important prediction of quantum theory. These fluctuations have many observable consequences, like the Casimir effect which is now measured with good accuracy and agreement with theory, provided that the latter accounts for differences between real experiments and the ideal situation considered by Casimir. But the vacuum energy density calculated by adding field mode energies is much larger than the density observed around us through gravitational phenomena. This ``vacuum catastrophe'' is one of the unsolved problems at the interface between quantum theory on one hand, inertial and gravitational phenomena on the other hand. It is however possible to put properly formulated questions in the vicinity of this paradox. These questions are directly connected to observable effects bearing upon the principle of relativity of motion in quantum vacuum.Comment: 8 pages, 2 figures, contribution to a special issue in CRAS (Comptes rendus de l'Academie des Sciences), corrected typos, added reference

Decoherence in trapped ions due to polarization of the residual background gas

We investigate the mechanism of damping and heating of trapped ions associated with the polarization of the residual background gas induced by the oscillating ions themselves. Reasoning by analogy with the physics of surface electrons in liquid helium, we demonstrate that the decay of Rabi oscillations observed in experiments on 9Be+ can be attributed to the polarization phenomena investigated here. The measured sensitivity of the damping of Rabi oscillations with respect to the vibrational quantum number of a trapped ion is also predicted in our polarization model.Comment: 26 pdf pages with 5 figures, http://www.df.ufscar.br/~quantum