A Comparison and Analog-Based Analysis of Sinuous Channels on the Rift Aprons of Ascraeus Mons and Pavonis Mons Volcanoes, Mars

The origin of sinuous channels on the flanks of the Tharsis volcanoes on Mars is debated among planetary scientists. Some argue a volcanic genesis [1] while others have suggested a fluvial basis [2-4]. The majority of the studies thus far have focused on channels on the rift apron of Ascraeus Mons. Here, however, we broadly examine the channels on the rift apron of Pavonis Mons and compare them with those studied channels around Ascraeus. We compare the morphologies of features from both of these volcanoes with similar features of known volcanic origin on the island of Hawai i. We show that the morphologies between these two volcanoes in the Tharsis province are very similar and were likely formed by comparable processes, as previous authors have suggested [5]. We show that, although the morphologies of many of the channels around these volcanoes show some parallels to terrestrial fluvial systems, these morphologies can also be formed by volcanic processes. The context of these features suggests that volcanic processes were the more likely cause of these channels

Origin of Sinuous Channels on the SW Apron of Ascraeus Mons and the Surrounding Plains, Mars

Ascraeus Mons is one of three large shield volcanoes located along a NE-SW trending lineament atop the Tharsis Bulge on Mars. Spacecraft images, beginning with Viking in the 1970 s, revealed that the SW rift apron of Ascraeus Mons is cut by numerous sinuous channels, many of which originate from large, elongated, bowl shaped amphitheaters known as the Ascraeus Chasmata. A number of these channels can be traced onto the flatter plains to the east of the rift apron. These features have been interpreted as either fluvial [1] or volcanic [2] in origin. Most recently, it has been shown that one of the longest channels on the Ascraeus rift apron appears to transition into a roofed-over lava channel or lava tube at its distal end, and thus the entire feature is likely of a volcanic origin [2]. In addition, field observations of recent lava flows on Hawaii have shown that lava is capable of producing features such as the complex braided and anastomosing channels and streamlined islands that are observed in the Ascraeus features [2]

Volcanic or Fluvial Channels on Ascraeus Mons: Focus on the Source Area of Sinuous Channels on the Southeast Rift Apron

Deciphering the Mars water history is important to understanding the planet's geological evolution and whether it could have sustained life. Channel features on Mars, such as the features documented in Kasei Valles, are generally accepted as evidence for water flowing over the Mars surface in the past [1]. However, not all channels are the product of fluvial processes and many can be interpreted as having a volcanic origin [2]. This research involves studying channel features on the flanks of the Ascraeus Mons volcano, which is a part of the Tharsis province. Numerous sinuous channels exist on the rift apron of Ascraeus Mons and they have been interpreted as either fluvial [3] or volcanic [4,5]. The channels originate from pits and linear depressions and extend for many 100 s of km downslope. Mapping the proximal to distal morphology of the complete channel and determining its relationship with other features on the apron provides evidence for the processes of formation and their relative temporal relationships. This study focused on sinuous channels located on the south-east part of the Ascraeus rift apron (Fig. 1). Observations of possible analogous features on Hawaii are used to provide insights into the processes of formation of the Mars features

Regio- and Diastereoselective Samarium-Mediated Allylic Sulfone Reductions

A series of allylic sulfones were synthesized containing a stereodirecting group and chelating element and subjected to samarium diiodide reductions in the presence of a proton donor. The resulting products could be obtained with high regioselectivity (no less than 95:5) and high diastereoselectivity (\u3e10:1) that correlated with the size of the stereodirecting group. A mechanism is proposed that includes loss of the sulfone and formation of a chelated organosamarium intermediate followed by intramolecular protonation by a samarium-bound proton source. In this way, both the regioselectivity and absolute stereochemistry of the resulting products are explained

Um estudo da utilização da gestão de custos no suporte ao composto de marketing em empresas varejistas: A study of the use of cost management to support the marketing mix in retail companies

Custos no suporte ao composto de Marketing, traz uma abordagem contemporânea da utilização da gestão de custos nas organizações. O presente artigo trás um estudo da visão que os proprietários e gerentes das empresas do ramo de Vestuário associadas à Associação Comercial e Industrial de Guarapuava – ACIG do município de Guarapuava - Paraná possuem em relação a utilização da ferramenta de gestão “gestão de custos”. A abordagem desse trabalho é em relação a utilização do ferramental de custos quando da aplicação das ferramentas de Marketing, os 4 P’s em sua aplicabilidade nas referidas lojas pesquisadas

Relations between hinterland and foreland shortening: Sevier orogeny, central North American Cordillera

This is the published version. Copyright 2000 American Geophysical Union. All Rights Reserved.The tectonic relations between foreland and hinterland deformation in noncollisional orogens are critical to understanding the overall development of orogens. The classic central Cordilleran foreland fold-and-thrust belt in the United States (Late Jurassic to early Tertiary Sevier belt) and the more internal zones to the west (central Nevada thrust belt) provide data critical to understanding the development of internal and external parts of orogens. The Garden Valley thrust system, part of the central Nevada thrust belt, crops out in south-central Nevada within a region generally considered to be the hinterland of the Jurassic to Eocene Sevier thrust belt. The thrust system consists of at least four principal thrust plates composed of strata as young as Pennsylvanian in age that are unconformably overlain by rocks as old as Oligocene, suggesting that contraction occurred between those times. New U/Pb dates on intrusions that postdate contraction, combined with new paleomagnetic data showing significant tilting of one area prior to intrusion, suggest that regionally these thrusts were active before ∼85–100 Ma. The thrust faults are characterized by long, relatively steeply dipping ramps and associated folds that are broad and open to close, upright and overturned. Although now fragmented by Cenozoic crustal extension, individual thrusts can be correlated from range to range for tens to hundreds of kilometers along strike. We correlate the structurally lowest thrust of the Garden Valley thrust system, the Golden Gate-Mount Irish thrust, southward with the Gass Peak thrust of southern Nevada. This correlation carries the following regional implications. At least some of the slip across Jurassic to mid-Cretaceous foreland thrusts in southern Nevada continues northward along the central Nevada thrust belt rather than northeastward into Utah. This continuation is consistent with age relations, which indicate that thrusts in the type Sevier belt in central Utah are synchronous with or younger than the youngest thrusts in southern Nevada. This in turn implies that geometrically similar Sevier belt thrusts in Utah must die out southward before they reach Nevada, that slip along the southern Nevada thrusts is partitioned between central Nevada and Utah thrusts, or that the Utah thrusts persist into southeastern Nevada but are located east of the longitude of the central Nevada thrust belt. As a result of overall cratonward migration of thrusting, the central Nevada thrust belt probably formed the Cordilleran foreland fold-thrust belt early in the shortening event but later lay in the hinterland of the Sevier fold-thrust belt of Idaho-Wyoming-Utah

Ability of T1 lipase to degrade amorphous P(3HB): structural and functional study

An enzyme with broad substrate specificity would be an asset for industrial application. T1 lipase apparently has the same active site residues as polyhydroxyalkanoates (PHA) depolymerase. Sequences of both enzymes were studied and compared, and a conserved lipase box pentapeptide region around the nucleophilic serine was detected. The alignment of 3-D structures for both enzymes showed their active site residues were well aligned with an RMSD value of 1.981 Å despite their sequence similarity of only 53.8%. Docking of T1 lipase with P(3HB) gave forth high binding energy of 5.4 kcal/mol, with the distance of 4.05 Å between serine hydroxyl (OH) group of TI lipase to the carbonyl carbon of the substrate, similar to the native PhaZ7 Pl . This suggests the possible ability of T1 lipase to bind P(3HB) in its active site. The ability of T1 lipase in degrading amorphous P(3HB) was investigated on 0.2% (w/v) P(3HB) plate. Halo zone was observed around the colony containing the enzyme which confirms that T1 lipase is indeed able to degrade amorphous P(3HB). Results obtained in this study highlight the fact that T1 lipase is a versatile hydrolase enzyme which does not only record triglyceride degradation activity but amorphous P(3HB) degradation activity as well