Crystal structure of barium oxonitridophosphate, Ba3P6O6N8

Ba3N8O6P6, trigonal, P3 (no. 147), a = 7.40227(9) Å, c = 6.3144(1) Å, V = 299.6 Å3, Z = 1, R(I) = 0.008, R(P) = 0.041, T = 297(2) K

Template-free inorganic synthesis of silica-based nanotubes and their self-assembly to mesocrystals

A novel synthesis approach for silica-based nanotubes (NTs) was discovered in the purely inorganic system containing the molecular compounds OP(NH2)3, SP(NH2)3 and SiCl4 in evacuated and sealed silica glass ampoules. Without any solvent or structure directing template the amorphous NTs self-organise to form orthogonally ordered, 3D hyperbranched mesocrystals, exhibiting an interesting material for nanofluidic device applications

Die Gefährdung des runden Fensters bei der CO2-Laser-Parazentese: Eine morphologisch-experimentelle Analyse an 61 humanen Felsenbeinen

Zusammenfassung: Hintergrund: Bei der CO2-Laser-Parazentese wird eine selbstheilende Perforation typischerweise im vorderen unteren Quadranten angelegt. Der vordere untere Quadrant kann durch eine prominente vordere Gehörgangswand verdeckt werden, so dass das Trommelfell im dorsalen Abschnitt perforiert werden muss. In dieser Studie sollte das Schädigungsrisiko für die Membran des runden Fensters (MRF) bei einer Laserapplikation in den dorsalen Trommelfellarealen orientierend abgeschätzt werden. Material und Methoden: An 61 humanen Felsenbeinpräparaten wurde das runde Fenster otomikrochirurgisch präpariert. Bei 25 Präparaten wurde vorher eine CO2-Laser-Parazentese mit doppelter Standardleistung (25W, 180ms, 2,2mm) im hinteren unteren Quadranten und bei 5Präparaten eine Laserapplikation direkt auf die runde Nische durchgeführt und die Wirkung der Laserstrahlung dokumentiert. Anschließend wurde bei allen Felsenbeinen die MRF präparatorisch dargestellt und die Winkelbeziehung der Membran zur Richtung des Laserstrahls digital gemessen. Ergebnisse: In keinem Fall wurde eine Schädigung der MRF durch den Laser beobachtet. Der Winkel zwischen der MRF und äußerem Gehörgang war bei 97% der Felsenbeine unter 30° und hatte damit einen annähernd parallelen Verlauf. Fazit: Die Lokalisation des Fensters kaudodorsal zur Gehörgangswandung, der verdeckende Knochenüberhang über der Membran, die Mukosaduplikaturen sowie die annähernd parallele Ausrichtung der Membran selbst zur Strahlrichtung des Lasers machen ein Erreichen dieser membranösen Struktur mit dem CO2-Laser sehr unwahrscheinlic

Strong (π,0)(\pi,0) spin fluctuations in β\beta-FeSe observed by neutron spectroscopy

We have performed powder inelastic neutron scattering measurements on the unconventional superconductor $\beta$-FeSe ($T_{\rm c} \simeq 8\,\mathrm{K}$). The spectra reveal highly dispersive paramagnetic fluctuations emerging from the square-lattice wave vector $(\pi,0)$ extending beyond 80 meV in energy. Measurements as a function of temperature at an energy of $\sim 13\,\mathrm{meV}$ did not show any variation from $T_{\rm c}$ to $104\,\mathrm{K}$. The results show that FeSe is close to an instability towards $(\pi,0)$ antiferromagnetism characteristic of the parent phases of the high-$T_{\rm c}$ iron arsenide superconductors, and that the iron paramagnetic moment is neither affected by the orthorhombic-to-tetragonal structural transition at $T_{\rm s} \simeq 90\,\mathrm{K}$ nor does it undergo a change in spin state over the temperature range studied.Comment: Revised version, includes Supplementary Materia

Unprecedented Zeolite-Like Framework Topology Constructed from Cages with 3-Rings in a Barium Oxonitridophosphate

A novel oxonitridophosphate, Ba19P36O6+xN66-xCl8+x(x≈4.54), has been synthesized by heating a multicomponent reactant mixture consisting of phosphoryl triamide OP(NH2)3, thiophosphoryl triamide SP(NH2)3, BaS, and NH4Cl enclosed in an evacuated and sealed silica glass ampule up to 750°C. Despite the presence of side phases, the crystal structure was elucidated ab initio from high-resolution synchrotron powder diffraction data (λ=39.998 pm) applying the charge flipping algorithm supported by independent symmetry information derived from electron diffraction (ED) and scanning transmission electron microscopy (STEM). The compound crystallizes in the cubic space group Fm3c (no. 226) with a = 2685.41(3) pm and Z = 8. As confirmed by Rietveld refinement, the structure comprises all-side vertex sharing P(O,N)4 tetrahedra forming slightly distorted 3846812 cages representing a novel composite building unit (CBU). Interlinked through their 4-rings and additional 3-rings, the cages build up a 3D network with a framework density FD = 14.87 T/1000 Å3 and a 3D 8-ring channel system. Ba2+ and Clˉ as extra-framework ions are located within the cages and channels of the framework. The structuralmodel is corroborated by 31P double-quantum(DQ) /single-quantum (SQ) and triple-quantum (TQ) /single-quantum (SQ) 2D correlation MAS NMR spectroscopy. According to 31P{1H} C-REDOR NMR measurements, the H content is less than one H atom per unit cell

Impact of Strain on Drain Current and Threshold Voltage of Nanoscale Double Gate Tunnel Field Effect Transistor: Theoretical Investigation and Analysis

Tunnel field effect transistor (TFET) devices are attractive as they show good scalability and have very low leakage current. However they suffer from low on-current and high threshold voltage. In order to employ the TFET for circuit applications, these problems need to be tackled. In this paper, a novel lateral strained double-gate TFET (SDGTFET) is presented. Using device simulation, we show that the SDGTFET has a higher on-current, low leakage, low threshold voltage, excellent subthreshold slope, and good short channel effects and also meets important ITRS guidelines.Comment: http://web.iitd.ac.in/~mamidal

Intercalation effect on hyperfine parameters of Fe in FeSe superconductor with Tc = 42 K

57Fe-Mossbauer spectra of superconducting beta-FeSe, the Li/NH3 intercalate product and a subsequent sample of this intercalate treated with moist He gas have been measured in temperature range 4.7 - 290 K. A correlation is established between hyperfine parameters and critical temperature Tc in these phases. A strong increase of isomer shift upon intercalation is explained by a charge transfer from the Li/NH3 intercalate to the FeSe layers resulting in an increase of Tc up to 42 K. A significant decrease of the quadrupole splitting above 240 K has been attributed to diffusive motion of Li+ ions within the interlamellar space.Comment: 6 pages, 5 figures, 1 tabl