74 research outputs found
A rigorous implementation of the Jeans--Landau--Teller approximation
Rigorous bounds on the rate of energy exchanges between vibrational and
translational degrees of freedom are established in simple classical models of
diatomic molecules. The results are in agreement with an elementary
approximation introduced by Landau and Teller. The method is perturbative
theory ``beyond all orders'', with diagrammatic techniques (tree expansions) to
organize and manipulate terms, and look for compensations, like in recent
studies on KAM theorem homoclinic splitting.Comment: 23 pages, postscrip
Identification of New Synthetic Cannabinoid ADB-CHMINACA (MAB-CHMINACA) Metabolites in Human Hepatocytes
Adiabatic invariants and trapping of point charge in a strong non-uniform magnetic field
We consider here the classical problem of charge trapping by strong nonuniform magnetic fields (Van Allen belts, magnetic bottles), and study it by means of the averaging methods of classical perturbation theory. At variance with the usual cases, this problem has three (in place of two) different time scales, which are associated to the Larmor rotation around field lines (fast motion), to the motion along field lines (intermediate scale motion), and to the drift across field lines (slow motion). Such time scales get well separated for strong magnetic fields, so that Nekhoroshev-Neishtadt perturbation methods can be applied. As a result, one finds that the system admits two adiabatic invariants (namely, the magnetic moment and a second quantity, related to the energy of the motion along the field lines), which turn out to be preserved for time scales growing exponentially with the field intensity. In fact, the system can be given an integrable form, up to an exponentially small remainder
Exponentially long equilibrium times in a one dimensional collisional model of a classical gas.
Around 1900, J. H. Jeans suggested that the "abnormal" specific heats observed in diatomic gases, specifically the lack of contribution to the heat capacity from the internal vibrational degrees of freedom, in apparent violation of the equipartition theorem, might be caused by the large separation between the time scale for the vibration and the time scale associated with a typical binary collision in the gas. We consider here a simple 1D model and show how, when these time scales are well separated, the collisional dynamics is constrained by a many particle adiabatic invariant. The effect is that the collisional energy exchanges between the translational and the vibrational degrees of freedom are slowed down by an exponential factor (as Jeans conjectured). A metastable situation thus occurs, in which the Fast vibrational degrees of freedom effectively do not contribute to the specific heat. Hence, the observed "freezing out" of the vibrational degrees of freedom could in principle be explained in terms of classical mechanics. We discuss the phenomenon analytically, on the basis of an approximation introduced by Landau and Teller (1936) for a related phenomenon, and estimate the time scale for the evolution to statistical equilibrium. The theoretical analysis is supported by numerical examples
On the Landau--Teller approximation for the energy exchanges with fast degrees of freedom.
We revisit the Landau-Teller heuristic approach to adiabatic invariants and, following Rapp, use it to investigate the energy exchanges between the different degrees of freedom, in simple Hamiltonian systems describing the collision of fast rotating or vibrating molecules with a fixed wall. We critically compare the theoretical results with particularly accurate numerical computations (quite small energy exchanges, namely of one part over 10^{30}, are measured)
Vitalfärbungs- und Fluorochromierungs-Beobachtungen am Vicia faba-Uromyces fabae- Komplex
ASSESSMENT OF DIFFERENT IMAGE TRANSFORMATION METHODS ON DIWATA-1 SMI IMAGES USING STRUCTURAL SIMILARITY MEASURE
Abstract. This paper aims to provide a qualitative assessment of different image transformation parameters as applied on images taken by the spaceborne multispectral imager (SMI) sensor installed in Diwata-1, the Philippines’ first Earth observation microsatellite, with the aim of determining the order of transformation that is sufficient for operationalization purposes. Images of the Palawan area were subjected to different image transformations by manual georeferencing using QGIS 3, and cloud masks generated and applied to remove the effects of clouds. The resulting images were then subjected to structural similarity (SSIM) tests using resampled and cloud masked Landsat 8 images of the same area to generate SSIM indices, which are then used as a quantitative means to assess the best performing transformation. The results of this study point to all transformed images having good SSIM ratings with their Landsat 8 counterparts, indicating that features shown in a Diwata-1 SMI image are structurally similar to the same features in a resampled Landsat 8 data. This implies that for Diwata-1 data processing operationalization purposes, higher order transformations, with the necessary effort to implement them, offer little advantage to lower order counterparts.
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