3,872 research outputs found
Cosmological Consequences of QCD Phase Transition(s) in Early Universe
We discuss the cosmological consequences of QCD phase transition(s) on the
early universe. We argue that our recent knowledge about the transport
properties of quark-gluon plasma (QGP) should throw additional lights on the
actual time evolution of our universe. Understanding the nature of QCD phase
transition(s), which can be studied in lattice gauge theory and verified in
heavy ion experiments, provides an explanation for cosmological phenomenon stem
from early universe.Comment: 8 pages, 2 eps figure
Tautomerization, acidity, basicity, and stability of cyanoform: a computational study
BACKGROUND: Cyanoform is long known as one of the strongest acid. Cyanoform is only stable below −40 °C. The issue of the stability and tautomeric equilibria of cyanoform (CF) are investigated at the DFT and MP2 levels of theory. The present work presents a detailed study of structural tautomer interconversion in three different media, namely, in the gas phase, in a solvent continuum, and in a microhydrated environment where the first solvation layer is described explicitly by one or two water molecule. In all cases, the transition state has been localized and identified. Proton affinities, deprotonation energies and the Raman spectra are reported analyzed and discussed. RESULTS: The 1 tautomer of cyanoform is shown to be more stable than 2 form by only 1.8 and 14.1 kcal/mol in the gas phase using B3LYP/6-311 ++G** and MP2/6-311 ++G** level of theory, respectively. This energy difference is reduced to 0.7 and 13.4 kcal/mol in water as a solvent using CPCM model using B3LYP/6-311 ++G** and MP2/6-311 ++G** level of theory, respectively. The potential energy barrier for this proton transfer process in the gas phase is 77.5 kcal/mol at MP2/6-311 ++G** level of theory. NBO analysis, analysis of the electrostatic potential (ESP) of the charge distribution, donor–acceptor interactions and charge transfer interactions in 1 and 2 are performed and discussed. CONCLUSIONS: Gross solvent continuum effects have but negligible effect on this barrier. Inclusion of one and two water molecules to describe explicitly the first solvation layer, within the supermolecule model, lowers the barrier considerably (29.0 and 7.6 kcal/mol, respectively). Natural bond orbital (NBO) analysis indicated that the stability of the cyanoform arising from charge delocalization. A very good agreement between experimental and theoretical data has been found at MP2/6-311 ++G** for the energies. On other hand, B3LYP/6-311 ++G** level of theory has good agreement with experimental spectra for CF compound. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s13065-016-0166-z) contains supplementary material, which is available to authorized users
Capacity of Reinforced Concrete Structural Elements Retrofitted with GFRP Under Cyclic Loading
Effects of suprathermal electrons on the proton temperature anisotropy in space plasmas: Electromagnetic ion-cyclotron instability
In collision-poor plasmas from space, e.g., the solar wind and planetary
magnetospheres, the kinetic anisotropy of the plasma particles is expected to
be regulated by the kinetic instabilities. Driven by an excess of ion (proton)
temperature perpendicular to the magnetic field , the
electromagnetic ion-cyclotron (EMIC) instability is fast enough to constrain
the proton anisotropy, but the observations do not conform to the instability
thresholds predicted by the standard theory for bi-Maxwellian models of the
plasma particles. This paper presents an extended investigation of the EMIC
instability in the presence of suprathermal electrons which are ubiquitous in
these environments. The analysis is based on the kinetic (Vlasov-Maxwell)
theory assuming that both species, protons and electrons, may be anisotropic,
and the EMIC unstable solutions are derived numerically providing an accurate
description for conditions typically encountered in space plasmas. The effects
of suprathermal populations are triggered by the electron anisotropy and the
temperature contrast between electrons and protons. For certain conditions the
anisotropy thresholds exceed the limits of the proton anisotropy measured in
the solar wind considerably restraining the unstable regimes of the EMIC modes.Comment: Accepted for publication in Astrophysics and space scienc
Experimental behavior of full-scale exterior beam-column space joints retrofitted by ferrocement layers under cyclic loading
A majority of the traditional reinforced concrete frame buildings, existing across the Middle East, lack adequate confinement in beam-column joints, or in other words, are shear deficient because they were constructed before the introduction of seismic codes for construction. This research studies the experimental behavior of full-scale beam-column space (three-dimensional) joints under displacement-controlled cyclic loading. Eleven joint specimens, included a traditionally reinforced one (without adequate shear reinforcement), a reference one with sufficient shear reinforcement according to ACI 318, and nine specimens retrofitted by ferrocement layers, were experimentally tested to evaluate a retrofit technique for strengthening shear deficient beam column joints. The studied variables were the number of layers, orientation angle of expanded wire mesh per layer, and presence of steel angles in the corners of joint specimen prior to wrapping with ferrocement layers. The experimental results showed that proper shear reinforcement for the test joints, according to ACI 318, enhanced the behavior of the specimen over that of the traditionally reinforced specimens without adequate shear reinforcement. The joints retrofitted by ferrocement layers showed higher ultimate capacity, higher ultimate displacement prior to failure (better ductility), and they did not suffer heavily damage as observed for the traditionally reinforced one. Increasing the number of ferrocement layers for retrofitted specimens led to improving performance for such specimens compared to the traditionally reinforced ones in terms of enhancing the ultimate capacity and ultimate displacement. Specimens retrofitted by ferrocement layers reinforced by expanded wire mesh of 60° orientation angle showed slightly better performance than those of 45° orientation angles. Retrofitting using steel angles in addition to ferrocement layers improves the seismic performance of the specimens, achieves better stability for stiffness degradation, attains higher capacity of the dissipated energy, and reduces the vulnerability of joints to excessive damage. Based on the experimental work in this study, it is recommended to retrofit beam-column joint specimens by two ferrocement layers in addition to steel angles as stiffeners taking the orientation angle of expanded wire mesh into consideration. Keywords: Retrofitting, Beam-column space joints, Ferrocement layers, Orientation of expanded wire mesh, Ultimate capacity, Stiffness degradation, Cyclic loading, Shear deficient, Traditionally reinforced building
The Enigma of the Dark Matter
One of the great scientific enigmas still unsolved, the existence of dark
matter, is reviewed. Simple gravitational arguments imply that most of the mass
in the Universe, at least 90%, is some (unknown) non-luminous matter. Some
particle candidates for dark matter are discussed with particular emphasis on
the neutralino, a particle predicted by the supersymmetric extension of the
Standard Model of particle physics. Experiments searching for these relic
particles, carried out by many groups around the world, are also discussed.
These experiments are becoming more sensitive every year and in fact one of the
collaborations claims that the first direct evidence for dark matter has
already been observed.Comment: Invited review article for the journal Contemporary Physics. The
level is suitable for researchers which are non-specialists in the subject,
and also for students. Latex, 20 pages, 5 figure
QFT results for neutrino oscillations and New Physics
The CP asymmetry in neutrino oscillations, assuming new physics at production
and/or detection processes, is analyzed. We compute this CP asymmetry using the
standard quantum field theory within a general new physics scenario that may
generate new sources of CP and flavor violation. Well known results for the CP
asymmetry are reproduced in the case of V -A operators, and additional
contributions from new physics operators are derived. We apply this formalism
to SUSY extensions of the Standard Model where the contributions from new
operators could produce a CP asymmetry observable in the next generation of
neutrino experiments.Comment: 6 pages, 3 figures, version to be published in Phys.Rev.
Behaviour of Rectangular R.C Columns Retrofitted by Fibre Reinforced Polymers Under Axial And Cyclic Loading
Like-sign dimuon charge asymmetry in Randall-Sundurm model
We confirm that in order to account for the recent D\O\ result of large
like-sign dimuon charge asymmetry, a considerable large new physics effect in
is required in addition to a large CP violating phase in mixing. In the Randall-Sundrum model of warped geometry, where the
fermion fields reside in the bulk, new sources of flavor and CP violation are
obtained. We analyze the like-sign dimuon asymmetry in this class of model, as
an example of the desired new physics. We show that the wrong charge asymmetry,
, which is related to the dimuon asymmetry, is significantly altered
compared to the Standard Model value. However, experimental limits from , as well as mixing and electroweak corrections
constrain it to be greater than a away from its experimental average
value. This model cannot fully account for the D\O\ anomaly due to its
inability to generate sufficient new contribution to the width difference
, even though the model can generate large contribution to the
mass difference .Comment: 20 pages, 9 figures, discussions and references added, accepted for
publication in Physical Review
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