Exploration and application of GRACE terrestrial water storage product for hydrologic studies in regional scale

University of Yamanashi (山梨大学)博士(工学)doctoral thesi

Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media.

Hydrogen evolution reaction is an important process in electrochemical energy technologies. Herein, ruthenium and nitrogen codoped carbon nanowires are prepared as effective hydrogen evolution catalysts. The catalytic performance is markedly better than that of commercial platinum catalyst, with an overpotential of only -12 mV to reach the current density of 10 mV cm-2 in 1 M KOH and -47 mV in 0.1 M KOH. Comparisons with control experiments suggest that the remarkable activity is mainly ascribed to individual ruthenium atoms embedded within the carbon matrix, with minimal contributions from ruthenium nanoparticles. Consistent results are obtained in first-principles calculations, where RuCxNy moieties are found to show a much lower hydrogen binding energy than ruthenium nanoparticles, and a lower kinetic barrier for water dissociation than platinum. Among these, RuC2N2 stands out as the most active catalytic center, where both ruthenium and adjacent carbon atoms are the possible active sites

The computational method of substructure’s frequency response function in transfer path analysis

The multi-degree-of-freedom coupled vibration system with “engine-mount-body” as the transfer path was divided into active substructure (engine), passive substructure (body) and linking components (mounts) between active and passive substructure. According to the dynamic equation of multi-degree-of-freedom coupling vibration system, the computational method of the substructure’s Frequency Response Function (FRF) was proposed. For the coupled vibration system of the real vehicle’s transfer path, the computational method of the substructure’s FRF was used to obtain the FRF of substructure and dynamic mount stiffness based on the FRF of system obtained by the hammering test. Combining the dynamic mount stiffness with the vibration acceleration of the active and passive sides of the mount, the operating load was identified based on the mount-stiffness method of the transfer path analysis. Combining the operating load with the FRF of substructure to analyze the contribution of the transfer path, the contribution of each path to the target location (the Z-direction of the front floor of the cab) was presented. The correctness of the computational method of the substructure’s FRF was presented by calculating the vibration isolation ratio of the mount, which provided theoretical support for the research of dynamic characteristics of the substructure and linking components

Development and Interpretation of New Sediment Rating Curve Considering the Effect of Vegetation Cover for Asian Basins

Suspended sediment concentration of a river can provide very important perspective on erosion or soil loss of one river basin ecosystem. The changes of land use and land cover, such as deforestation or afforestation, affect sediment yield process of a catchment through changing the hydrological cycle of the area. A sediment rating curve can describe the average relation between discharge and suspended sediment concentration for a certain location. However, the sediment load of a river is likely to be undersimulated from water discharge using least squares regression of log-transformed variables and the sediment rating curve does not consider temporal changes of vegetation cover. The Normalized Difference Vegetation Index (NDVI) can well be used to analyze the status of the vegetation cover well. Thus long time monthly NDVI data was used to detect vegetation change in the past 19 years in this study. Then monthly suspended sediment concentration and discharge from 1988 to 2006 in Laichau station were used to develop one new sediment rating curve and were validated in other Asian basins. The new sediment model can describe the relationship among sediment yield, streamflow, and vegetation cover, which can be the basis for soil conservation and sustainable ecosystem management

Remote sensing based analysis of recent variations in water resources and vegetation of a semi-arid region

This study is designed to demonstrate use of free remote sensing data to analyze response of water resources and grassland vegetation to a climate change induced prolonged drought in a sparsely gauged semi-arid region. Water resource changes over Hulun Lake region derived from monthly Gravity Recovery and Climate Experiment (GRACE) and Tropical Rainfall Measuring Mission (TRMM) products were analyzed. The Empirical Orthogonal Functions (EOF) analysis results from both GRACE and TRMM showed decreasing trends in water storage changes and precipitation over 2002 to 2007 and increasing trends after 2007 to 2012. Water storage and precipitation changes on the spatial and temporal scale showed a very consistent pattern. Further analysis proved that water storage changes were mainly caused by precipitation and temperature changes in this region. It is found that a large proportion of grassland vegetation recovered to its normal state after above average rainfall in the following years (2008-2012) and only a small proportion of grassland vegetation (16.5% of the study area) is degraded and failed to recover. These degraded grassland vegetation areas are categorized as ecologically vulnerable to climate change and protective strategies should be designed to prevent its further degradation

Attribution analyses of impacts of environmental changes on streamflow and sediment load in a Mountainous basin, Vietnam

Located in the southeastern China and northern Vietnam, the Red River is an important international trans-boundary river that has experienced rapid deforestation and environmental changes over the past decades. We conducted attribution analysis of impacts of various environmental changes on streamflow and sediment load. The contribution of reclassified environmental changes to total change of the streamflow and sediment load was separated. Land cover change based on climate-induced and human-induced indicators were defined. We found that human-induced land cover change was the main factor affecting changes of the streamflow and sediment load. Changes of the land cover were more pronounced in the dry season than in the wet season whereas sediment load changed more in the wet season than in the dry season. In addition, changes in sediment load were mainly caused by human-induced land cover change and the changes of land cover were more influential on sediment load than on streamflow in the Red River basin

Rural drinking water issues in India’s drought-prone area: a case of Maharashtra state

Obtaining sufficient drinking water with acceptable quality under circumstances of lack, such as droughts, is a challenge in drought-prone areas of India. This study examined rural drinking water availability issues during a recent drought (2012) through 22 focus group discussions (FGDs) in a drought-prone catchment of India. Also, a small chemical water quality study was undertaken to evaluate the suitability of water for drinking purpose based on Bureau of Indian Standards (BIS). The drought that began in 2011 and further deteriorated water supplies in 2012 caused a rapid decline in reservoir storages and groundwater levels that led, in turn, to the failure of the public water supply systems in the Upper Bhima Catchment. Dried up and low-yield dug wells and borewells, tanker water deliveries from remote sources, untimely water deliveries, and degraded water quality were the major problems identified in the FGDs. In addition to severe drinking water scarcity during drought, the quality of the drinking water was found to be a major problem, and it apparently was neglected by local governments and users. Severe contamination of the drinking water with nitrate-nitrogen, ammonium-nitrogen, and chlorides was found in the analyzed drinking water samples. Hence, in addition to the water scarcity, the results of this study point to an immediate need to investigate the problem of contaminated drinking water sources while designing relief measures for drought-prone areas of India

The computational method of substructure’s frequency response function in transfer path analysis

The multi-degree-of-freedom coupled vibration system with “engine-mount-body” as the transfer path was divided into active substructure (engine), passive substructure (body) and linking components (mounts) between active and passive substructure. According to the dynamic equation of multi-degree-of-freedom coupling vibration system, the computational method of the substructure’s Frequency Response Function (FRF) was proposed. For the coupled vibration system of the real vehicle’s transfer path, the computational method of the substructure’s FRF was used to obtain the FRF of substructure and dynamic mount stiffness based on the FRF of system obtained by the hammering test. Combining the dynamic mount stiffness with the vibration acceleration of the active and passive sides of the mount, the operating load was identified based on the mount-stiffness method of the transfer path analysis. Combining the operating load with the FRF of substructure to analyze the contribution of the transfer path, the contribution of each path to the target location (the Z-direction of the front floor of the cab) was presented. The correctness of the computational method of the substructure’s FRF was presented by calculating the vibration isolation ratio of the mount, which provided theoretical support for the research of dynamic characteristics of the substructure and linking components.</jats:p