64 research outputs found

    Self Incrimination and the Waiver Thereof

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    Ammonia Production Technologies

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    Molybdenum and Tungsten Carbonyl Compounds Generate Carbonyl Sulfide (COS), but not Carbonyl Selenide (COSe), when Treated with Elemental Sulfur and Selenium

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    Carbonyl sulfide (COS) is implicated in prebiotic chemistry, and recent work on COS/H2S donors has invigorated COS chemistry. We demonstrate that [TpM(CO)3]- (M=Mo,W) react with S8 to form COS, but form [TpW(CO)2]2Se3 not COSe upon reaction with Se. These results advance the metal-mediated interconnectivity of CO and reactive S/Se species

    Molybdenum and Tungsten Carbonyl Compounds Generate Carbonyl Sulfide (COS), but not Carbonyl Selenide (COSe), when Treated with Elemental Sulfur and Selenium

    No full text
    Carbonyl sulfide (COS) is implicated in prebiotic chemistry, and recent work on COS/H2S donors has invigorated COS chemistry. We demonstrate that [TpM(CO)3]- (M=Mo,W) react with S8 to form COS, but form [TpW(CO)2]2Se3 not COSe upon reaction with Se. These results advance the metal-mediated interconnectivity of CO and reactive S/Se species.</jats:p

    Reversible Coordination of H<sub>2</sub> by a Distannyne

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