Moisture absorption and diffusivity of epoxy filled layered-structure nanocomposite

This paper studies moisture absorption and diffusivity of epoxy reinforced layered structure nanocomposites and its effect on fracture toughness. Two different types of layered fillers employed in the study were clay and graphene platelets, in which both surface layers were unmodified and modified by characterized by swelling analysis and fracture toughness measurement. The outcomes surfactant. The nanocomposites were showed that the moisture absorption and diffusivity decreased with the addition of layered fillers. It was found that the modified graphene platelets and clay outperformed the unmodified layers and neat epoxy in terms of reduction of moisture absorption and diffusivity. The modified graphene platelets reduced the moisture uptake and diffusivity about 30% and 33%, respectively compare to neat epoxy, thus indicates its outstanding performance in barrier applications. However, once the nanocomposites were swelling in the water for 5 days, it is noticed that the fracture toughness of nanocomposites were reduced significantly about 35% in average. Nevertheless, the modified graphene platelets still display the better performance compare to the other samples although there was reduction of fracture toughness

From clay to graphene for polymer nanocomposites-a survey

The development of aerospace and automotive in- dustries requests lightweight, high-performance materials, and polymer nanocomposites are ideal candidates in this case, which is shown by the increasingly more publications in this research field over the past two decades. However, the perfor- mance of nanocomposite not only depend on the properties of their individual constituents, but on their morphology and surface characteristics of fillers as well. Selections of nanofillers geometries, e.g. particulate, fibrous or layered have a tremendous influence on the properties of nanocomposites and their processing methods. In this paper, we review the chronological works performed in the field of polymer nano- composites, in particular epoxy nanocomposites reinforced with layered fillers, such as clay and graphene. Surprisingly layered fillers are commercially available and more cost- effective than nanoparticles and carbon nanofibres, and these make them to the most extensively studied fillers that can be geared toward future applications, particularly in large-scale polymer nanocomposite production

From clay to graphene for polymer nanocomposites-a survey

The development of aerospace and automotive in- dustries requests lightweight, high-performance materials, and polymer nanocomposites are ideal candidates in this case, which is shown by the increasingly more publications in this research field over the past two decades. However, the perfor- mance of nanocomposite not only depend on the properties of their individual constituents, but on their morphology and surface characteristics of fillers as well. Selections of nanofillers geometries, e.g. particulate, fibrous or layered have a tremendous influence on the properties of nanocomposites and their processing methods. In this paper, we review the chronological works performed in the field of polymer nano- composites, in particular epoxy nanocomposites reinforced with layered fillers, such as clay and graphene. Surprisingly layered fillers are commercially available and more cost- effective than nanoparticles and carbon nanofibres, and these make them to the most extensively studied fillers that can be geared toward future applications, particularly in large-scale polymer nanocomposite production

Melt compounding with graphene to develop functional, high-performance elastomers

Rather than using graphene oxide, which is limited by a high defect concentration and cost due to oxidation and reduction, we adopted cost-effective, 3.56 nm thick graphene platelets (GnPs) of high structural integrity to melt compound with an elastomer—ethylene–propylene–diene monomer rubber (EPDM)—using an industrial facility. An elastomer is an amorphous, chemically crosslinked polymer generally having rather low modulus and fracture strength but high fracture strain in comparison with other materials; and upon removal of loading, it is able to return to its original geometry, immediately and completely. It was found that most GnPs dispersed uniformly in the elastomer matrix, although some did form clusters. A percolation threshold of electrical conductivity at 18 vol% GnPs was observed and the elastomer thermal conductivity increased by 417% at 45 vol% GnPs. The modulus and tensile strength increased by 710% and 404% at 26.7 vol% GnPs, respectively. The modulus improvement agrees well with the Guth and Halpin-Tsai models. The reinforcing effect of GnPs was compared with silicate layers and carbon nanotube. Our simple fabrication would prolong the service life of elastomeric products used in dynamic loading, thus reducing thermosetting waste in the environment

Melt compounding with graphene to develop functional, high-performance elastomers

Rather than using graphene oxide, which is limited by a high defect concentration and cost due to oxidation and reduction, we adopted cost-effective, 3.56 nm thick graphene platelets (GnPs) of high structural integrity to melt compound with an elastomer—ethylene–propylene–diene monomer rubber (EPDM)—using an industrial facility. An elastomer is an amorphous, chemically crosslinked polymer generally having rather low modulus and fracture strength but high fracture strain in comparison with other materials; and upon removal of loading, it is able to return to its original geometry, immediately and completely. It was found that most GnPs dispersed uniformly in the elastomer matrix, although some did form clusters. A percolation threshold of electrical conductivity at 18 vol% GnPs was observed and the elastomer thermal conductivity increased by 417% at 45 vol% GnPs. The modulus and tensile strength increased by 710% and 404% at 26.7 vol% GnPs, respectively. The modulus improvement agrees well with the Guth and Halpin-Tsai models. The reinforcing effect of GnPs was compared with silicate layers and carbon nanotube. Our simple fabrication would prolong the service life of elastomeric products used in dynamic loading, thus reducing thermosetting waste in the environment

A facile approach to fabricate highly sensitive, flexible strain sensor based on elastomeric/graphene platelet composite film

This work developed a facile approach to fabricate highly sensitive and flexible polyurethane/graphene platelets composite film for wearable strain sensor. The composite film was fabricated via layer-by-layer laminating method which is simple and cost-effective; it exhibited outstanding electrical conductivity of 1430 ± 50 S/cm and high sensitivity to strain (the gauge factor is up to 150). In the sensor application test, the flexible strain sensor achieves real-time monitoring accurately for five bio-signals such as pulse movement, finger movement, and cheek movement giving a great potential as wearable-sensing device. In addition, the developed strain sensor shows response to pressure and temperature in a certain region. A multifaceted comparison between reported flexible strain sensors and our strain sensor was made highlighting the advantages of the current work in terms of (1) high sensitivity (gauge factor) and flexibility, (2) facile approach of fabrication, and (3) accurate monitoring for body motions

Market Integration Shape Organic Farmers’ Organisation

Increasing consumption of organic products in globalised food chains will require the involvement of thousands more smallholder farmers in many regions of the world. A study of Egypt, China and Uganda identified the three key factors of property rights regimes, cultural differences and social organisation as determents of the supply chain organization and farmers’ degree of direct integration in the export markets. Patterns are emerging where smallholder farmers are being socially and economically linked to larger farmers who may do some processing before the raw materials are handed over to the contracting company. Where transactions costs are high, local communities may develop and contract out the land directly to exporting companies who farm using employees. Four organisational patterns are identified which each leads to different types of livelihood benefits for the producers; preliminary results indicate that income and a reliable market access is the dominant benefits

Interface modification of clay and graphene platelets reinforced epoxy nanocomposites: a comparative study

The interface between the matrix phase and dispersed phase of a composite plays a critical role in influencing its properties. However, the intricate mecha-nisms of interface are not fully understood, and polymer nanocomposites are no exception. This study compares the fabrication, morphology, and mechanical and thermal properties of epoxy nanocomposites tuned by clay layers (denoted as m-clay) and graphene platelets (denoted as m-GP). It was found that a chemical modification, layer expansion and dispersion of filler within the epoxy matrix resulted in an improved interface between the filler mate-rial and epoxy matrix. This was confirmed by Fourier transform infrared spectroscopy and transmission electron microscope. The enhanced interface led to improved mechanical properties (i.e. stiffness modulus, fracture toughness) and higher glass transition temperatures (Tg) compared with neat epoxy. At 4 wt% m-GP, the critical strain energy release rate G1c of neat epoxy improved by 240 % from 179.1 to 608.6 J/m2 and Tg increased from 93.7 to 106.4 �C. In contrast to m-clay, which at 4 wt%, only improved the G1c by 45 % and Tg by 7.1 %. The higher level of improvement offered by m-GP is attributed to the strong interaction of graphene sheets with epoxy because the covalent bonds between the carbon atoms of graphene sheets are much stronger than silicon-based clay

Fatigue behavior and tribological properties of laser additive manufactured aluminum alloy/boron nitride nanosheet nanocomposites

Laser additive manufacturing is a promising approach to prepare near-neat shape parts from Al nanocomposites with high mechanical and tribological properties. Owing to its lubricious nature, boron nitride nanosheets (BNNSs) were added into AlSi10Mg alloy via high-speed ball milling and laser metal deposition (LMD) to manufacture self-lubricating Al alloy nanocomposites with outstanding wear resistance and fatigue performance. The study shows that number of cycles-to-failure due to tensile fatigue increased from 103 for pure AlSi10Mg to 106 upon adding only 0.1 wt% of BNNSs. At 0.2 wt% BNNSs, the friction coefficient and wear-out volume of AlSi10Mg alloy decrease by 58% and 57%, respectively. Scanning electron microscopy micrographs show that pure AlSi10Mg has a worn surface of grooves, wide ridges, debris and large protrusions of worn material along the groove edges. The wear mechanism is mainly plastic deformation, delamination and adhesion in pure AlSi10Mg. On the other hand, the LMD-built AlSi10Mg/BNNS composites exhibit less rough surface with clear wear trails due to the thin lubricant layer formed from the extruded BNNSs during the test. An extended finite element model for the crack propagation during fatigue testing is developed, where the obtained results are in accord with the experimental measurements. The present study shows that additive manufacturing technology is capable to fabricate Al matrix composites with tailored properties for various design applications

Organic Food and Farming in Egypt

Description of the organic Food and farm sector in Egypt, production and farmstructure, historical development, institutional set-up, certificiers, market trends for the domestic as well as export and future prospects for growth