2,812 research outputs found
Elimination of the Translational Kinetic Energy Contamination in pre-Born-Oppenheimer Calculations
In this paper we present a simple strategy for the elimination of the
translational kinetic energy contamination of the total energy in
pre-Born--Oppenheimer calculations carried out in laboratory-fixed Cartesian
coordinates (LFCCs). The simple expressions for the coordinates and the
operators are thus preserved throughout the calculations, while the
mathematical form and the parametrisation of the basis functions are chosen so
that the translational and rotational invariances are respected. The basis
functions are constructed using explicitly correlated Gaussian functions (ECGs)
and the global vector representation. First, we observe that it is not possible
to parametrise the ECGs so that the system is at rest in LFCCs and at the same
time the basis functions are square-integrable with a non-vanishing norm. Then,
we work out a practical strategy to circumvent this problem by making use of
the properties of the linear transformation between the LFCCs and
translationally invariant and center-of-mass Cartesian coordinates as well as
the transformation properties of the corresponding basis function parameter
matrices. By exploiting these formal mathematical relationships we can identify
and separate the translational contamination terms in the matrix representation
of the kinetic energy operator in the LFCC formalism. We present numerical
examples for the translational contamination and its elimination for the two
lowest rotational energy levels of the singlet hydrogen molecule, corresponding
to para- and ortho-H2, respectively, treated as four-particle quantum systems
Breathing straws
Following nasal, septal or endoscopic surgery, it is common practice to insert nasal packs in both nasal cavities to achieve haemostasis, if there has been any bleeding at the end of the procedure. However, such packs make it difficult for patients to breathe, mainly in the first post-operative night which leads to discomfort and poor sleep. To enable patients to breathe better with nasal packs in situ, we describe a simple technique using trimmed straws and wrapped Netcell® packs for post-operative care following septal surgery, rhinoplasty and endoscopic sinus surgery. These packs also assist suction of any blood or mucous from the post-nasal spac
Perforatationstrauma im Gesichtsschädel: Eine ungewöhnliche Verletzung beim Skifahren
Zusammenfassung: Pfählungsverletzungen am Kopf und im Gesicht sind selten. Wir berichten über den Fall eines 48-jährigen Patienten, der sich beim Skifahren eine Pfählungsverletzung des Gesichtschädels mit einem 11cm langen Ast zugezogen hatte. Der Patient präsentierte sich bei der Einlieferung in die Klinik neurologisch unauffällig und kreislaufstabil. In den CT-Untersuchungen des Kopfs konnten Frakturen im Gesichtschädel und ein 11cm langer Fremdkörper, ausgehend vom Sinus maxillaris durch den Gesichtschädel bis paravertebral reichend, ohne Verletzung von Gefäßen nachgewiesen werden. Zusätzlich zog sich der Patient Frakturen an der Hand und an den Rippen zu. Er wurde in ein Zentrum für Kiefer- und Gesichtschirurgie verlegt, mehrfach operiert und konnte 8Monate nach dem Unfall wieder in sein gewohntes privates und berufliches Leben zurückkehre
Focal neuromyotonia: do I love you?
We present a rare case of focal neuromyotonia in a 73-year-old woman with a follow up of 5years. The clinical picture showed a fixed contraction of the 3rd and 4th finger of the left hand. Similar to other published cases, our patient suffered from COPD and was treated with beta-2-sympathomimetics. This clinical picture shows a rare but rather salient differential diagnosis of Dupuytren's contracture. EMG of the affected muscles may yield a diagnosis and prevent the patient from a long and ineffective treatment "odyssey
Tracking the evolution of multiple in vitro HCV replicon mutants under protease inhibitor selection pressure by 454 ultra deep sequencing.
Perforatationstrauma im Gesichtsschädel. Eine ungewöhnliche Verletzung beim Skifahren
Facial perforation injuries are very rare. We describe a case of a 48-year-old man who sustained a perforation trauma from an 11 cm long wooden tree branch in the middle of the face in a skiing accident. He suffered from additional injuries, such as fractures of the ribs and hand, but was neurologically without pathologic findings and was cardiopulmonary stable.The branch penetrated the head from the sinus maxillaris through the maxilla just missing the internal and external carotid arteries and ending just short of the cervical vertebra. The patient was transported to a center for oral and maxillofacial surgery and underwent several operations.He could return to his normal social and professional life 8 months after the accident
Minimal-invasive, ballonassistierte Aufrichtung und innere Fixation von Tibiaplateaufrakturen
Zusammenfassung: Aufgrund der häufig insuffizienten Weichteilsituation im Rahmen von Tibiaplateaufrakturen und der damit assoziierten höheren Rate an postoperativen Wundheilungsstörungen und Weichteilinfektionen ist ihre operative Behandlung nicht selten eine herausfordernde Aufgabe. Die klassische offene Reposition und Plattenosteosynthese beinhaltet eine ausgiebige Weichteilpräparation und partielle Periostablösung, um so die abgesunkenen Fragmente zu bergen und aufzurichten. Die Wiederherstellung der Gelenkfläche gestaltet sich dabei häufig als schwierig. In der vorliegenden Arbeit beschreiben wir eine neuartige operative Technik, in der das eingesunkene Tibiaplateau durch einen perkutan eingebrachten Ballon in Kombination mit einer minimal-invasiven Plattenosteosynthese versorgt wird. Darüber hinaus berichten wir über 5Fälle, welche mit diesem Verfahren bislang behandelt wurde
Asymptotic Level Density of the Elastic Net Self-Organizing Feature Map
Whileas the Kohonen Self Organizing Map shows an asymptotic level density
following a power law with a magnification exponent 2/3, it would be desired to
have an exponent 1 in order to provide optimal mapping in the sense of
information theory. In this paper, we study analytically and numerically the
magnification behaviour of the Elastic Net algorithm as a model for
self-organizing feature maps. In contrast to the Kohonen map the Elastic Net
shows no power law, but for onedimensional maps nevertheless the density
follows an universal magnification law, i.e. depends on the local stimulus
density only and is independent on position and decouples from the stimulus
density at other positions.Comment: 8 pages, 10 figures. Link to publisher under
http://link.springer.de/link/service/series/0558/bibs/2415/24150939.ht
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