Phenomenological model for charge dynamics and optical response of disordered systems: application to organic semiconductors

We provide a phenomenological formula which describes the low-frequency optical absorption of charge carriers in disordered systems with localization. This allows to extract, from experimental data on the optical conductivity, the relevant microscopic parameters determining the transport properties, such as the carrier localization length and the elastic and inelastic scattering times. This general formula is tested and applied here to organic semiconductors, where dynamical molecular disorder is known to play a key role in the transport properties. The present treatment captures the basic ideas underlying the recently proposed transient localization scenario for charge transport, extending it from the d.c. mobility to the frequency domain. When applied to existing optical measurements in rubrene FETs, our analysis provides quantitative evidence for the transient localization phenomenon. Possible applications to other disordered electronic systems are briefly discussed.Comment: extended version with optical conductivity formulas for both non-degenerate and degenerate electron system

Avoiding Stripe Order: Emergence of the Supercooled Electron Liquid

In the absence of disorder, electrons can display glassy behavior through supercooling the liquid state, avoiding the solidification into a charge ordered state. Such supercooled electron liquids are experimentally found in organic $\theta$-$MM'$ compounds. We present theoretical results that qualitatively capture the experimental findings. At intermediate temperatures, the conducting state crosses over into a weakly insulating pseudogap phase. The stripe order phase transition is first order, so that the liquid phase is metastable below $T_s$. In the supercooled liquid phase the resistivity increases further and the density of states at the Fermi level is suppressed, indicating kinetic arrest and the formation of a glassy state. Our results are obtained using classical Extended Dynamical Mean Field Theory.Comment: 4 pages, 4 figures, submitted to the proceedings of "Superstripes 2015", Journal of Superconductivity and Novel Magnetism (2015

Emergent heavy fermion behavior at the Wigner-Mott transition

We study charge ordering driven by Coulomb interactions on triangular lattices relevant to the Wigner-Mott transition in two dimensions. Dynamical mean-field theory reveals the pinball liquid phase, a charge ordered metallic phase containing quasilocalized (pins) coexisting with itinerant (balls) electrons. Based on an effective periodic Anderson model for this phase, we find an antiferromagnetic Kondo coupling between pins and balls and strong quasiparticle renormalization. Non-Fermi liquid behavior can occur in such charge ordered systems due to the spin-flip scattering of itinerant electrons off the pins in analogy with heavy fermion compoundsJ. M. acknowledges financial support from MINECO (MAT2012-37263-C02-01). This work is supported by the French National Research Agency through Grant No. ANR-12-JS04-0003-01 SUBRISSYM

Glassy dynamics in geometrically frustrated Coulomb liquids without disorder

We show that introducing long-range Coulomb interactions immediately lifts the massive ground state degeneracy induced by geometric frustration for electrons on quarter-filled triangular lattices in the classical limit. Important consequences include the stabilization of a stripe-ordered crystalline (global) ground state, but also the emergence of very many low-lying metastable states with amorphous "stripe-glass" spatial structures. Melting of the stripe order thus leads to a frustrated Coulomb liquid at intermediate temperatures, showing remarkably slow (viscous) dynamics, with very long relaxation times growing in Arrhenius fashion upon cooling, as typical of strong glass formers. On shorter time scales, the system falls out of equilibrium and displays the aging phenomena characteristic of supercooled liquids above the glass transition. Our results show remarkable similarity with the recent observations of charge-glass behavior in ultra-clean triangular organic materials of the $\theta$-(BEDT-TTF)$_2$ family.Comment: 5 pages,4 figure

Impact of quantized vibrations on the efficiency of interfacial charge separation in photovoltaic devices

We demonstrate that charge separation at donor-acceptor interfaces is a complex process that is controlled by the combined action of Coulomb binding for electron-hole pairs and partial relaxation due to quantized phonons. A joint electron-vibration quantum dynamical study reveals that high energy vibrations sensitively tune the charge transfer probability as a function of time and injection energy, due to polaron formation. These results have bearings for the optimization of energy transfer both in organic and quantum dot photovoltaics, as well as in biological light harvesting complexes.Comment: 5 pages, 3 figures. v2 contains additional discussion of experiments, and extra physical motivatio

Supporting Increment Planning Processes within the ULISSE Framework

ULISSE is an EU project whose aim is data valorization around the ISS experiments. The ULISSE software platform is endowed with a number of additional services to improve both data production and data analysis. This paper describes the Planning and Scheduling Service, a module developed to support functions of data production around the ISS activities and integrated in the ULISSE platform. Its current use to support work for the Fluid Science Laboratory facility is also shown and fully analyzed from design to application service delivery

Enriching APSI with Validation Capabilities: the KEEN environment and its use in Robotics

This paper presents the KnowledgE ENgineering (KEEN) design support system in which Validation and Verification (V&V) methods are used to strengthen onground development of software for plan-based autonomy. In particular, the paper describes a collection of verification methods, based on Timed Game Automata (TGA), deployed for the design and development of timeline-based Planning and Scheduling (P&S) applications within the APSI-TRF framework. The KEENs V&V functionalities are illustrated describing software development to synthesize plans for a planetary rover

Continuous Planning and Execution with Timelines

Planning systems need to be endowed with some additional features to cope effectively with execution: e.g., the ability to keep the plan database updated with respect to the actual feedbacks provided by the controlled system, to mention but one. In this paper, we identify a set of noteworthy planning and execution open issues relatively to the timeline-based planning approach. We address those issues presenting a domain independent deliberative system, implemented on top of the APSI-TRF, the A PSI Timeline-based Representation Framework, extended with timeline dispatching and execution-supervision capabilities so as to allow continuous planning and closed-loop re-planning activities. Some ongoing research directions are also briefly introduced

APSI-based Deliberation in Goal Oriented Autonomous Controllers

This paper describes a timeline-based, domain independent deliberative layer, based on E SA APSI technology, deployed in the context of the Goal Oriented Autonomous Controller (G OAC) project. In particular the paper describes a new controller composed by (1) a planning module that exploits the timeline-based approach provided by the APSI - TRF and is able to model and solve planning problems, (2) a module that dispatches planned timelines, supervises their execution status and entails continuous planning and re-planning. An example will illustrate both modules at work

Strange metal behavior from incoherent carriers scattered by local moments

We study metallic transport in an effective model that describes the coupling of electrons to fluctuating magnetic moments with full SU(2) symmetry, exhibiting characteristic behavior of metals at the approach of the Mott transition. We show that scattering by fluctuating local moments causes a fully incoherent regime of electron transport with linear T-dependent resistivities. This strange metal regime is characterized by almost universal, "Planckian" slope and a finite intercept at $T=0$, that we can associate respectively to the fluctuations in orientation and amplitude of the local moments. Our results indicate a route for understanding the microscopic origin of strange metal behavior that is unrelated to quantum criticality and does not rely on the existence of quasiparticles.Comment: 5 pages, 3 figure