Modeling elastic wave propagation in fluid-filled boreholes drilled in nonhomogeneous media: BEM – MLPG versus BEM-FEM coupling

The efficiency of two coupling formulations, the boundary element method (BEM)-meshless local Petrov–Galerkin (MLPG) versus the BEM-finite element method (FEM), used to simulate the elastic wave propagation in fluid-filled boreholes generated by a blast load, is compared. The longitudinal geometry is assumed to be invariant in the axial direction (2.5D formulation). The material properties in the vicinity of the borehole are assumed to be nonhomogeneous as a result of the construction process and the ageing of the material. In both models, the BEM is used to tackle the propagation within the fluid domain inside the borehole and the unbounded homogeneous domain. The MLPG and the FEM are used to simulate the confined, damaged, nonhomogeneous, surrounding borehole, thus utilizing the advantages of these methods in modeling nonhomogeneous bounded media. In both numerical techniques the coupling is accomplished directly at the nodal points located at the common interfaces. Continuity of stresses and displacements is imposed at the solid–solid interface, while continuity of normal stresses and displacements and null shear stress are prescribed at the fluid–solid interface. The performance of each coupled BEM-MLPG and BEM-FEM approach is determined using referenced results provided by an analytical solution developed for a circular multi-layered subdomain. The comparison of the coupled techniques is evaluated for different excitation frequencies, axial wavenumbers and degrees of freedom (nodal points).Ministerio de Economía y Competitividad BIA2013-43085-PCentro Informático Científico de Andalucía (CICA

Platinum(II), palladium(II), nickel(II), and gold(I) complexes of the “electrospray-friendly” thiolate ligands 4-SC₅H₄N- and 4-SC₆H₄OMe-

The series of platinum(II), palladium(II), and nickel(II) complexes [ML₂(dppe)] [M = Ni, Pd, Pt; L = 4-SC₅H₄N or 4-SC₆H₄OMe; dppe = Ph₂PCH₂CH₂PPh₂] containing pyridine-4-thiolate or 4-methoxybenzenethiolate ligands, together with the corresponding gold(I) complexes [AuL(PPh3)], were prepared and their electrospray ionization mass spectrometric behavior compared with that of the thiophenolate complexes [M(SPh)₂(dppe)] (M = Ni, Pd, Pt) and [Au(SPh)(PPh₃)]. While the pyridine-4-thiolate complexes yielded protonated ions of the type [M + H]+ and [M + 2H]²+ ions in the Ni, Pd, and Pt complexes, an [M + H]+ ion was only observed for the platinum derivative of 4-methoxybenzenethiolate. Other ions, which dominated the spectra of the thiophenolate complexes, were formed by thiolate loss and aggregate formation. The X-ray crystal structure of [Pt(SC₆H₄OMe-4)₂(dppe)] is also reported

Habitat connectivity in reef fish communities and marine reserve design in Old Providence-Santa Catalina, Colombia

On the insular platform of Old Providence/Santa Catalina, Colombia, we compared nearshore lagoonal patch reefs to those on the northern bank distant from the islands to determine the importance of habitat connectivity to fish community structure. Nearshore patch reefs had greater proximity to mangrove, seagrass and rocky shore habitats, and they had significantly more individuals. Nearshore reefs also tended to have a greater total biomass, more species, a higher proportion of predators of mobile invertebrates and small fishes, and a lower proportion of herbivores. Biomass of snappers and grunts at nearshore sites was four times greater compared to bank sites, and was correlated with the amount of seagrass and sand/rubble habitat within 500 m of each patch reef. We also compared length-frequency distributions and abundances of grunts and snappers among all sites (deep and shallow forereefs, patch reefs and deep and shallow leeside slopes). The results were consistent with ontogenetic migrations from shallow sites, primarily seagrass and mangrove habitats, to deeper sites and to those further out on the bank. The evidence suggests that species differed in both distance and direction of dispersal, which may be affected by the abundance and distribution of preferred habitats. Marine reserves near the islands should target nearshore nursery areas and patch reefs harboring species of limited dispersal capability. Reserves on the northern bank would protect spawners of those species showing the greatest dispersal capability

A longitudinal study of empathy in preclinical and clinical medical students and clinical supervisors

Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated.Background: Although appropriate empathy in health professionals is essential, a loss of empathy can occur during medical education. The structure of clinical learning may be one factor that is implicated in a loss of empathy. This study examines student and doctor empathy, and possible associations between empathy and the structure of clinical learning. Methods: There were three groups of participants: medical students (n = 281), who completed a longitudinal survey consisting of the Jefferson Scale of Empathy and an open question about empathy at the beginning and end of the 2013 academic year; private doctors (medical practitioners) in South Australia (n = 78) who completed a survey consisting of the Jefferson Scale of Empathy and an open question about empathy at the end of the students’ academic year; and doctors (medical practitioners) from public teaching hospitals (n = 72) in southern Adelaide, South Australia who completed a survey consisting of the Jefferson Scale of Empathy at the end of the students’ academic year. Results: Year one students’ empathy scores at the end of the year (102.8 ± 17.7) were significantly lower than at the start of the year (112.3 ± 9.6) p < .05). There were no other significant differences in students’ empathy scores by year groups or across the two time points. Empathy scores were almost identical for private and hospital clinicians and higher than average scores for students. Free-text comments highlighted the importance students and doctors place on empathy. Students described issues that adversely affected their empathy, including specific incidents, systemic issues, and course structure, but also described some positive role models. Doctors’ comments focused on the importance of empathy but qualified its meaning in the therapeutic setting. Conclusion: Medical students and practitioners alike ascribe importance to empathy in clinical practice, yet its developmental course remains poorly understood with possible decrement across the course of medical education. A more sophisticated understanding of empathy in medical students is needed, with attention to issues that might adversely impact on this crucial aspect of their development

Numerics of boundary-domain integral and integro-differential equations for BVP with variable coefficient in 3D

This is the post-print version of the article. The official published version can be accessed from the links below - Copyright @ 2013 Springer-VerlagA numerical implementation of the direct boundary-domain integral and integro-differential equations, BDIDEs, for treatment of the Dirichlet problem for a scalar elliptic PDE with variable coefficient in a three-dimensional domain is discussed. The mesh-based discretisation of the BDIEs with tetrahedron domain elements in conjunction with collocation method leads to a system of linear algebraic equations (discretised BDIE). The involved fully populated matrices are approximated by means of the H-Matrix/adaptive cross approximation technique. Convergence of the method is investigated.This study is partially supported by the EPSRC grant EP/H020497/1:"Mathematical Analysis of Localised-Boundary-Domain Integral Equations for Variable-Coefficients Boundary Value Problems"

Using Arcane Data: Past Performance in NASA Sciences Principal Investigator (PI) Development Programs and Improving Future Peer Review for Space Flight Missions

This panel will explore challenges and initial findings from three qualitative studies that use the National Aeronautics and Space Administration's (NASA) Science Mission Directorate's(SMD) internal administrative data to begin to assess program effectiveness and document outputs and outcomes. SMD has funded both at and outside NASA, projects that promotethe development of SMD's future principal investigators (PI) workforce and science and technology investigations on space flight missions that advance the high priority science,technology, and exploration objectives. NASA's internal administrative data are arcane because they developed outside of relational databases. The studies reveal unique challenges to locating and using these data to document effective program processes, i.e.,peer review criteria for large flight missions, and results from the PI-development projects,e.g. the Hands-On Project Experience (HOPE) Training Opportunity solicitations limited to NASA Centers the Jet Propulsion Laboratory; and graduate student/postdoctoral opportunities at higher education institutions