One nanosecond time synchronization using series and GPS

Subnanosecond time sychronization between two remote rubidium frequency standards is verified by a traveling clock comparison. Using a novel, code ignorant Global Positioning System (GPS) receiver developed at JPL, the SERIES geodetic baseline measurement system is applied to establish the offset between the 1 Hz. outputs of the remote standards. Results of the two intercomparison experiments to date are presented as well as experimental details

Satellite Emission Range Inferred Earth Survey (SERIES) project

The Global Positioning System (GPS) was developed by the Department of Defense primarily for navigation use by the United States Armed Forces. The system will consist of a constellation of 18 operational Navigation Satellite Timing and Ranging (NAVSTAR) satellites by the late 1980's. During the last four years, the Satellite Emission Range Inferred Earth Surveying (SERIES) team at the Jet Propulsion Laboratory (JPL) has developed a novel receiver which is the heart of the SERIES geodetic system designed to use signals broadcast from the GPS. This receiver does not require knowledge of the exact code sequence being transmitted. In addition, when two SERIES receivers are used differentially to determine a baseline, few cm accuracies can be obtained. The initial engineering test phase has been completed for the SERIES Project. Baseline lengths, ranging from 150 meters to 171 kilometers, have been measured with 0.3 cm to 7 cm accuracies. This technology, which is sponsored by the NASA Geodynamics Program, has been developed at JPL to meet the challenge for high precision, cost-effective geodesy, and to complement the mobile Very Long Baseline Interferometry (VLBI) system for Earth surveying

Nitrogen-Linked Diphosphine Ligands with Ethers Attached to Nitrogen for Chromium-Catalyzed Ethylene Tri- and Tetramerizations

A series of bis(diphenylphosphino)amine ligands with a donor group attached to the nitrogen linker have been prepared. Metalation of these ligands with chromium trichloride provides precursors to highly active, relatively stable, and selective catalysts for trimerization and tetramerization of ethylene. It has been demonstrated in oligomerization reactions performed at 1 and 4 atm of ethylene that these new systems increase total productivity by enhancing catalyst stability, as compared with those lacking a donor group on the diphosphine ligand. Furthermore, the use of chlorobenzene solvent (rather than toluene) significantly improves productivity, stability, and selectitvity. The product distributions and minor byproducts provide information relevant to mechanistic issues surrounding these types of reactions

VLBI measurements of radio source positions at the Jet Propulsion Laboratory

The results of approximately 1300 observations of 67 radio sources are presented. Most of the measurements were made at the stations of the Deep Space Network in California, Spain, and Australia at wavelengths of 13.1 and 3.6 cm, between 1971 and 1978. The formal errors in the derived source positions are generally in the neighborhood of 0.01 seconds of arc and the positions agree fairly well with those previously published

Delay/Doppler-Mapping GPS-Reflection Remote-Sensing System

A radio receiver system that features enhanced capabilities for remote sensing by use of reflected Global Positioning System (GPS) signals has been developed. This system was designed primarily for ocean altimetry, but can also be used for scatterometry and bistatic synthetic-aperture radar imaging. Moreover, it could readily be adapted to utilize navigation-satellite systems other than the GPS, including the Russian Global Navigation Satellite System GLONASS) and the proposed European Galileo system. This remote-sensing system offers both advantages and disadvantages over traditional radar altimeters: One advantage of GPS-reflection systems is that they cost less because there is no need to transmit signals. Another advantage is that there are more simultaneous measurement opportunities - one for each GPS satellite in view. The primary disadvantage is that in comparison with radar signals, GPS signals are weaker, necessitating larger antennas and/or longer observations. This GPS-reflection remote-sensing system was tested in aircraft and made to record and process both (1) signals coming directly from GPS satellites by means of an upward-looking antenna and (2) GPS signals reflected from the ground by means of a downward-looking antenna. In addition to performing conventional GPS processing, the system records raw signals for postprocessing as required

Tuning coordination in s-block carbazol-9-yl complexes

1,3,6,8-Tetra-tert-butylcarbazol-9-yl and 1,8-diaryl-3,6-di(tert-butyl)carbazol-9-yl ligands have been utilized in the synthesis of potassium and magnesium complexes. The potassium complexes (1,3,6,8-tBu4carb)K(THF)4 (1; carb=C12H4N), [(1,8-Xyl2-3,6-tBu2carb)K(THF)]2 (2; Xyl=3,5-Me2C6H3) and (1,8-Mes2-3,6-tBu2carb)K(THF)2 (3; Mes=2,4,6-Me3C6H2) were reacted with MgI2 to give the Hauser bases 1,3,6,8-tBu4carbMgI(THF)2 (4) and 1,8-Ar2-3,6-tBu2carbMgI(THF) (Ar=Xyl 5, Ar=Mes 6). Structural investigations of the potassium and magnesium derivatives highlight significant differences in the coordination motifs, which depend on the nature of the 1- and 8-substituents: 1,8-di(tert-butyl)-substituted ligands gave π-type compounds (1 and 4), in which the carbazolyl ligand acts as a multi-hapto donor, with the metal cations positioned below the coordination plane in a half-sandwich conformation, whereas the use of 1,8-diaryl substituted ligands gave σ-type complexes (2 and 6). Space-filling diagrams and percent buried volume calculations indicated that aryl-substituted carbazolyl ligands offer a steric cleft better suited to stabilization of low-coordinate magnesium complexes

Lied Animal Shelter Animal Campus Renewable Energy Demonstration Project

The Animal Shelter campus plan includes a new adoption center coupled with a dog adoption park, a wellness/veterinary technician education center, a show arena, and an addition to the existing shelter that will accommodate all animal control and sheltering for the Las Vegas Valley. The new facility will provide a sophisticated and innovative presentation of the animals to be adopted in an attempt to improve the public's perception of shelter animals. Additionally, the Regional Animal Campus will be a ''green building'', embodying a design intent on balancing environmental responsiveness, resource efficiency and cultural and community sensitivity. Designing an energy-efficient building helps reduce pollution from burning fossil fuels, reduce disturbance of natural habitats for the harvesting of resources and minimizes global warming. The project will be a leader in the use of renewable energy by relying on photovoltaic panels, wind turbines, and solar collectors to produce a portion of the project's energy needs The building will operate more efficiently in comparison to a typical shelter through the use of monitoring and specialized cooling/heating equipment. Windows bringing in natural daylight will reduce the center's demand for electricity