A New Method to Derive Electronegativity from Resonant Inelastic X-ray Scattering

Electronegativity is a well-known property of atoms and substituent groups. Because there is no direct way to measure it, establishing a useful scale for electronegativity often entails correlating it to another chemical parameter; a wide variety of methods have been proposed over the past 80 years to do just that. This work reports a new approach that connects electronegativity to a spectroscopic parameter derived from resonant inelastic x-ray scattering. The new method is demonstrated using a series of chlorine-containing compounds, focusing on the Cl 2p−1LUMO1 electronic states reached after Cl 1s→LUMO core excitation and subsequent KL radiative decay. Based on an electron-density analysis of the LUMOs, the relative weights of the Cl 2pz atomic orbital contributing to the Cl 2p3/2 molecular spin-orbit components are shown to yield a linear electronegativity scale consistent with previous approaches

Resonant Inelastic X-ray Scattering of Methyl Chloride at the Chlorine K Edge

We present a combined experimental and theoretical study of isolated CH3Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the spin-orbit intensities, a result interpreted as due to chemical environment and singlet-triplet exchange in the molecular core levels. From analysis of the polarization-resolved data, Cl 2px, y and 2pz electronic populations can be determined

Angular and Dynamical Properties in Resonant Inelastic X-ray Scattering: Case Study of Chlorine-containing Molecules

Polarization-dependent resonant inelastic x-ray scattering (RIXS) has been shown to be a probe of molecular-field effects on the electronic structure of isolated molecules. In this experimental analysis we explain the linear dichroism observed in Cl 2p polarized RIXS following Cl 1s excitation of a series of chlorofluoromethanes (CF3Cl, CF2Cl2, CFCl3, and CCl4) as due to molecular-field effects, including singlet-triplet exchange. We present an approach to extract directly the 2p inner-shell electronic state populations from the experimental measurements. Using the angular properties of the measured KV emission we also are able to determine the value of the polarization anisotropy parameter βp for each resolved component of the KV emission spectra

Thomson-resonant Interference Effects in Elastic X-ray Scattering Near the Cl K Edge of HCl

We experimentally observed interference effects in elastic x-ray scattering from gas-phase HCl in the vicinity of the Cl K edge. Comparison to theory identifies these effects as interference effects between non-resonant elastic Thomson scattering and resonant Raman scattering. The results indicate the non-resonant Thomson and resonant Raman contributions are of comparable strength. The measurements also exhibit strong polarization dependence, allowing an easy identification of the resonant and non-resonant contributions

Femtosecond Nuclear Motion of HCl Probed by Resonant X-ray Raman Scattering in the Cl 1s Region

Femtosecond dynamics are observed by resonant x-ray Raman scattering (RXS) after excitation along the dissociative Cl 1s→6ơ* resonance of gas-phase HCl. The short core-hole lifetime results in a complete breakdown of the common nondispersive behavior of soft-x-ray transitions between parallel potentials. We evidence a general phenomenon of RXS in the hard-x-ray region: a complete quenching of vibrational broadening. This opens up a unique opportunity for superhigh resolution x-ray spectroscopy beyond vibrational and lifetime limitations

LatentForensics: Towards frugal deepfake detection in the StyleGAN latent space

The classification of forged videos has been a challenge for the past few years. Deepfake classifiers can now reliably predict whether or not video frames have been tampered with. However, their performance is tied to both the dataset used for training and the analyst's computational power. We propose a deepfake detection method that operates in the latent space of a state-of-the-art generative adversarial network (GAN) trained on high-quality face images. The proposed method leverages the structure of the latent space of StyleGAN to learn a lightweight binary classification model. Experimental results on standard datasets reveal that the proposed approach outperforms other state-of-the-art deepfake classification methods, especially in contexts where the data available to train the models is rare, such as when a new manipulation method is introduced. To the best of our knowledge, this is the first study showing the interest of the latent space of StyleGAN for deepfake classification. Combined with other recent studies on the interpretation and manipulation of this latent space, we believe that the proposed approach can further help in developing frugal deepfake classification methods based on interpretable high-level properties of face images.Comment: 7 pages, 3 figures, 5 table

THE EFFECT OF THE USE OF LANTHANUM-DOPED MESOPOROUS CERIA ON THE PERFORMANCE OF AU/MESOPOROUS CERIA CATALYSTS FOR TOTAL OXIDATION OF TOLUENE

ISCSC2012, International Symposium on Catalysis and Specialty Chemicals, 23-26 sep. 2012, Tlemcen Algeria.Catalyc combustion is one of the most promising technology for VOCs abatement, due to its definitive character and save of energ