Using Tellus data to enhance targeting of volcanogenic massive sulphide mineralisation in the Tyrone Igneous Complex

The Tyrone Igneous Complex of Northern Ireland has been a target for base and precious metal exploration since the 1970s. Historic exploration was hampered by poor exposure and consequently a limited understanding of the local geology. Extensive new field mapping, utilising the high-resolution Tellus geophysical survey, coupled with U-Pb zircon geochronology and whole-rock geochemistry, has greatly improved our understanding of the complex and its potential to host volcanogenic massive sulphide (VMS) mineralisation. Targeting of Tellus and historic, geochemical and geophysical anomalies along VMS prospective stratigraphic horizons has identified new mineral occurrences and areas for further exploration. A correlation has been made with the Buchans–Robert’s Arm arc system of Newfoundland, host to numerous economic deposits

Adolescent dietary patterns are associated with lifestyle family psycho-social factors

Background/ Objectives: Dietary intake during adolescence contributes to lifelong eating habits and the development of early risk factors for disease in adulthood. Few studies have examined the dietary patterns of adolescents and the social and environmental factors that may affect them during this life stage. The present study describes dietary patterns in a cohort of adolescents and examines their associations with socioeconomic factors, as well as parental and adolescent risk factor behaviours. Design: A semi quantitative FFQ was used to assess study adolescents’ usual dietary intake over the previous year. Information was collected on family functioning and various socio economic and risk factor variables via questionnaire. Adolescents visited the clinic for anthropometric measurements. Setting: The Western Australian Pregnancy Cohort Study (Raine Study), Perth, Western Australia. Subjects: Adolescents (n 1631) aged 14 years from a pregnancy cohort study. Results: Factor analysis identified two distinct dietary patterns that differed predominantly in fat and sugar intakes. The ‘Western’ pattern consisted of high intakes of take away foods, soft drinks, confectionery, French fries, refined grains, full fat dairy products and processed meats. The ‘Healthy’’ pattern included high intakes of whole grains, fruit, vegetables, legumes and fish. ANOVA showed that the ‘Western’ dietary pattern was positively associated with greater television viewing and having a parent that smoked, and was inversely associated with family income. The ‘Healthy’’ pattern was positively associated with female gender, greater maternal education, better family functioning and being in a two parent family, and was inversely associated with television viewing. Conclusions: This study suggests that both lifestyle factors and family psycho social environment are related to eating patterns in Australian adolescents

Relationship between Vitamin D Status and Autonomic Nervous System Activity

This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).Vitamin D deficiency is associated with increased arterial stiffness. However, the mechanisms underlying this association have not been clarified. The aim was to investigate whether changes in autonomic nervous system activity could underlie an association between 25 hydroxy vitamin D and arterial stiffness. A total of 49 subjects (age = 60 8 years, body mass index = 26.7 4.6 kg/m2, 25 hydroxy vitamin D = 69 22 nmol/L) underwent measurements of pulse wave velocity (PWV) and augmentation index (AIx), spontaneous baroreflex sensitivity, plasma metanephrines and 25 hydroxy vitamin D. Subjects with 25 hydroxy vitamin D 50 nmol/L were restudied after 200,000 International Units 25 hydroxy vitamin D. Plasma metanephrine was positively associated with AIx (p = 0.02) independent of age, sex, smoking and cholesterol and negatively associated with 25 hydroxy vitamin D (p = 0.002) independent of age, sex and season. In contrast, there was no association between baroreflex sensitivity and 25 hydroxy vitamin D (p = 0.54). Treatment with vitamin D increased 25 hydroxy vitamin D from 43 5 to 96 24 nmol/L (p < 0.0001) but there was no significant change in plasma metanephrine (115 25 vs. 99 39 pmol/L, p = 0.12). We conclude that as plasma metanephrine was negatively associated with 25 hydroxy vitamin D and positively with AIx, it could mediate an association between these two variables. This hypothesis should be tested in larger interventional studies

Excitonic coupling in covalently-bound Perylene Bisimide dimers revealed by two-dimensional electronic spectroscopy

Supramolecular structures based on Perylene Bisimides (PBIs) have been extensively studied because of their fundamental photophysical properties and for their application in a range of different optoelectronic devices. Two-dimensional electronic spectroscopy (2D-ES) is the most complete third order (χ(3)) technique, it has been shown that it is particularly useful to disentangle close-lying energy levels and to reveal dynamics in coupled molecular systems. Two different PBI covalently “head-to-tail” bound dimers (D0 and D1) with increasing interchromophoric separation, and a reference monomer (M) were synthesised and studied by means of 2D-ES in order to characterise the 1 to 2-exciton state transition and how its behaviour changes in relation to the PBI-PBI distance

Ultrafast dynamics in light-driven molecular rotary motors probed by femtosecond stimulated raman spectroscopy

Photochemical isomerization in sterically crowded chiral alkenes is the driving force for molecular rotary motors in nanoscale machines. Here the excited state dynamics and structural evolution of the prototypical light driven rotary motor are followed on the ultrafast timescale by femtosecond stimulated Raman spectroscopy (FSRS) and transient absorption (TA). TA reveals a sub 100 fs blue shift and decay of the Franck-Condon bright state arising from relaxation along the reactive potential energy surface. The decay is accompanied by coherently excited vibrational dynamics which survive the excited state structural evolution. The ultrafast Franck-Condon bright state relaxation is to a dark excited state, which FSRS reveals to have a rich spectrum compared to the electronic ground state, with the most intense Raman active modes shifted to significantly lower wavenumber. This is discussed in terms of a reduced bond order of the central bridging bond and overall weakening of bonds in the dark state, which is supported by electronic structure calculations. The observed evolution in the FSRS spectrum is assigned to vibrational cooling accompanied by partitioning of the dark state between the product isomer and the original ground state. Formation of the product isomer is observed in real time by FSRS. It is formed vibrationally hot and cools over several picoseconds, completing the characterization of the light driven half of the photocycle

ENGR 1009: Preparation for Engineering Problem Solving (Syllabus)

Course Description: Applications of algebra and trigonometry to engineering problems. Accelerated preparation for an engineering or technology major

Delay/Doppler-Mapping GPS-Reflection Remote-Sensing System

A radio receiver system that features enhanced capabilities for remote sensing by use of reflected Global Positioning System (GPS) signals has been developed. This system was designed primarily for ocean altimetry, but can also be used for scatterometry and bistatic synthetic-aperture radar imaging. Moreover, it could readily be adapted to utilize navigation-satellite systems other than the GPS, including the Russian Global Navigation Satellite System GLONASS) and the proposed European Galileo system. This remote-sensing system offers both advantages and disadvantages over traditional radar altimeters: One advantage of GPS-reflection systems is that they cost less because there is no need to transmit signals. Another advantage is that there are more simultaneous measurement opportunities - one for each GPS satellite in view. The primary disadvantage is that in comparison with radar signals, GPS signals are weaker, necessitating larger antennas and/or longer observations. This GPS-reflection remote-sensing system was tested in aircraft and made to record and process both (1) signals coming directly from GPS satellites by means of an upward-looking antenna and (2) GPS signals reflected from the ground by means of a downward-looking antenna. In addition to performing conventional GPS processing, the system records raw signals for postprocessing as required

Of Heart and Mind: Social Policy Essays in Honor of Sar A. Levitan

The essays in this volume, authored by close friends, associates and students of Sar Levitan, pay tribute to the enduring mark he left on the field of social policy. The book is loosely organized around the method of analysis taught and practiced by Levitan: identifying problems through the examination of facts, developing a thorough understanding of institutions, assessing institutional policies, and evaluating policy options.https://research.upjohn.org/up_press/1197/thumbnail.jp

Airfoil design utilizing parallel processors. II-Applications

Presented as Paper 95-0126 at the 33rd Aerospace Sciences Meeting and Exhibit January 9-12,1995 / Reno, NVThe article of record as published may be found at https://doi.org/10.2514/6.1995-126One test case and two airfoil design applications were performed utilizing a parallel optimization scheme coupled to different fiow solvers. Parallel processors use computational fluid dynamics to evaluate the aerodynamic performance of multiple geometries simultaneously. The test case designed an airfoil to match the pressure distribution corresponding to an airfoil of a known shape. A transonic design application varied an airfoil's shape to maximize its lift-to-drag ratio