Overview of NASA supported Stirling thermodynamic loss research

NASA is funding research to characterize Stirling machine thermodynamic losses. NASA's primary goal is to improve Stirling design codes to support engine development for space and terrestrial power. However, much of the fundamental data is applicable to Stirling cooling and heat pump applications. The research results are reviewed. Much was learned about oscillating flow hydrodynamics, including laminar/turbulent transition, and tabulated data was documented for further analysis. Now, with a better understanding of the oscillating flow field, it is time to begin measuring the effects of oscillating flow and oscillating pressure level on heat transfer in heat exchanger flow passages and in cylinders

Studies on the use of sulfites to control shrimp melanosis (Blackspot) (Presented at the 11th Annual Meeting of the Tropical and Subtropical Fisheries Technological Conference of the Americas, January 14, 1986, Tampa, Florida)

Shrimp melanosis, commonly known as 'blackspot' is a harmless but objectionable surface dicoloration caused by polyphenoloxidase enzyme systems which remain active during refrigeration or ice storage. In the early 1950's sulfiting agents, particularily sodium bisulfite was first introduced to prevent or inhibit melanosis, thus yielding a more valuable harvest (1). Such use of sulfites was 'prior sanctioned1 by the U.S. Food and Drug Administration (FDA) in 1956 (2). More recent FDA decisions reaffirmed this practice, (3) but continuing regulatory scrutiny could restrict or eliminate the application of sulfite on shrimp. The regulatory action is prompted by an increasing concern for adverse 'allergic' reactions most common amongst hyper-(sulfite) sensitive asthmatics. Thus work was initiated to find alternatives to replace or reduce the amount of sulfites required to inhibit shrimp melanosis. This work would screen for possible alternatives which would require subsequent verification with field tests and statistical evaluations. (21pp.

Efficiency Costs of Subsidy Rules for Crop Insurance

Participation in federal crop insurance programs has been encouraged through premium subsidies. The current subsidy depends on contract features as well as coverage levels. This type of subsidy rule causes farmers to choose contract designs and coverages that are not efficient for managing risk, in order to capture subsidy. Farmers are found to be as well off with a flat subsidy that is up to 25% less than the value of the current regressive proportional subsidy.crop insurance, futures, risk management, subsidy, Risk and Uncertainty,

Comparison of GLIMPS and HFAST Stirling engine code predictions with experimental data

Predictions from GLIMPS and HFAST design codes are compared with experimental data for the RE-1000 and SPRE free piston Stirling engines. Engine performance and available power loss predictions are compared. Differences exist between GLIMPS and HFAST loss predictions. Both codes require engine specific calibration to bring predictions and experimental data into agreement

Looking at the bright side - The story of AA Dor as revealed by its cool companion

Irradiation effects in close binaries are crucial for a reliable determination of system parameters and understanding the close binary evolution. We study irradiated light originating from the low mass component of an eclipsing system comprising a hot subdwarf primary and a low mass companion, to precisely interpret their high precision photometric and spectroscopic data, and accurately determine their system and surface parameters. We re-analyse the archival VLT/UVES spectra of AA Dor system where irradiation features have already been detected. After removing the predominant contribution of the hot subdwarf primary, the residual spectra reveal more than 100 emission lines from the heated side of the secondary with maximum intensity close to the phases around secondary eclipse. We analyse 22 narrow emission lines of the irradiated secondary, mainly of OII, with a few CII lines. Their phase profiles constrain the emission region of the heated side to a radius $\geq$ 95% of the radius of the secondary. The shape of their velocity profiles reveals two distinct asymmetry features one at the quadrature and the other at the secondary eclipse. We identify more than 70 weaker emission lines originating from HeI, NII, SiIII, CaII and MgII. We correct the radial velocity semi-amplitude of the center-of-light to the centre-of-mass of the secondary and calculate accurate masses of both components. The resulting masses $M_{1}$=0.46 $\pm$ 0.01$M_{\odot}$ and $M_{2}$=0.079 $\pm$ 0.002$M_{\odot}$ are in perfect accordance with those of a canonical hot subdwarf primary and a low mass star just at the substellar limit for the companion. We compute a first generation atmosphere model of the irradiated low mass secondary, which matches the observed spectrum well. We find an indication of an extended atmosphere of the irradiated secondary star.Comment: 13 pages, 9 figures, accepted for publication in A&

Economically Optimal Distiller Grain Inclusion in Beef Feedlot Rations: Recognition of Omitted Factors

With the rapid expansion of the ethanol industry, the feeding landscape familiar to the feedlot industry is changing. While concerns regarding rising corn prices persist, many within the industry are looking at distiller’s grains, a by-product of ethanol production, to serve as a feed substitute. The question remains as to what extent these two feed sources are substitutable. The purpose of this study is to identify the economically optimal inclusion rate of distiller’s grains in beef feedlot rations, considering an array of often omitted factors. Most currently prevailing recommendation rates are strictly biologically based and frequently reference only one feeding trial. Unique economic factors considered in this research include the impact of by-product inclusion rates on animal performance (utilizing recently conducted meta-analysis from 17 relevant feeding trials), enhanced likelihood of death loss from heightened sulfur content, and manure disposal costs. Results indicate that excluding these factors can significantly impact optimal inclusion levels and that reliance on a single or few feeding trials may greatly bias results.distiller’s grains, livestock rations, manure disposal cost,

Benzene C−H Bond Activation in Carboxylic Acids Catalyzed by O-Donor Iridium(III) Complexes: An Experimental and Density Functional Study

The mechanism of benzene C−H bond activation by [Ir(μ-acac-O,O,C^3)(acac-O,O)(OAc)]_2 (4) and [Ir(μ-acac-O,O,C^3)(acac-O,O)(TFA)]_2 (5) complexes (acac = acetylacetonato, OAc = acetate, and TFA = trifluoroacetate) was studied experimentally and theoretically. Hydrogen−deuterium (H/D) exchange between benzene and CD_(3)COOD solvent catalyzed by 4 (ΔH^‡ = 28.3 ± 1.1 kcal/mol, ΔS^‡ = 3.9 ± 3.0 cal K^(−1) mol^(−1)) results in a monotonic increase of all benzene isotopologues, suggesting that once benzene coordinates to the iridium center, there are multiple H/D exchange events prior to benzene dissociation. B3LYP density functional theory (DFT) calculations reveal that this benzene isotopologue pattern is due to a rate-determining step that involves acetate ligand dissociation and benzene coordination, which is then followed by heterolytic C−H bond cleavage to generate an iridium-phenyl intermediate. A synthesized iridium-phenyl intermediate was also shown to be competent for H/D exchange, giving similar rates to the proposed catalytic systems. This mechanism nicely explains why hydroarylation between benzene and alkenes is suppressed in the presence of acetic acid when catalyzed by [Ir(μ-acac-O,O,C^3)(acac-O,O)(acac-C^3)]_2 (3) (Matsumoto et al. J. Am. Chem. Soc. 2000, 122, 7414). Benzene H/D exchange in CF_(3)COOD solvent catalyzed by 5 (ΔH^‡ = 15.3 ± 3.5 kcal/mol, ΔS^‡ = −30.0 ± 5.1 cal K^(−1) mol^(−1)) results in significantly elevated H/D exchange rates and the formation of only a single benzene isotopologue, (C_(6)H_(5)D). DFT calculations show that this is due to a change in the rate-determining step. Now equilibrium between coordinated and uncoordinated benzene precedes a single rate-determining heterolytic C−H bond cleavage step

The para-substituent effect and pH-dependence of the organometallic Baeyer–Villiger oxidation of rhenium–carbon bonds

We studied the Baeyer–Villiger (BV) type oxidation of phenylrhenium trioxide (PTO) by H2O2 in the aqueous phase using Quantum Mechanics (density functional theory with the M06 functional) focusing on how the solution pH and the para-substituent affect the Gibbs free energy surfaces. For both PTO and MTO (methylrhenium trioxide) cases, we find that for pH > 1 the BV pathway having OH− as the leaving group is lower in energy than the one involving simultaneous protonation of hydroxide. We also find that during this organometallic BV oxidation, the migrating phenyl is a nucleophile so that substituting functional groups in the para-position of phenyl with increased electron-donating character lowers the migration barrier, just as in organic BV reactions. However, this substituent effect also pushes electron density to Re, impeding HOO− coordination and slowing down the reaction. This is in direct contrast to the organic analog, in which para-substitution has an insignificant influence on 1,2-addition of peracids. Due to the competition of the two opposing effects and the dependence of the resting state on pH and concentration, the reaction rate of the organometallic BV oxidation is surprisingly unaffected by para-substitution