Photocatalytic activity of nanotubular TiO2films obtained by anodic oxidation: A comparison in gas and liquid phase

The availability of immobilized nanostructured photocatalysts is of great importance in the purification of both polluted air and liquids (e.g., industrial wastewaters). Metal-supported titanium dioxide films with nanotubular morphology and good photocatalytic efficiency in both environments can be produced by anodic oxidation, which avoids release of nanoscale materials in the environment. Here we evaluate the effect of different anodizing procedures on the photocatalytic activity of TiO2nanostructures in gas and liquid phases, in order to identify the most efficient and robust technique for the production of TiO2layers with different morphologies and high photocatalytic activity in both phases. Rhodamine B and toluene were used as model pollutants in the two media, respectively. It was found that the role of the anodizing electrolyte is particularly crucial, as it provides substantial differences in the oxide specific surface area: nanotubular structures show remarkably different activities, especially in gas phase degradation reactions, and within nanotubular structures, those produced by organic electrolytes lead to better photocatalytic activity in both conditions tested

Exploitation of Soybean Oil Acid Degumming Waste: Biocatalytic Synthesis of High Value Phospholipids

The acid degumming waste of the seeds oil refining industry is currently disposed of, but, instead, it could be exploited as an important source for the preparation of many products. In this work, the waste coming from the soybean oil refining step was first recovered and treated, allowing the isolation of a fraction enriched of phospholipids (PLs). Then, the latter was transformed, via an enzymatic reaction catalysed by phospholipase D (from Streptomyces netropsis), into more valuable products: polar head modified PLs-enriched mixtures containing phosphatidylserine (PS), phosphatidylglycerol (PG), phosphatidylethanolamine (PE) and phosphatidylhydroxybutyrate (PB). In the following we show how biocatalysis can be exploited for the production of value-added PLs, to be used as functional food and nutraceutical ingredients, from a renewable feedstock. This alternative to the industrial usual disposal procedures should impart to the whole process a greater value in terms of carbon recycling, in agreement with the paradigms of bioeconomy for a wiser reuse of renewable resources in a circular economy perspective

Uncovering potential interviewer-related biases in self-efficacy assessment: a study among chronic disease patients

Abstract Background Self-efficacy refers to an individual's belief in their ability to accomplish specific tasks and achieve goals, and plays an essential role in achieving positive outcomes in a wide range of domains. Central to the measurement of any form of self-efficacy is the assessment without bias, also in case of an interview situation. Methods Outpatients with macular edema, an eye disease, participated in this questionnaire-based cross-sectional study. The study assessed self-efficacy using the General Self-Efficacy Scale (GSE) in German. Interviewers read questionnaires aloud to patients. Differential item functioning (DIF) was investigated using likelihood-ratio χ2 tests for interviewer, sex, age, education, working status, income, diagnosis, and health-status. Results The analysis included N = 556 patients. Median age was 68.4 (IQR: 62.0 – 76.0) years and mean overall GSE score 32.8 (SD: 4.81). No DIF was detected for interviewer. However, DIF was found in item 1 for education (uniform DIF, NCDIFno degree vs. degree = 0.042; easier with degree vs. none), in item 1 and 3 for income (item 1: non-uniform DIF, NCDIF<€ 1,125 vs.≥€ 1,125≤€ 1,950 = 0.050 / NCDIF< € 1,125 vs.≥€ 1,950 = 0.099; item 3: uniform DIF, NCDIF<€ 1,125 vs.≥€ 1,125—≤€ 1,950 = 0.024 / NCDIF< € 1,125 vs.≥€ 1,950: 0.095; both easier with higher income), in item 2 for working status (uniform DIF, NCDIFretired vs. other = 0.017; easier if working) and in item 3 for sex (non-uniform DIF, NCDIFmale vs. female = 0.043; easier for women in low ability, harder for them from medium ability on). Conclusions Given that no DIF was detected concerning interviewers, our findings indicate that an objective assessment of self-efficacy in a face-to-face interview may be feasible, provided that interviewers receive appropriate training. Since DIF effects concerning other patients characteristics found were small, the GSE may provide a relatively bias free way to assess self-efficacy in an interview setting