Recycled gabbro signature in hotspot magmas unveiled by plume–ridge interactions

Lavas erupted within plate interiors above upwelling mantle plumes have chemical signatures that are distinct from midocean ridge lavas. When a plume interacts with a mid-ocean ridge, the compositions of both their lavas changes, but there is no consensus as to how this interaction occurs1–3. For the past 15 Myr, the Pacific–Antarctic mid-ocean ridge has been approaching the Foundation hotspot4 and erupted lavas have formed seamounts. Here we analyse the noble gas isotope and trace element signature of lava samples collected from the seamounts. We find that both intraplate and on-axis lavas have noble gas isotope signatures consistent with the contribution from a primitive plume source. In contrast, nearaxis lavas show no primitive noble gas isotope signatures, but are enriched in strontium and lead, indicative of subducted former oceanic lower crust melting within the plume source5–7. We propose that, in a near-ridge setting, primitive, plumesourced magmas formed deep in the plume are preferentially channelled to and erupted at the ridge-axis. The remaining residue continues to rise and melt, forming the near-axis seamounts. With the deep melts removed, the geochemical signature of subduction contained within the residue becomes apparent. Lavas with strontium and lead enrichments are found worldwide where plumes meet mid-ocean ridges6–8, suggesting that subducted lower crust is an important but previously unrecognised plume component

Evaluation of palagonite: crystallization, chemical changes and element budget

[1] The structural and chemical evolution of palagonite was studied as a function of glass composition, alteration environment, and time by applying a range of analytical methods (electron microprobe, infrared photometry, atomic force microscopy, X-ray fluorescence, and X-ray diffraction). Palagonitization of volcanic glass is a continuous process of glass dissolution, palagonite formation, and palagonite evolution, which can be subdivided into two different reaction stages with changing element mobilities. The first stage is characterized by congruent dissolution of glass and contemporaneous precipitation of “fresh,” gel-like, amorphous, optically isotropic, mainly yellowish palagonite. This stage is accompanied by loss of Si, Al, Mg, Ca, Na, and K, active enrichment of H2O, and the passive enrichment of Ti and Fe. The second stage is an aging process during which the thermodynamically unstable palagonite reacts with the surrounding fluid and crystallizes to smectite. This stage is accompanied by uptake of Si, Al, Mg, and K from solution and the loss of Ti and H2O. Ca and Na are still showing losses, whereas Fe reacts less consistently, remaining either unchanged or showing losses. The degree and direction of element mobility during palagonitization was found to vary mainly with palagonite aging, as soon as the first precipitation of palagonite occurs. This is indicated by the contrasting major element signatures of palagonites of different aging steps, by the changes in the direction of element mobility with palagonite aging, and by the general decrease of element loss with increasing formation of crystalline substances in the palagonite. Considering the overall element budget of a water-rock system, the conversion of glass to palagonite is accompanied by much larger element losses than the overall alteration process, which includes the formation of secondary phases and palagonite aging. The least evolved palagonitized mafic glass studied has undergone as much as 65 wt% loss of elements during palagonite formation, compared to ∼28 wt% element loss during bulk alteration. ABout 33 wt% element loss was calculated for one of the more evolved, in terms of the aging degree, rocks studied, compared to almost no loss for bulk alteration

Remote detection of past habitability at Mars-analogue hydrothermal alteration terrains using an ExoMars Panoramic Camera emulator

JKH is funded by a Birkbeck University of London Graduate Teaching Assistantship. CRC is funded by a Royal Society of Edinburgh Personal Research Fellowship co-funded by Marie Curie Actions. The Aberystwyth research leading to these results has been funded by the UK Space Agency, ExoMars Panoramic Camera (PanCam) Grant Nos. ST/G003114/1, ST/I002758/1, STL001454/1, and the UK Space Agency CREST2 PanCam-2020 research Grant No. ST/L00500X/1. Additional Aberystwyth funding has come from The European Community’s Seventh Framework Programme (FP7/2007-2013), Grant Agreement Nos. 21881 PRoVisG, 241523 PRoViScout, and Grant Agreement No. 312377 PRoViDE. PMG is funded by a UK Space Agency Aurora Fellowship (grants ST/J005215/1 and ST/L00254X/1).A major scientific goal of the European Space Agency’s ExoMars 2018 rover is to identify evidence of life within the martian rock record. Key to this objective is the remote detection of geological substrates that are indicative of past habitable environments, which will rely on visual (stereo wide-angle, and high resolution images) and multispectral (440–1000 nm) data produced by the Panoramic Camera (PanCam) instrument. We deployed a PanCam emulator at four hydrothermal sites in the Námafjall volcanic region of Iceland, a Mars-analogue hydrothermal alteration terrain. At these sites, sustained acidic–neutral aqueous interaction with basaltic substrates (crystalline and sedimentary) has produced phyllosilicate, ferric oxide, and sulfate-rich alteration soils, and secondary mineral deposits including gypsum veins and zeolite amygdales. PanCam emulator datasets from these sites were complemented with (i) NERC Airborne Research and Survey Facility aerial hyperspectral images of the study area; (ii) in situ reflectance spectroscopy (400–1000 nm) of PanCam spectral targets; (iii) laboratory X-ray Diffraction, and (iv) laboratory VNIR (350–2500 nm) spectroscopy of target samples to identify their bulk mineralogy and spectral properties. The mineral assemblages and palaeoenvironments characterised here are analogous to neutral–acidic alteration terrains on Mars, such as at Mawrth Vallis and Gusev Crater. Combined multispectral and High Resolution Camera datasets were found to be effective at capturing features of astrobiological importance, such as secondary gypsum and zeolite mineral veins, and phyllosilicate-rich substrates. Our field observations with the PanCam emulator also uncovered stray light problems which are most significant in the NIR wavelengths and investigations are being undertaken to ensure that the flight model PanCam cameras are not similarly affected.Publisher PDFPeer reviewe

Insights into mantle composition and mantle melting beneath mid-ocean ridges from postspreading volcanism on the fossil Galapagos Rise

New major and trace element and Sr, Nd, and Pb isotope data, together with 39Ar-40Ar ages for lavas from the extinct Galapagos Rise spreading center in the eastern Pacific reveal the evolution in magma compositions erupted during slowdown and after the end of active spreading at a mid-ocean ridge. Lavas erupted at 9.2 Ma, immediately prior to the end of spreading are incompatible element depleted mid-ocean ridge tholeiitic basalts, whereas progressively younger (7.5 to 5.7 Ma) postspreading lavas are increasingly alkalic, have higher concentrations of incompatible elements, higher La/Yb, K/Ti, 87Sr/86Sr, and lower 143Nd/144Nd ratios and were produced by smaller degrees of mantle melting. The large, correlated variations in trace element and isotope compositions can only be explained by melting of heterogenous mantle, in which incompatible trace element enriched lithologies preferentially contribute to smaller degree mantle melts. The effects of variable degrees of melting of heterogeneous mantle on lava compositions must be taken into account when using mid-ocean ridge basalt (MORB) to infer the conditions of melting beneath active spreading ridges. For example, the stronger “garnet signature” inferred from Sm/Nd and 143Nd/144Nd ratios for postspreading lavas from the Galapagos Rise results from a larger contribution from enriched lithologies with high La/Yb and Sm/Yb, rather than from a greater proportion of melting in the stability field of garnet peridotite. Correlations between ridge depth and Sm/Yb and fractionation-corrected Na concentrations in MORB worldwide could result from variations in mantle fertility and/or variations in the average degree of melting, rather than from large variations in mantle temperature. If more fertile mantle lithologies are preferentially melted beneath active spreading ridges, then the upper mantle may be significantly more “depleted” than is generally inferred from the compositions of MORB

IODP Expedition 334: An Investigation of the Sedimentary Record, Fluid Flow and State of Stress on Top of the Seismogenic Zone of an Erosive Subduction Margin

The Costa Rica Seismogenesis Project (CRISP) is an experiment to understand the processes that control nucleation and seismic rupture of large earthquakes at erosional subduction zones. Integrated Ocean Drililng Program (IODP) Expedition 334 by R/V JOIDES Resolution is the first step toward deep drilling through the aseismic and seismic plate boundary at the Costa Rica subduction zone offshore the Osa Peninsula where the Cocos Ridge is subducting beneath the Caribbean plate. Drilling operations included logging while drilling (LWD) at two slope sites (Sites U1378 and U1379) and coring at three slope sites (Sites U1378–1380) and at one site on the Cocos plate (Site U1381). For the first time the lithology, stratigraphy, and age of the slope and incoming sediments as well as the petrology of the subducting Cocos Ridge have been characterized at this margin. The slope sites recorded a high sediment accumulation rate of 160–1035m m.y.-1 possibly caused by on-land uplift triggered by the subduction of the Cocos Ridge. The geochemical data as well as the in situ temperature data obtained at the slope sites suggest that fluids are transported from greater depths. The geochemical profiles at Site U1381 reflect diffusional communication of a fluid with seawater-like chemistry and the igneous basement of the Cocos plate (Solomon et al., 2011; Vannucchi et al., 2012a). The present-day in situ stress orientation determined by borehole breakouts at Site U1378 in the middle slope and Site U1379 in the upper slope shows a marked change in stress state within ~12 km along the CRISP transect; that may correspond to a change from compression (middle slope) to extension (upper slope)

Feedbacks between the formation of secondary minerals and the infiltration of fluids into the regolith of granitic rocks in different climatic zones (Chilean Coastal Cordillera)

Subsurface fluid pathways and the climate-dependent infiltration of fluids into the subsurface jointly control the intensity and depth of mineral weathering reactions. The products of these weathering reactions (secondary minerals), such as Fe(III) oxyhydroxides and clay minerals, in turn exert a control on the subsurface fluid flow and hence on the development of weathering profiles. We explored the dependence of mineral transformations on climate during the weathering of granitic rocks in two 6 m deep weathering profiles in Mediterranean and humid climate zones along the Chilean Coastal Cordillera. We used geochemical and mineralogical methods such as (micro ) X-ray fluorescence, oxalate/dithionite extractions, X-ray diffraction and electron microprobe mapping to elucidate the transformations involved during weathering. In the profile of the Mediterranean climate zone, we found a low weathering intensity affecting the profile down to 6 m depth. In the profile of the humid climate zone, we found a high weathering intensity. Based on our results, we propose mechanisms that can intensify the progression of weathering to depth. The most important is weathering-induced fracturing (WIF) by Fe(II) oxidation in biotite and precipitation of Fe(III) oxyhydroxides, and by swelling of interstratified smectitic clay minerals that promotes the formation of fluid pathways. We also propose mechanisms that mitigate the development of a deep weathering zone, like the precipitation of secondary minerals (e.g., clay minerals) and amorphous phases that can impede the subsurface fluid flow. We conclude that the depth and intensity of primary mineral weathering in the profile of the Mediterranean climate zone is significantly controlled by WIF. It generates a surface-subsurface connectivity that allows fluid infiltration to great depth and hence promotes a deep weathering zone. Moreover, the water supply to the subsurface is limited in the Mediterranean climate and thus most of the weathering profile is generally characterized by a low weathering intensity. The depth and intensity of weathering processes in the profile of the humid climate zone, on the other hand, are controlled by an intense formation of secondary minerals in the upper section of the weathering profile. This intense formation arises from pronounced dissolution of primary minerals due to the high water infiltration (high precipitation rate) into the subsurface. The secondary minerals, in turn, impede the infiltration of fluids to great depth and thus mitigate the intensity of primary mineral weathering at depth. These two settings illustrate that the depth and intensity of primary mineral weathering in the upper regolith are controlled by positive and negative feedbacks between the formation of secondary minerals and the infiltration of fluids.</p

Denudation and Weathering Rates of Carbonate Landscapes From Meteoric 10Be/9Be Ratios

Knowledge of the rates of carbonate rock denudation, the relative apportionment of chemical weathering versus physical erosion, and their sensitivity to climate, vegetation, and tectonics is essential for disclosing feedbacks within the carbon cycle and the functioning of karst landscapes that supply important services to humans. Currently, however, for carbonate lithologies, no method exists that allows to simultaneously partition denudation into erosion and weathering fluxes at spatial scales ranging from soil to watersheds. To determine total denudation rates in carbonate landscapes from an individual soil or river sample, we adapted a published framework that combines cosmogenic meteoric 10 Be as an atmospheric flux tracer with stable 9 Be that is released from rocks by weathering, to the limestone‐dominated French Jura Mountains. By analyzing water, soil, sediment, travertine, and bedrock for 10 Be/ 9 Be, major and trace elements, carbon stable isotopes and radiogenic strontium, we quantified contributions of Be from primary versus secondary carbonate phases and its release during weathering from carbonate bedrock versus silicate impurities. We calculated partitioning of Be between solids and solutes, and rates of catchment‐wide (from sediment) and point source (from soil) denudation, weathering and erosion. Our results indicate that average denudation rates are 300–500 t/km 2 /yr. Denudation is dominated by weathering intensity (W/D) ratios of >0.92, and a non‐negligible contribution from deeper (below soil) weathering. Our rates agree to within less than a factor of two with decadal‐scale denudation rates from combined suspended and dissolved fluxes, highlighting the substantial potential of this method for future Earth surface studies

Submarine record of volcanic island construction and collapse in the Lesser Antilles arc: First scientific drilling of submarine volcanic island landslides by IODP Expedition 340

IODP Expedition 340 successfully drilled a series of sites offshore Montserrat, Martinique and Dominica in the Lesser Antilles from March to April 2012. These are among the few drill sites gathered around volcanic islands, and the first scientific drilling of large and likely tsunamigenic volcanic island-arc landslide deposits. These cores provide evidence and tests of previous hypotheses for the composition and origin of those deposits. Sites U1394, U1399, and U1400 that penetrated landslide deposits recovered exclusively seafloor-sediment, comprising mainly turbidites and hemipelagic deposits, and lacked debris avalanche deposits. This supports the concepts that i/ volcanic debris avalanches tend to stop at the slope break, and ii/ widespread and voluminous failures of pre-existing low-gradient seafloor sediment can be triggered by initial emplacement of material from the volcano. Offshore Martinique (U1399 and 1400), the landslide deposits comprised blocks of parallel strata that were tilted or micro-faulted, sometimes separated by intervals of homogenized sediment (intense shearing), while Site U1394 offshore Montserrat penetrated a flat-lying block of intact strata. The most likely mechanism for generating these large-scale seafloor-sediment failures appears to be propagation of a decollement from proximal areas loaded and incised by a volcanic debris avalanche. These results have implications for the magnitude of tsunami generation. Under some conditions, volcanic island landslide deposits comprised of mainly seafloor sediment will tend to form smaller magnitude tsunamis than equivalent volumes of subaerial block-rich mass flows rapidly entering water. Expedition 340 also successfully drilled sites to access the undisturbed record of eruption fallout layers intercalated with marine sediment which provide an outstanding high-resolution dataset to analyze eruption and landslides cycles, improve understanding of magmatic evolution as well as offshore sedimentation processes. This article is protected by copyright. All rights reserved