Impact of lithium composition on the thermoelectric properties of the layered cobalt oxide system LixCoO2

Thermoelectric properties of the layered cobalt oxide system LixCoO2 were investigated in a wide range of Li composition, 0.98 >= x >= 0.35. Single-phase bulk samples of LixCoO2 were successfully obtained through electrochemical deintercalation of Li from the pristine LiCoO2 phase. While LixCoO2 with x >= 0.94 is semiconductive, the highly Li-deficient phase (0.75 >= x >= 0.35) exhibits metallic conductivity. The magnitude of Seebeck coefficient at 293 K (S293K) significantly depends on the Li content (x). The S293K value is as large as +70 ~ +100 uV/K for x >= 0.94, and it rapidly decreases from +90 uV/K to +10 uV/K as x is lowered within a Li composition range of 0.75 >= x >= 0.50. This behavior is in sharp contrast to the results of x <= 0.40 for which the S293K value is small and independent of x (+10 uV/K), indicating that a discontinuous change in the thermoelectric characteristics takes place at x = 0.40 ~ 0.50. The unusually large Seebeck coefficient and metallic conductivity are found to coexist in a narrow range of Li composition at about x = 0.75. The coexistence, which leads to an enhanced thermoelectric power factor, may be attributed to unusual electronic structure of the two-dimensional CoO2 block.Comment: 29 pages, 1 table, 8 figure

Insights from in situ and environmental TEM on the oriented attachment of α-Fe₂O₃ nanoparticles during α-Fe₂O₃ nanorod formation

Acicular α-Fe2O3 nanorods (NRs), at an intermediate stage of development, were isolated using a snapshot valve-assisted hydrothermal synthesis (HS) technique, for the purpose of complementary in situ transmission electron microscopy (iTEM) and environmental TEM (ETEM) investigations of the effect of local environment on the oriented attachment (OA) of α-Fe2O3 nanoparticles (NPs) during α-Fe2O3 NR growth. Observations of static snapshot HS samples suggested that α-Fe2O3 NPs undergo reorientation following initial attachment, consistent with an intermediate OA stage, prior to ‘envelopment’ with the developing NR to adopt a perfect single crystal. Conversely, the heating of partially developed α-Fe2O3 NRs up to 250 °C, under vacuum, during iTEM, demonstrated the progressive coalescence of loosely packed α-Fe2O3 NPs and the coarsening of α-Fe2O3 NRs, without any direct evidence for an intermediate OA stage. Direct evidence was obtained for the action of an OA mechanism prior to the consumption of α-Fe2O3 NPs at the tips of developing α-Fe2O3 NRs during ETEM investigation, under an He pressure of 5 mbar at 500 °C. However, α-Fe2O3 NPs more strongly attached to the side-walls of developing α-Fe2O3 NRs were more likely to be consumed through a local NP destabilisation and reordering process, in the absence of an OA mechanism. Hence, the emerging ETEM evidence suggests a competition between OA and diffusion processes at the α-Fe2O3 NP coalescence stage of acicular α-Fe2O3 NR crystal development, depending on whether the localised growth conditions facilitate freedom of NP movement

Spatial Structure and Coherent Motion in Dense Planetary Rings Induced by Self-Gravitational Instability

We investigate the formation of spatial structure in dense, self-gravitating particle systems such as Saturn's B-ring through local $N$-body simulations to clarify the intrinsic physics based on individual particle motion. In such a system, Salo (1995) showed that the formation of spatial structure such as wake-like structure and particle grouping (clump) arises spontaneously due to gravitational instability and the radial velocity dispersion increases as the formation of the wake structure. However, intrinsic physics of the phenomena has not been clarified. We performed local $N$-body simulations including mutual gravitational forces between ring particles as well as direct (inelastic) collisions with identical (up to $N\sim40000$) particles. In the wake structure particles no longer move randomly but coherently. We found that particle motion was similar to Keplerian motion even in the wake structure and that the coherent motion was produced since the particles in a clump had similar eccentricity and longitude of perihelion. This coherent motion causes the increase and oscillation in the radial velocity dispersion. The mean velocity dispersion is rather larger in a more dissipative case with a smaller restitution coefficient and/or a larger surface density since the coherence is stronger in the more dissipative case. Our simulations showed that the wavelength of the wake structure was approximately given by the longest wavelength \hs{\lambda}{cr} = 4\pi^2 G\Sigma/\kappa^2 in the linear theory of axisymmetric gravitational instability in a thin disk, where $G$, $\Sigma$, and $\kappa$ are the gravitational constant, surface density, and a epicyclic frequency.Comment: Accepted by Earth, Planets, and Space. 39 pages, 20 figures. PostScript files also available from http://www.geo.titech.ac.jp/nakazawalab/hdaisaka/works

Long distance decoy state quantum key distribution in optical fiber

The theoretical existence of photon-number-splitting attacks creates a security loophole for most quantum key distribution (QKD) demonstrations that use a highly attenuated laser source. Using ultra-low-noise, high-efficiency transition-edge sensor photodetectors, we have implemented the first version of a decoy-state protocol that incorporates finite statistics without the use of Gaussian approximations in a one-way QKD system, enabling the creation of secure keys immune to photon-number-splitting attacks and highly resistant to Trojan horse attacks over 107 km of optical fiber.Comment: 4 pages, 3 figure

An Approximation for the rp-Process

Hot (explosive) hydrogen burning or the Rapid Proton Capture Process (rp-process) occurs in a number of astrophysical environments. Novae and X-ray bursts are the most prominent ones, but accretion disks around black holes and other sites are candidates as well. The expensive and often multidimensional hydro calculations for such events require an accurate prediction of the thermonuclear energy generation, while avoiding full nucleosynthesis network calculations. In the present investigation we present an approximation scheme applicable in a temperature range which covers the whole range of all presently known astrophysical sites. It is based on the concept of slowly varying hydrogen and helium abundances and assumes a kind of local steady flow by requiring that all reactions entering and leaving a nucleus add up to a zero flux. This scheme can adapt itself automatically and covers situations at low temperatures, characterized by a steady flow of reactions, as well as high temperature regimes where a $(p,\gamma)-(\gamma,p)$-equilibrium is established. In addition to a gain of a factor of 15 in computational speed over a full network calculation, and an energy generation accurate to more than 15 %, this scheme also allows to predict correctly individual isotopic abundances. Thus, it delivers all features of a full network at a highly reduced cost and can easily be implemented in hydro calculations.Comment: 18 pages, LaTeX using astrobib and aas2pp4, includes PostScript figures; Astrophysical Journal, in press. PostScript source also available at http://quasar.physik.unibas.ch/preps.htm

Local well-posedness for the nonlinear Schr\"odinger equation in the intersection of modulation spaces Mp,qs(Rd)∩M∞,1(Rd)M_{p, q}^s(\mathbb{R}^d) \cap M_{\infty, 1}(\mathbb{R}^d)

We introduce a Littlewood-Paley characterization of modulation spaces and use it to give an alternative proof of the algebra property, somehow implicitly contained in Sugimoto (2011), of the intersection $M^s_{p,q}(\mathbb{R}^d) \cap M_{\infty, 1}(\mathbb{R}^d)$ for $d \in \mathbb{N}$, $p, q \in [1, \infty]$ and $s \geq 0$. We employ this algebra property to show the local well-posedness of the Cauchy problem for the cubic nonlinear Schr\"odinger equation in the above intersection. This improves Theorem 1.1 by B\'enyi and Okoudjou (2009), where only the case $q = 1$ is considered, and closes a gap in the literature. If $q > 1$ and $s > d \left(1 - \frac{1}{q}\right)$ or if $q = 1$ and $s \geq 0$ then $M^s_{p,q}(\mathbb{R}^d) \hookrightarrow M_{\infty, 1}(\mathbb{R}^d)$ and the above intersection is superfluous. For this case we also reobtain a H\"older-type inequality for modulation spaces.Comment: 14 page

Two-Component Fokker-Planck Models for the Evolution of Isolated Globular Clusters

Two-component (normal and degenerate stars) models are the simplest realization of clusters with a mass spectrum because high mass stars evolve quickly into degenerates, while low mass stars remain on the main-sequence for the age of the universe. Here we examine the evolution of isolated globular clusters using two-component Fokker-Planck (FP) models that include heating by binaries formed in tidal capture and in three-body encounters. Three-body binary heating dominates and the postcollapse expansion is self-similar, at least in models with total mass M <= 3 x 10^5 M_\odot, initial half-mass radius r_{h,i} >= 5 pc, component mass ratio m_2/m_1 <= 2, and number ratio N_1/N_2 <= 300 when m_2=1.4 M_\odot. We derive scaling laws for \rho_c, v_c, r_c, and r_h as functions of m_1/m_2, N, M, and time t from simple energy-balance arguments, and these agree well with the FP simulations. We have studied the conditions under which gravothermal oscillations (GTOs) occur. If E_{tot} and E_c are the energies of the cluster and of the core, respectively, and t_{rh} and t_c are their relaxation times, then \epsilon \equiv (E_{tot}/t_{rh})/(E_c/t_{rc}) is a good predictor of GTOs: all models with \epsilon>0.01 are stable, and all but one with \epsilon < 0.01 oscillate. We derive a scaling law for \epsilon against N and m_1/m_2 and compared with our numerical results. Clusters with larger m_2/m_1 or smaller N are stabler.Comment: 15 pages (LaTeX) with 8 figures. To appear in ApJ March 10, 1998 issu

Eddington-limited X-ray Bursts as Distance Indicators. I. Systematic Trends and Spherical Symmetry in Bursts from 4U 1728-34

We investigate the limitations of thermonuclear X-ray bursts as a distance indicator for the weakly-magnetized accreting neutron star 4U 1728-34. We measured the unabsorbed peak flux of 81 bursts in public data from the Rossi X-Ray Timing Explorer (RXTE). The distribution of peak fluxes was bimodal: 66 bursts exhibited photospheric radius expansion and were distributed about a mean bolometric flux of 9.2e-8 erg/cm^2/s, while the remaining (non-radius expansion) bursts reached 4.5e-8 erg/cm^2/s, on average. The peak fluxes of the radius-expansion bursts were not constant, exhibiting a standard deviation of 9.4% and a total variation of 46%. These bursts showed significant correlations between their peak flux and the X-ray colors of the persistent emission immediately prior to the burst. We also found evidence for quasi-periodic variation of the peak fluxes of radius-expansion bursts, with a time scale of approximately 40 d. The persistent flux observed with RXTE/ASM over 5.8 yr exhibited quasi-periodic variability on a similar time scale. We suggest that these variations may have a common origin in reflection from a warped accretion disk. Once the systematic variation of the peak burst fluxes is subtracted, the residual scatter is only approximately 3%, roughly consistent with the measurement uncertainties. The narrowness of this distribution strongly suggests that i) the radiation from the neutron star atmosphere during radius-expansion episodes is nearly spherically symmetric, and ii) the radius-expansion bursts reach a common peak flux which may be interpreted as a standard candle intensity.Adopting the minimum peak flux for the radius-expansion bursts as the Eddington flux limit, we derive a distance for the source of 4.4-4.8 kpc.Comment: 9 pages, 7 figures, accepted by ApJ. Minor referee's revisions, also includes 9 newly public X-ray burst

High prevalence of bronchiectasis is linked to HTLV-1-associated inflammatory disease.

BACKGROUND: Human T-lymphotropic virus type 1 (HTLV-1), a retrovirus, is the causative agent of HTLV-1-associated myelopathy/tropical spastic paraparesis (HAM/TSP) and adult T-cell leukaemia/lymphoma (ATLL). The reported association with pulmonary disease such as bronchiectasis is less certain. METHODS: A retrospective case review of a HTLV-1 seropositive cohort attending a national referral centre. The cohort was categorised into HTLV-1 symptomatic patients (SPs) (ATLL, HAM/TSP, Strongyloidiasis and HTLV associated inflammatory disease (HAID)) and HTLV-1 asymptomatic carriers (ACs). The cohort was reviewed for diagnosis of bronchiectasis. RESULT: 34/246 ACs and 30/167 SPs had been investigated for respiratory symptoms by computer tomography (CT) with productive cough +/- recurrent chest infections the predominant indications. Bronchiectasis was diagnosed in one AC (1/246) and 13 SPs (2 HAID, 1 ATLL, 10 HAM/TSP) (13/167, RR 19.2 95 % CI 2.5-14.5, p = 0.004) with high resolution CT. In the multivariate analysis ethnicity (p = 0.02) and disease state (p < 0.001) were independent predictors for bronchiectasis. The relative risk of bronchiectasis in SPs was 19.2 (95 % CI 2.5-14.5, p = 0.004) and in HAM/TSP patients compared with all other categories 8.4 (95 % CI 2.7-26.1, p = 0.0002). Subjects not of African/Afro-Caribbean ethnicity had an increased prevalence of bronchiectasis (RR 3.45 95 % 1.2-9.7, p = 0.02). CONCLUSIONS: Bronchiectasis was common in the cohort (3.4 %). Risk factors were a prior diagnosis of HAM/TSP and ethnicity but not HTLV-1 viral load, age and gender. The spectrum of HTLV-associated disease should now include bronchiectasis and HTLV serology should be considered in patients with unexplained bronchiectasis

Tachyon Kinks in Boundary String Field Theory

We study tachyon kinks with and without electromagnetic fields in the context of boundary string field theory. For the case of pure tachyon only an array of kink-antikink is obtained. In the presence of electromagnetic coupling, all possible static codimension-one soliton solutions such as array of kink-antikink, single topological BPS kink, bounce, half kink, as well as nonBPS topological kink are found, and their properties including the interpretation as branes are analyzed in detail. Spectrum of the obtained kinks coincides with that of Dirac-Born-Infeld type effective theory.Comment: LaTex, 29 pages, 17 Figure