Petrochemistry and mineral chemistry studies on metamorphic ultramafic rocks in Yanghou area, Zhenghe Country, Fujian Province, China

Petrochemistry studies indicate that the Yanghou metamorphic ultramafic rocksare composed of metamorphosed harzburgite and burgite and ultramafic cumulate . Trace element geochemistry and mineral chemistry studies on the metamorphosed harzburgite indicate that it is the relict of the depleted mantle. From systematic studies on petrochemistry , mineral chemistry and geochronology, it s concluded that the Yanghou metamorphic ultramafic rocks are components of Later Sinian-Early Paleozoic ophiolite in South China.岩石化学研究表明, 洋后变质超镁铁岩是由变质方辉橄榄岩和变质超镁铁堆积岩组成。变质方辉橄榄岩的微量元素地球化学及矿物化学特征表明, 应为亏损的残余地慢产物。通过系统的岩石地球化学、矿物化学及年代学研究, 认为洋后变质超镁铁岩可能为华南晚震旦一早古生代的蛇绿岩组成部分。published_or_final_versio

珊瑚中微量铀的ID-ICP-MS 高精度测定及其在珊瑚U/Ca 温度计研究中的应用

建立了同位素稀释技术与IC-MS 相结合的ID-ICP-MS 分析方法, 成功测量了取自南海北部的滨珊瑚样品中的微量铀, 获得0.5% 左右的精度。并以此建立南海北部近岸海域的珊瑚U/Ca 温度计, 其温度精度可达士0.5 ℃。ID-ICP-MS, an analytical method that combines isotope dilution technique and ICP-MS method had been developed in our laboratory. Trace uranium of the coral samples from the northern area of the South China Sea had been measured to an accuracy of 0.5%. Depended on these results, a high resolution coral U/Ca thermometer for thes area was established. Monthly average SSTs with a precision of ±0.5℃ were attainable by this U/Ca thermometer.published_or_final_versio

汉诺坝玄武岩中麻粒岩和辉石岩捕虏体Sr-Nd-Pb同位素五维空间特征及其地质意义

研究了汉诺坝玄武岩中麻粒岩和辉石岩捕虏体在Sr-Nd-Pb同位素五维空间中的特征 .结合捕虏体的空间分布相对位置, 认为层离作用可较好地解释不同类型捕虏体同位素之间的相互关系。published_or_final_versio

南海北部珊瑚Ba/Ca比值的季节变化及其环境意义

利用等离子体质谱技术分析了取自海南岛南部沿岸的现代滨珊瑚高分辨率的Ba／Ca比值。结果表明，该珊瑚的Ba／Ca比值具有明显的双峰态的季节变化，其中春季和秋季Ba／Ca比值较高，而冬、夏两季则较低。海南岛南部及邻近地区季节降雨的变化所控制的陆源Ba输入是这些珊瑚Ba／Ca比值变化的重要控制因素，而该区夏季相对较高的表层海水生产力可能也对其有重要影响。High-resolution Ba/Ca ratios of a modern Porites coral from Sanya Bay, offshore of Hainan Island, were measured by ICP-MS. The results exhibit seasonal periodical ventilation of the coralline Ba/Ca ratios with higher Ba/ca ratios in spring and autumn and lower in winter and summer. variation of the terrestrial Ba flux to this area,which was controlled by seasonal precipitation of Southern Hainan Island and surmunded areas, is the key role to these Ba/Ca patterns. On the other hand, the relatively high surface productivity of the area in summer may contribute to the lower Ba/Ca ratios of the coral.postprin

Sr, Nd Pb isotopic characteristics of granulite and pyroxenite xenoliths in Hannuoba basalts, Hebei Province, and their implications for geologic processes

Rb-Sr, Sm-Nd and Pb isotopic systematics are reported for granulite and pyroxenite xenoliths in Hannuoba basalts, Hebei Province. The isotopic characteristics of xenoliths suggest t hat they might have formed recently , although there is no strict constraint on the precise age. The decoupling of low Rb/Sr and high [87]Sr/[86]Sr ratios implies the multi-stage evolution history and strong mixing processes. There are close ties between granulite and pyroxenites with different mineral assemblages on the Sr-Nd, Pb-Sr and Pb-Nd correlation figures. The granulite is the common end-member o f the three kinds o f pyroxenite. Combined with the distribution of the xenoliths in space and their isotopic relationships, It is proposed that delamination can be well used to explain the ties.系统研究了河北汉诺坝玄武岩中二辉麻粒岩和辉石岩捕虏体的Sr、Nd、Pb 同位素特征。虽然未确定捕虏体的形成时代, 但同位素特征显示它们可能为较近期( 中生代以来) 形成。低的Rb/Sr 与高 的[87]Sr/[86]Sr 比值的解耦表明捕虏体的形成经历了较强的混合作用。在二元同位素相关图上, 三类具不同矿物组成的辉石岩与二辉麻粒岩有密切关系, 即二辉麻粒岩投点位置是三类辉石岩的共同端点。综合考虑捕虏体的空间分布及其在Sr 、Nd、Pb 同位素协变图上的关系, 可以认为层离作用可较好地解释这些现象。published_or_final_versio

Precise Sm-Nd and U-Pb isotopic dating of the supergiant Shizhuyuan polymetallic deposit and its host granite, SE China

The supergiant Shizhuyuan W-Sn-Bi-Mo deposit is hosted by the Qianlishan granite, a small, highly fractionated granitic pluton (~10 km2) with multiple phases of intrusions within the Early Yanshanian granitoid province of SE China. Strong alteration of skarn and greisen that formed in the contact zone between the first and second phases of granite intrusions and Devonian limestone is responsible for the polymetallic mineralizations. SHRIMP U-Pb zircon analysis indicates that the two early phases of the Qianlishan granite formed contemporaneously at 152 ± 2 Ma. Metasomatic minerals (garnet, fluorite and wolframite) separated from the skarn and greisen yield a Sm-Nd isochron age of 149 ± 2 Ma that is interpreted as the formation age of the Shizhuyuan deposit. Therefore, the mineralization of the supergiant Shizhuyuan polymetallic deposit formed contemporaneously with, or very shortly after, the intrusion of the small, highly fractionated Qianlishan granite. © 2004 Cambridge University Press.published_or_final_versio

Highly heterogeneous Late Mesozoic lithospheric mantle beneath the North China Craton: evidence from Sr–Nd–Pb isotopic systematics of mafic igneous rocks

The lithospheric mantle beneath the North China Craton changed dramatically in its geophysical and geochemical characteristics from Palaeozoic to Cenozoic times. This study uses samples of Mesozoic basalts and mafic intrusions from the North China Craton to investigate the nature of this mantle in Mesozoic times. Sr-Nd-Pb isotopic data demonstrate that the Late Mesozoic lithospheric mantle was extremely heterogeneous. In the central craton or the Luzhong region, it is slightly Sr-Nd isotopically enriched, beneath the Taihangshan region it has an EMI character (87Sr/86Sri = 0.7050-0.7066; εNd = -17--10), and beneath the Luxi-Jiaodong region, it possesses EM2-like characteristics (87Sr/86Sri up to 0.7114). Compositional variation with time is also apparent in the Mesozoic lithospheric mantle. Our data suggest that the old lithospheric mantle was modified during Mesozoic times by a silicic melt, where beneath the Luxi-Jiaodong region it was severely modified, but in the Luzhong and Taihangshan regions the effects were much less marked. The silicic melt may have been the product of partial melting of crustal materials brought into the mantle by the subducted slab during the formation of circum-cratonic orogenic belts. This Mesozoic mantle did not survive for a long time, and was replaced by a Cenozoic mantle with depleted geochemical characteristics. © 2004 Cambridge University Press.published_or_final_versio

Preliminary study on TIMS U-Th dating technique and their application

Thermal ionization mass spectrometry (TIMS) U-Th technique in dating purecarbonate has been established in our laboratory and was used to determine the ages of the Holocene coral samples from the South China Sea and a National Reference Material of uranium-series, GBW04413. The TIMS results of GBW04413 are in good agreement with their reference data determined from α-couning, indication that the ages by TIMS U-Th method are reliable. The TIMS ages of the coral samples older than 5ka have slightly older TIMS U-Th ages than their [14] C ages, which agrees with previous studies [12, 13, 16].尝试了用热电离质谱方法测定南海第四纪珊瑚的U- Th 年龄, 并利用国家铀系年龄标准物质GBW04413 来监测分析结果的合理性。结果显示, GBW04413 的TIMS 年龄与作为推荐值的A记数方法测定结果一致, 反映出其可靠性; 而年龄在1ka 左右的珊瑚样品的TIMS 年龄与14C 年龄一致, >5ka 样品的TIMS 年龄老于14C 年龄, 体现两种方法的系统差别。published_or_final_versio

下地壳及壳慢过渡带化学不均一性 -- 河北汉诺坝地区深源捕虏体元素地球化学证据

河北汉诺坝玄武岩中长英质麻粒岩、镁铁质麻粒岩和辉石岩捕虏体的主量元素和微量元素特征, 反映了下地壳及壳鳗过渡带组成具有高度化学不均一性。不相容元素原始地慢标准化曲线特征的差异表明捕虏体成因复杂。MgO 与不相容元素无或仅有很弱的相关性, 与相容元素的相关性则相对较明显。这些特征反映了下地壳及壳慢过渡带存在较强和多元的混合作用。捕虏体的加权平均值比基于麻粒岩地体资料估算的下地壳平均组成偏基性, 揭示了二者可能的成因差异。The major and trace element data of granulite and pyroxenite xenoliths, which are entrained in Hannuoba basalt Hebei Province, North China, suggest the highly chemical heterogeneity in the lower crust and crust-mantle transitional zone. There is no or only POor linear correlation between MgO and incompatible elements. Whereas a bit remarked correlations are observed between MgO and most compatible elements.The geochemical characteristics suggest that the strong and multiple mixing processes may have Occurred universally both in the lower crust and crust-mantle transitional zone. The weighed average composition of xenoliths shows a more mafic composition of the lower crust than that estimated from granulite data, which may imply the difference in the genesis.published_or_final_versio

Coralline Sr/Ca and Mg/Ca thermometer for the northern South China Sea: calibration and primary application high resolution on high-resolution SST reconstructing

利用全谱直读等离子体光谱(ICP2AES) 的分析方法精确分析了南海珊瑚的SrPCa 和MgPCa 比值,结合实测表层海水温度(SST),标定了海南岛南部三亚海域和西沙海域两个滨珊瑚的SrPCa 和MgPCa 温度计。在此基础上,尝试对两个南海北部全新世时期的珊瑚进行SST记录重建。结果显示约540aB.P. (小冰期) 西沙海域夏季月均SST 较现代低约1℃,而约6 500aB.P. (大暖期) 海南岛三亚海域夏季月均SST则高出现代1.0～1.5℃。The method for precisely and simultaneously measuring the coralline Sr/Ca and Mg/Ca ratios was established using inductively coupled plasma atomic emission spectrometry (ICP-AES). Using this method, the high-resolution Sr/Ca and Mg/Ca ratios of two Porites lutea from Sanya, South Hainan Island and Xisha Islands were measured. By comparing to the instrumentally measured sea surface temperatures in these two areas, the coralline Sr/Ca thermometer and the Mg/Ca thermometer were calibrated. These two thermometers can provide SST records with an error bar < 0.2℃, and they are suitable for high-resolution SST reconstructions in these areas. Based on these two thermometers, two short SST records were reconstructed from two Holocene Porites corals of the northern South China Sea. The results indicated that the monthly summer SSTs in Xisha Islands at about 540 years ago (the Little Ice Age) were 1℃ lower than that at present, and the monthly summer SSTs in Sanya, southern Hainan Island at 6 500 years ago (the Megathermal) were about 1℃ to 1 5℃ higher than that at present.published_or_final_versio