Multiscale Mass-Spring Models of Carbon Nanotube Arrays Accounting for Mullins-like Behavior and Permanent Deformation

Based on a one-dimensional discrete system of bistable springs, a mechanical model is introduced to describe plasticity and damage in carbon nanotube (CNT) arrays. The energetics of the mechanical system are investigated analytically, the stress-strain law is derived, and the mechanical dissipation is computed, both for the discrete case as well as for the continuum limit. An information-passing approach is developed that permits the investigation of macroscopic portions of the material. As an application, the simulation of a cyclic compression experiment on real CNT foam is performed, considering both the material response during the primary loading path from the virgin state and the damaged response after preconditioning

The removal of thermally aged films of triacylglycerides by surfactant solutions

Thermal ageing of triacylglycerides (TAG) at high temperatures produces films which resist removal using aqueous surfactant solutions. We used a mass loss method to investigate the removal of thermally aged TAG films from hard surfaces using aqueous solutions of surfactants of different charge types. It was found that cationic surfactants are most effective at high pH, whereas anionics are most effective at low pH and a non-ionic surfactant is most effective at intermediate pH. We showed that the TAG film removal process occurs in several stages. In the first ‘‘lag phase’’ no TAG removal occurs; the surfactant first partitions into the thermally aged film. In the second stage, the TAG film containing surfactant was removed by solubilisation into micelles in the aqueous solution. The effects of pH and surfactant charge on the TAG removal process correlate with the effects of these variables on the extent of surfactant partitioning to the TAG film and on the maximum extent of TAG solubilisation within the micelles. Additionally, we showed how the TAG removal is enhanced by the addition of amphiphilic additives such as alcohols which act as co-surfactants. The study demonstrates that aqueous surfactant solutions provide a viable and more benign alternative to current methods for the removal of thermally aged TAG films

Multidimensional Gaussian sums arising from distribution of Birkhoff sums in zero entropy dynamical systems

A duality formula, of the Hardy and Littlewood type for multidimensional Gaussian sums, is proved in order to estimate the asymptotic long time behavior of distribution of Birkhoff sums $S_n$ of a sequence generated by a skew product dynamical system on the $\mathbb{T}^2$ torus, with zero Lyapounov exponents. The sequence, taking the values $\pm 1$, is pairwise independent (but not independent) ergodic sequence with infinite range dependence. The model corresponds to the motion of a particle on an infinite cylinder, hopping backward and forward along its axis, with a transversal acceleration parameter $\alpha$. We show that when the parameter $\alpha /\pi$ is rational then all the moments of the normalized sums $E((S_n/\sqrt{n})^k)$, but the second, are unbounded with respect to n, while for irrational $\alpha /\pi$, with bounded continuous fraction representation, all these moments are finite and bounded with respect to n.Comment: To be published in J. Phys.

Listening to ironically-enjoyed music: A self-regulatory perspective

This research examines adults’ reported motivations for listening to music that they enjoy ironically. In a pilot (N = 96) and main (N = 175) studies, open-ended responses from adults were analysed using Thematic Analysis. Based on the pilot study, ironically enjoyed music was defined as “Music that is enjoyed because of being bad, despite being bad, or for different reasons than intended.” Although many relevant self-regulatory functions of listening to music in general were also relevant to ironically- enjoyed music, it also emerged that ironic enjoyment of music has characteristics that are unique to it: the additional role of mocking, ridiculing, and laughing at the music, and the social benefit that this provides. Music that was listened to “because of” its negative features had a variety of musical features, and the listening usually served functions unique to ironic enjoyment of music, such as mockery. When music was listened to “despite” negative qualities, the music itself was often described as having attractive rhythm, melody or lyrics, while the irony protected the listener from conflicting values associated with the music, helping the listener communicate to others that they did not identify with the music on a higher level. Unfamiliar music mainly played a social role, whereas familiar music related to nostalgia as well as most other functions

Initial Observations of Lunar Impact Melts and Ejecta Flows with the Mini-RF Radar

The Mini-RF radar on the Lunar Reconnaissance Orbiter's spacecraft has revealed a great variety of crater ejecta flow and impact melt deposits, some of which were not observed in prior radar imaging. The craters Tycho and Glushko have long melt flows that exhibit variations in radar backscatter and circular polarization ratio along the flow. Comparison with optical imaging reveals that these changes are caused by features commonly seen in terrestrial lava flows, such as rafted plates, pressure ridges, and ponding. Small (less than 20 km) sized craters also show a large variety of features, including melt flows and ponds. Two craters have flow features that may be ejecta flows caused by entrained debris flowing across the surface rather than by melted rock. The circular polarization ratios (CPRs) of the impact melt flows are typically very high; even ponded areas have CPR values between 0.7-1.0. This high CPR suggests that deposits that appear smooth in optical imagery may be rough at centimeter- and decimeter- scales. In some places, ponds and flows are visible with no easily discernable source crater. These melt deposits may have come from oblique impacts that are capable of ejecting melted material farther downrange. They may also be associated with older, nearby craters that no longer have a radar-bright proximal ejecta blanket. The observed morphology of the lunar crater flows has implications for similar features observed on Venus. In particular, changes in backscatter along many of the ejecta flows are probably caused by features typical of lava flows

Evidence for Water Ice on the Moon: Results for Anomalous Polar Craters from the LRO Mini-RF Imaging Radar

The Mini-RF radar instrument on the Lunar Reconnaissance Orbiter spacecraft mapped both lunar poles in two different RF wavelengths (complete mapping at 12.6 cm S-band and partial mapping at 4.2 cm X-band) in two look directions, removing much of the ambiguity of previous Earth- and spacecraft-based radar mapping of the Moon's polar regions. The poles are typical highland terrain, showing expected values of radar cross section (albedo) and circular polarization ratio (CPR). Most fresh craters display high values of CPR in and outside the crater rim; the pattern of these CPR distributions is consistent with high levels of wavelength-scale surface roughness associated with the presence of block fields, impact melt flows, and fallback breccia. A different class of polar crater exhibits high CPR only in their interiors, interiors that are both permanently dark and very cold (less than 100 K). Application of scattering models developed previously suggests that these anomalously high-CPR deposits exhibit behavior consistent with the presence of water ice. If this interpretation is correct, then both poles may contain several hundred million tons of water in the form of relatively "clean" ice, all within the upper couple of meters of the lunar surface. The existence of significant water ice deposits enables both long-term human habitation of the Moon and the creation of a permanent cislunar space transportation system based upon the harvest and use of lunar propellant

3D printing of twisting and rotational bistable structures with tuning elements

Three-dimensional (3D) printing is ideal for the fabrication of various customized 3D components with fine details and material-design complexities. However, most components fabricated so far have been static structures with fixed shapes and functions. Here we introduce bistability to 3D printing to realize highly-controlled, reconfigurable structures. Particularly, we demonstrate 3D printing of twisting and rotational bistable structures. To this end, we have introduced special joints to construct twisting and rotational structures without post-assembly. Bistability produces a well-defined energy diagram, which is important for precise motion control and reconfigurable structures. Therefore, these bistable structures can be useful for simplified motion control in actuators or for mechanical switches. Moreover, we demonstrate tunable bistable components exploiting shape memory polymers. We can readjust the bistability-energy diagram (barrier height, slope, displacement, symmetry) after printing and achieve tunable bistability. This tunability can significantly increase the use of bistable structures in various 3D-printed components

Evidence for Water Ie on the Moon: Results for Anomalous Polar Craters from the LRO Mini-RF Imaging Radar

The Mini-RF radar instrument on the Lunar Reconnaissance Orbiter spacecraft mapped both lunar poles in two different RF wavelengths (complete mapping at 12.6 cm S-band and partial mapping at 4.2 cm X-band) in two look directions, removing much of the ambiguity of previous Earth- and spacecraft-based radar mapping of the Moon's polar regions. The poles are typical highland terrain, showing expected values of radar cross section (albedo) and circular polarization ratio (CPR). Most fresh craters display high values of CPR in and outside the crater rim; the pattern of these CPR distributions is consistent with high levels of wavelength-scale surface roughness associated with the presence of block fields, impact melt flows, and fallback breccia. A different class of polar crater exhibits high CPR only in their interiors, interiors that are both permanently dark and very cold (less than 100 K). Application of scattering models developed previously suggests that these anomalously high-CPR deposits exhibit behavior consistent with the presence of water ice. If this interpretation is correct, then both poles may contain several hundred million tons of water in the form of relatively "clean" ice, all within the upper couple of meters of the lunar surface. The existence of significant water ice deposits enables both long-term human habitation of the Moon and the creation of a permanent cislunar space transportation system based upon the harvest and use of lunar propellant

The clinical features of the piriformis syndrome: a systematic review

Piriformis syndrome, sciatica caused by compression of the sciatic nerve by the piriformis muscle, has been described for over 70 years; yet, it remains controversial. The literature consists mainly of case series and narrative reviews. The objectives of the study were: first, to make the best use of existing evidence to estimate the frequencies of clinical features in patients reported to have PS; second, to identify future research questions. A systematic review was conducted of any study type that reported extractable data relevant to diagnosis. The search included all studies up to 1 March 2008 in four databases: AMED, CINAHL, Embase and Medline. Screening, data extraction and analysis were all performed independently by two reviewers. A total of 55 studies were included: 51 individual and 3 aggregated data studies, and 1 combined study. The most common features found were: buttock pain, external tenderness over the greater sciatic notch, aggravation of the pain through sitting and augmentation of the pain with manoeuvres that increase piriformis muscle tension. Future research could start with comparing the frequencies of these features in sciatica patients with and without disc herniation or spinal stenosis

Consolidation of Geologic Studies of Geopressured-Geothermal Resources in Texas: Colocation of Heavy-Oil and Geothermal Resources in South Texas

In a five-county area of South Texas, geopressured-geothermal reservoirs in the Eocene Wilcox Group occur below heavy-oil reservoirs in the Eocene Jackson Group. This colocation warrants consideration of the use of geothermal fluids for a thermally enhanced waterflood. Geothermal fairways comprise thick deltaic sandstones within growth-fault-bounded compartments containing geopressured water in excess of 250°F. Geothermal reservoirs occur at depths of 11,000 to 15,000 ft in continuous sandstones 100 to 200 ft thick. Permeability ranges from 1 to 150 md, and porosity from 12 to 24 percent. Updip pinch-out of shallowly buried (200 to 2,000 ft) barrier-bar/strandplain sandstones largely controls the distribution of heavy-oil reservoirs. Subtle structure, small faults, and sandbody pinch-outs form lateral barriers of the reservoirs. Structural, depositional, and diagenetic variations affect reservoir compartmentalization. The heavy-oil reservoirs are typically porous (25 to 35 percent), permeable (100 to 1,000 md), slightly clayey fine to medium sand. Calcite-cemented zones of low porosity (>5 percent) and permeability (0.01 md) compartmentalize reservoirs. Injection of hot (300°F), moderately fresh to saline brines will improve oil recovery by lowering viscosity and decreasing residual oil saturation. Matrix clays are smectites, which could swell and clog pore throats if injected waters were fresh. The high temperature of injected fluids will collapse some of the interlayer clays, thus increasing porosity and permeability. Reservoir heterogeneity resulting from facies variation and diagenesis must be considered when siting production and injection wells within the heavy-oil reservoir. The suitability of abandoned gas wells as geothermal production wells and their long-term well productivity also affect the economics of geothermally enhanced hot-water flooding.Bureau of Economic Geolog