Exciton-optical-phonon coupling: comparison with experiments for ZnO quantum wells

The temperature-dependent linewidths of excitons in ZnO quantum wells were studied by measuring absorption spectra from 5 K to room temperature. We deduced experimentally the exciton-longitudinal-optical (LO) phonon coupling strength, which showed reduction of coupling with decrease in well width. This reduction was explained in terms of confinement-induced enhancement of the excitonic binding energy by comparing the binding energy dependence of calculated coupling strength.Comment: 5 pages, 2 figures, 1 table, accepted for publication in JA

Possible origin of 60-K plateau in the YBa2Cu3O(6+y) phase diagram

We study a model of YBa2Cu3O(6+y) to investigate the influence of oxygen ordering and doping imbalance on the critical temperature Tc(y) and to elucidate a possible origin of well-known feature of YBCO phase diagram: the 60-K plateau. Focusing on "phase only" description of the high-temperature superconducting system in terms of collective variables we utilize a three-dimensional semi microscopic XY model with two-component vectors that involve phase variables and adjustable parameters representing microscopic phase stiffnesses. The model captures characteristic energy scales present in YBCO and allows for strong anisotropy within basal planes to simulate oxygen ordering. Applying spherical closure relation we have solved the phase XY model with the help of transfer matrix method and calculated Tc for chosen system parameters. Furthermore, we investigate the influence of oxygen ordering and doping imbalance on the shape of YBCO phase diagram. We find it unlikely that oxygen ordering alone can be responsible for the existence of 60-K plateau. Relying on experimental data unveiling that oxygen doping of YBCO may introduce significant charge imbalance between CuO2 planes and other sites, we show that simultaneously the former are underdoped, while the latter -- strongly overdoped almost in the whole region of oxygen doping in which YBCO is superconducting. As a result, while oxygen content is increased, this provides two counter acting factors, which possibly lead to rise of 60K plateau. Additionally, our result can provide an important contribution to understanding of experimental data supporting existence of multicomponent superconductivity in YBCO.Comment: 9 pages, 8 figures, submitted to PRB, see http://prb.aps.or

Chemical potential jump between hole- and electron-doped sides of ambipolar high-Tc cuprate

In order to study an intrinsic chemical potential jump between the hole- and electron-doped high-Tc superconductors, we have performed core-level X-ray photoemission spectroscopy (XPS) measurements of Y0.38La0.62Ba1.74La0.26Cu3Oy (YLBLCO), into which one can dope both holes and electrons with maintaining the same crystal structure. Unlike the case between the hole-doped system La_2-xSrxCuO4 and the electron-doped system Nd_2-xCexCuO4, we have estimated the true chemical potential jump between the hole- and electron-doped YLBLCO to be ~0.8 eV, which is much smaller than the optical gaps of 1.4-1.7 eV reported for the parent insulating compounds. We attribute the reduced jump to the indirect nature of the charge-excitation gap as well as to the polaronic nature of the doped carriers.Comment: 4 pages, 3 figure

Precise calibration of Mg concentration in MgxZn1-xO thin films grown on ZnO substrates

The growth techniques for MgxZn1-xO thin films have advanced at a rapid pace in recent years, enabling the application of this material to a wide range of optical and electrical applications. In designing structures and optimizing device performances, it is crucial that the Mg content of the alloy be controllable and precisely determined. In this study, we have established laboratory-based methods to determine the Mg content of MgxZn1-xO thin films grown on ZnO substrates, ranging from the solubility limit of x ~ 0.4 to the dilute limit of x < 0.01. For the absolute determination of Mg content, Rutherford backscattering spectroscopy is used for the high Mg region above x = 0.14, while secondary ion mass spectroscopy is employed to quantify low Mg content. As a lab-based method to determine the Mg content, c-axis length is measured by X-ray diffraction and is well associated with Mg content. The interpolation enables the determination of Mg content to x = 0.023, where the peak from the ZnO substrate overlaps the MgxZn1-xO peak in standard laboratory equipment, and thus quantitative determination. At dilute Mg contents below x = 0.023, the localized exciton peak energy of the MgxZn1-xO films as measured by photoluminescence is found to show a linear Mg content dependence, which is well resolved from the free exciton peak of ZnO substrate down to x = 0.0043. Our results demonstrate that X-ray diffraction and photoluminescence in combination are appropriate methods to determine Mg content in a wide Mg range from x = 0.004 to 0.40 in a laboratory environment.Comment: 21 pages, 1 table, 7 figure

Manipulation of Topological States and Bulk Band Gap Using Natural Heterostructures of a Topological Insulator

We have performed angle-resolved photoemission spectroscopy on (PbSe)5(Bi2Se3)3m, which forms a natural multilayer heterostructure consisting of a topological insulator (TI) and an ordinary insulator. For m = 2, we observed a gapped Dirac-cone state within the bulk-band gap, suggesting that the topological interface states are effectively encapsulated by block layers; furthermore, it was found that the quantum confinement effect of the band dispersions of Bi2Se3 layers enhances the effective bulk-band gap to 0.5 eV, the largest ever observed in TIs. In addition, we found that the system is no longer in the topological phase at m = 1, pointing to a topological phase transition between m = 1 and 2. These results demonstrate that utilization of naturally-occurring heterostructures is a new promising strategy for realizing exotic quantum phenomena and device applications of TIs.Comment: 5 pages, 5 figure

Spectral shape analysis of ultraviolet luminescence in \textit{n}-type ZnO:Ga

Thin films of laser molecular-beam epitaxy grown \textit{n}-type Ga-doped ZnO were investigated with respect to their optical properties. Intense room-temperature photoluminescence (PL) in the near-band edge (NBE) region was observed. Moreover, its broadening of PL band was significantly larger than predicted by theoretical results modeled in terms of potential fluctuations caused by the random distribution of donor impurities. In addition, the lineshape was rather asymmetrical. To explain these features of the NBE bands, a vibronic model was developed accounting for contributions from a series of phonon replicas.Comment: 5 pages, 3 figures, 1 table, to appear in the Nov. 1st issue of J. Appl. Phys. (Scheduled Issue

Climatic Conditions for modelling the Northern Hemisphere ice sheets throughout the ice age cycle

International audienceThe ice sheet-climate interaction as well as the climatic response to orbital parameters and atmospheric CO2 concentration are examined in order to drive an ice sheet model throughout an ice age cycle. Feedback processes between ice sheet and atmosphere are analyzed by numerical experiments using a high resolution General Circulation Model (GCM) under different conditions at the Last Glacial Maximum. Among the proposed processes, the ice albedo feedback, the elevation-mass balance feedback and the desertification effect over the ice sheet were found to be the dominant processes for the ice-sheet mass balance. For the elevation-mass balance feedback, the temperature lapse rate over the ice sheet is proposed to be weaker than assumed in previous studies. Within the plausible range of parameters related to these processes, the ice sheet response to the orbital parameters and atmospheric CO2 concentration for the last glacial/interglacial cycle was simulated in terms of both ice volume and geographical distribution, using a three-dimensional ice-sheet model. Careful treatment of climate-ice sheet feedback is essential for a reliable simulation of the ice sheet changes during ice age cycles