The HI and Ionized Gas Disk of the Seyfert Galaxy NGC 1144 = Arp 118: A Violently Interacting Galaxy with Peculiar Kinematics

We present observations of the distribution and kinematics of neutral and ionized gas in NGC 1144, a galaxy that forms part of the Arp 118 system. Ionized gas is present over a huge spread in velocity (1100 km/s) in the disk of NGC 1144, but HI emission is detected over only 1/3 of this velocity range, in an area that corresponds to the NW half of the disk. In the nuclear region of NGC 1144, a jump in velocity in the ionized gas component of 600 km/s is observed. Faint, narrow HI absorption lines are also detected against radio sources in the SE part of the disk of NGC 1144, which includes regions of massive star formation and a Seyfert nucleus. The peculiar HI distribution, which is concentrated in the NW disk, seems to be the inverse of the molecular distribution which is concentrated in the SE disk. Although this may partly be the result of the destruction of HI clouds in the SE disk, there is circumstantial evidence that the entire HI emission spectrum of NGC 1144 is affected by a deep nuclear absorption line covering a range of 600 km/s, and is likely blueshifted with respect to the nucleus. In this picture, a high column-density HI stream is associated with the nuclear ionized gas velocity discontinuity, and the absorption effectively masks any HI emission that would be present in the SE disk of NGC 1144.Comment: manuscript, arp118.ps: 28 pages; 1 Table: arp118.tab1.ps; 16 Figures: arp118.fig1-16.ps; Accepted to Ap

Selectivity of C−H vs. C−F Bond Oxygenation by Homo- and Heterometallic Fe_4, Fe_3Mn, and Mn_4 Clusters

A series of tetranuclear [LM_3(HFArPz)_3OM'][OTf]_2 (M, M' = Fe or Mn) clusters that displays 3-(2-fluorophenyl)pyrazolate (HFArPz) as bridging ligand is reported. With these complexes manganese is demonstrated to facilitate C(sp^2)−F bond oxygenation via a putative terminal metal-oxo species. Moreover, the presence of both ortho C(sp^2)−H and C(sp^2)−F bonds in proximity provides an opportunity to investigate the selectivity of intramolecular C(sp^2)−X bond oxygenation (X = H or F) in these isostructural compounds. With iron as the apical metal center (M' = Fe) C(sp^2)−F bond oxygenation occurs almost exclusively, whereas with manganese (M' = Mn) the opposite reactivity is preferred