Crystallization in a dense suspension of self-propelled particles

Using Brownian dynamics computer simulations we show that a two-dimensional suspension of self-propelled ("active") colloidal particles crystallizes at sufficiently high densities. Compared to the equilibrium freezing of passive particles the freezing density is both significantly shifted and depends on the structural or dynamical criterion employed. In non-equilibrium the transition is accompanied by pronounced structural heterogeneities. This leads to a transition region between liquid and solid in which the suspension is globally ordered but unordered liquid-like "bubbles" still persist

Lattice Dynamics of Solid Cubane within the Quasi-Harmonic Approximation

Solid cubane, which is composed of weakly interacting cubic molecules, exhibits many unusual and interesting properties, such as a very large thermal expansion and a first-order phase transition at T$_{p}$=394 K from an orientationally-ordered phase of R$\bar{3}$ symmetry to a {\it non-cubic} disordered phase of the same symmetry with a volume expansion of 5.4%, among the largest ever observed. We study the lattice dynamics of solid cubane within the quasi-harmonic and rigid-molecule approximation to explain some of these unusual dynamical properties. The calculated phonon density of states, dispersion curves and thermal expansion agree surprisingly well with available experimental data. We find that the amplitude of thermally excited orientational excitations (i.e. librons) increases rapidly with increasing temperature and reaches about 35$^{\rm o}$ just before the orientational phase transition. Hence, the transition is driven by large-amplitude collective motions of the cubane molecules. Similarly the amplitude of the translational excitations shows a strong temperature dependence and reaches one tenth of the lattice constant at T=440 K. This temperature is in fair agreement with the experimental melting temperature of 405 K, indicating that the Lindemann criterion works well even for this unusual molecular solid.Comment: 15 pages, 6 figures (devoted to Prof. Ciraci in honor of his sixtieth birthday

Development of an Airborne Molecular Direct Detection Doppler Lidar for Tropospheric Wind Profiling

Global measurement of tropospheric winds is a key measurement for understanding atmospheric dynamics and improving numerical weather prediction. Global wind profiles remain a high priority for the operational weather community and also for a variety of research applications including studies of the global hydrologic cycle and transport studies of aerosols and trace species. In addition to space based winds, high altitude airborne Doppler lidar systems flown on research aircraft, UAV's or other advanced sub-orbital platforms would be of great scientific benefit for studying mesoscale dynamics and storm systems such as hurricanes. The Tropospheric Wind Lidar Technology Experiment (TWiLiTE) is a three year program to advance the technology readiness level of the key technologies and subsystems of a molecular direct detection wind lidar system by validating them, at the system level, in an integrated airborne lidar system. The TWiLiTE Doppler lidar system is designed for autonomous operation on the WB57, a high altitude aircraft operated by NASA Johnson. The WE357 is capable of flying well above the midlatitude tropopause so the downward looking lidar will measure complete profiles of the horizontal wind field through the lower stratosphere and the entire troposphere. The completed system will have the capability to profile winds in clear air from the aircraft altitude of 18 km to the surface with 250 m vertical resolution and < 3 mis velocity accuracy. Progress in technology development and status of the instrument design will be presented

Reaching out to the other side: Formal-linguistics-based SLA and Socio-SLA

Generative linguistics has long been concerned with the linguistic competence of the “ideal speaker-listener, in a completely homogeneous speech-community, who knows its language perfectly” (Chomsky 1965: 3). Research in formal-linguistics-based second language acquisition takes as its starting point the second language (L2) speaker's underlying mental representation. Here the factors of interest are influence of the learner's native language and, in generative SLA, the operation of innate linguistic mechanisms (Universal Grammar). Similar to methodology in formal syntax, lxSLA adopts techniques such as grammaticality judgment, comprehension and perception tasks supplementing spontaneously produced oral data. While there may be individual differences in oral production, tasks that tap learners' mental representations reveal commonalities across learners from a given native language background with the same amount/ type of exposure and age of initial L2 exposure. When it comes to phonology, age has long been a central factor with numerous comparative studies showing younger learners far outperforming older learners (see Piske et al. 2001). This paper discusses a case of possible non-acquisition by L2 children who had had considerable exposure to the L2. Children's non-acquisition is only apparent, and this allows us to consider the value of lxSLA methodology on the one hand, and and raises issues about what might be lacking in the current socio-SLA paradigm, on the other. We argue that only when we return to the cooperation that marked its birth in the 1960s will we have a comprehensive picture of SLA

Прогнозирование и определение температуры детали в процессе ИПА

Для повышения темпов внедрения и улучшения уровня контроля процесса ионно-плазменного азотирования разработана математическая модель влияния режимов азотирования на температуру подложки

Fluid-solid phase transitions in 3D complex plasmas under microgravity conditions

Phase behavior of large three-dimensional complex plasma systems under microgravity conditions onboard the International Space Station is investigated. The neutral gas pressure is used as a control parameter to trigger phase changes. Detailed analysis of structural properties and evaluation of three different melting/freezing indicators reveal that complex plasmas can exhibit melting by increasing the gas pressure. Theoretical estimates of complex plasma parameters allow us to identify main factors responsible for the observed behavior. The location of phase states of the investigated systems on a relevant equilibrium phase diagram is estimated. Important differences between the melting process of 3D complex plasmas under microgravity conditions and that of flat 2D complex plasma crystals in ground based experiments are discussed.Comment: 13 pages, 10 figures; submitted to Phys. Rev.

Crystallization in mass-asymmetric electron-hole bilayers

We consider a \textit{mass-asymmetric} electron and hole bilayer. Electron and hole Coulomb correlations and electron and hole quantum effects are treated on first princles by path integral Monte Carlo methods. For a fixed layer separation we vary the mass ratio $M$ of holes and electrons between 1 and 100 and analyze the structural changes in the system. While, for the chosen density, the electrons are in a nearly homogeneous state, the hole arrangement changes from homogeneous to localized, with increasing $M$ which is verified for both, mesoscopic bilayers in a parabolic trap and for a macroscopic system.Comment: 10 pages, latex (styles files included

Effectiveness of 0.05% oxymetazoline (Vicks Sinex Micromist) nasal spray in the treatment of objective nasal congestion demonstrated to 12h post-administration by magnetic resonance imaging

Introduction: This study aimed to assess the qualitative and quantitative utility of MRI imaging to illustrate the magnitude and duration of the effect of a standard 100 μg dose of oxymetazoline in a commercially available formulation that also contains aromatic oils. Methods: This was a randomized, open label, single dose, parallel group study in 21 adult male and female subjects who reported moderate to severe nasal congestion due to acute upper respiratory tract infection or hay fever. MRI scans were acquired using a 3T Philips Achieva scanner with a 16 channel head receive coil. High resolution MRI scans of the nasal turbinates were obtained immediately prior to dosing (baseline) and at approximately 1, 8, 10, 11, and 12 hours after dosing. The efficacy variables of primary interest were inferior turbinate total volume at 8 and 12 hours post-dosing. The secondary efficacy variables analysed were inferior turbinate total volume at 1, 10, and 11 hours post-dosing, middle turbinate total volume at 1, 8, 10, 11, and 12 hours post-dosing. Results: Changes from baseline volumes measured for the inferior and middle turbinates of subjects receiving the oxymetazoline formulation showed significant (P<0.05) decreases at all times up to and including 12 hours post-administration. No significant decreases from baseline were detected in subjects receiving a sham ‘spray’ (untreated control - spray bottles with no spray solution). Statistical ANCOVA results of inferior and middle turbinate volume indicated significant differences (P<0.05) at all measurement points up to and including 12 hours post-administration between the oxymetazoline treatment group and the untreated control with the only exception the middle turbinate volume at 10 hours (P=0.0896). The significant changes were likely to be clinically relevant though this was not measured in the study. No AEs were reported during this study and no other safety evaluations were made. Conclusions: This study showed that MRI assessment of nasal congestion in human volunteers is a robust, repeatable and viable measurement technique. The application of a 100 µg Vicks Sinex Micromist® nasal decongestant (0.05% oxymetazoline solution) delivered a highly significant reduction in inferior and middle turbinate volumes compared with the application of a control, measurable by the MRI method up to and including a 12 hour post-dose scan

Homotransplantation of the liver in a patientwith hepatoma and hereditary tyrosinemia

A girl with hereditary tyrosinemia, diagnosed at 6 months of age, was treated with a diet restricted inphenylalanine and tyrosine. At 91/2 years of age she developed an acutely enlarged liver and spleen, and the diagnosis of hepatocarcinoma was made. The patient received a liver transplant and tyrosine metabolites became normal while she was receiving a regular diet. Three months later, an infected thrombosis of the portal vein caused her death. Liver transplant appears to be an effective method of enzyme replacement in tyrosinemia and should be considered for prevention of hepatoma. © 1978 The C. V. Mosby Company