Calculating optical absorption spectra of thin polycrystalline films: Structural disorder and site-dependent van der Waals interaction

We propose a new approach for calculating the change of the absorption spectrum of a molecule when moved from the gas phase to a crystalline morphology. The so-called gas-to-crystal shift $\Delta{\cal E}_m$ is mainly caused by dispersion effects and depends sensitively on the molecule's specific position in the nanoscopic setting. Using an extended dipole approximation, we are able to divide $\Delta{\cal E}_m= -Q W_{m}$ in two factors where $Q$ depends only on the molecular species and accounts for all non-resonant electronic transitions contributing to the dispersion, while $W_m$ is a sum running over the position of all molecules expressing the site-dependence of the shift in a given molecular structure. The ability of our approach to predict absorption spectra is demonstrated using the example of polycrystalline films of 3,4,9,10-perylene-tetracarboxylic-diimide (PTCDI).Comment: 6 pages, 4 figure

Unbearable wearables

As wearable devices play an increasing role in the management of health and disease, adverse skin reactions to wearables have become more common. However, the management of allergic contact dermatitis is challenging and new treatment options more compatible with wearable devices are needed. In a 40-year-old woman with contact dermatitis to a continuous glucose monitoring device, topical clobetasol propionate 0.05% spray proved to be an effective treatment that was compatible with the application of adhesive wearables. This case demonstrates that spray formulations of topical steroids are a good option for the treatment of dermatitis under wearable devices such as continuous glucose monitors or ostomy appliance

Logistic Map Potentials

We develop and illustrate methods to compute all single particle potentials that underlie the logistic map, x --> sx(1-x) for 0<s<=4. We show that the switchback potentials can be obtained from the primary potential through functional transformations. We are thereby able to produce the various branches of the corresponding analytic potential functions, which have an infinite number of branch points for generic s>2. We illustrate the methods numerically for the cases s=5/2 and s=10/3

‘Clustering of exemptions’ as a collective action threat to herd immunity

In this paper, we examine the phenomenon of ‘clustering of exemptions’ to childhood vaccination, and the dangers this poses both to those exempted as well as the general population. We examine how clusters of exemptions might form through collective action as described by Thomas Schelling, and how religious groups who live in close proximity to one another can “self-select” in a way that exacerbates this phenomenon. Given the growing number of exemptions and the increasing visibility of the anti-vaccine movement, policy makers must be vigilant for dangerous clustering in order to avoid loss of herd immunity

Staining and peeling of the internal limiting membrane using a fluorescent dye (Rhodamine 6 G)

Aim: To assess whether low concentrations of a fluorescent dye such as Rhodamine 6G would help the unaided human eye visualise the vitreous and the internal limiting membrane (ILM) under standard halogen illumination.Material/methods: The UV/Vis absorption (E) and fluorescence (I) spectra of Rhodamine 6G in water were measured and compared with Indocyanine Green (ICG). Surgery was performed in two rhesus monkeys and consisted of standard pars plana vitrectomy with halogen light source used for illumination. Rhodamine 6G was diluted in balanced salt solution (BSS). A few drops of the dye in a concentration of 0.1% (307 mOsm) were applied over the posterior pole in the air-filled globe and washed out by irrigation after 1 min. Immediately after surgery, the globes were enucleated, fixated and prepared for histological evaluation.Results: In contrast to ICG, both the maximum of the absorption and emission of Rhodamin 6G are very much within the spectral sensitivity of the human eye. The Rhodamine 6G--BSS itself appears red in colour. Using a dye concentration of 0.1%, there was no visible red-staining of the ILM as such. As the dye was irrigated out with BSS, a marked green fluorescence of the fluid within the vitreous cavity was noted. With halogen illumination through a standard 20-gauge light pipe, the dye provided a sufficient green fluorescence to identify and safely remove the ILM and to clearly differentiate areas of peeled from non-peeled ILM. During light microscopy, eyes revealed a peeled ILM demarcation with no signs of acute retinal toxicity.Conclusion: The findings indicate that a fluorescent dye can be used for ILM peeling. Assuming that the fluorophore provides a high enough fluorescence quantum yield after adsorption to the ILM, much lower dye concentrations could be used compared with absorbent dyes, thereby minimising toxic effects

Herbicide-Resistant Soybeans in Arkansas: Lessons Learned and Future Direction

In Arkansas Delta soybean production, glyphosate resistant (GR) Palmer amaranth has significantly impacted weed management. The incidence of herbicide resistant (HR) weeds has farreaching crop science, economic, and communications implications, which have been explored by the corresponding expertise of our research team members to form a comprehensive literature review. The review was used to develop policy recommendations to address current and future HR genetically modified (GM) crop use and the associated issues. The review of crop science research indicated an overall increase in herbicide application, as well as an increase in weed management programs focused around glyphosate rather than the application of multiple herbicides. The review also revealed some management methods have potential to resolve the problem, including alternating herbicide application, avoiding sub-lethal rates, using “burn down” herbicides prior to planting, crop rotation, tillage, and zero tolerance weed policies. The use of fewer herbicides rather than multiple types creates a monopolistic edge for the companies producing those few herbicides, allowing greater market control. Crisis communication methods, including developing internal readiness, conducting needs assessments, developing a relevant message, and conveying the message through appropriate channels, can be used to develop a response to the issue that will best communicate necessary information to the target audience. The team used these findings to formulate policy recommendations, which include management, economic, and communication plans that may provide a starting point to address the issue

Weiterbildung von Managern und Führungskräften auf ökologisch wirtschaftenden Bauernhöfen

Are organic farms suited to offer educational training for managers and stakeholders working in leading positions in companies or institutions? Eight interviews with experts were carried out in 2007 and analysed by methods of qualitative social research. Substantial deficiencies of managers and executives lie in the field of soft skills and have their origin in the school system among other reasons. The basic precondition for a successful course/training is the transfer of items that were perceived and learned in daily life. The experts are convinced that organic farms are well suited to offer educational courses and seminars for managers and executives especially because of some characteristics of organic farming: holistic and systemic perception, ethical values, farm diversity, sustainability, exposure to time und bounds, coherences on different farm levels etc. The ways of performance can be different (conceptual design, participants, target group, topic, methodology, marketing, etc.). To assure sustainable success three parameters are essential: professionalism, reliability and exclusiveness

Sheaf theory for stacks in manifolds and twisted cohomology for S^1-gerbes

This is the first of a series of papers on sheaf theory on smooth and topological stacks and its applications. The main result of the present paper is the characterization of the twisted (by a closed integral three-form) de Rham complex on a manifold. As an object in the derived category it will be related with the push-forward of the constant sheaf from a S^1-gerbe with Dixmier-Douady class represented by the three-form. In order to formulate and prove this result we develop in detail the foundations of sheaf theory for smooth stacks.Comment: 39 pages, v2 typos corrected and references added. v3 confusion in 2.2.5 cleaned u