Spontaneous Formation of Stable Capillary Bridges for Firming Compact Colloidal Microstructures in Phase Separating Liquids: A Computational Study

Computer modeling and simulations are performed to investigate capillary bridges spontaneously formed between closely packed colloidal particles in phase separating liquids. The simulations reveal a self-stabilization mechanism that operates through diffusive equilibrium of two-phase liquid morphologies. Such mechanism renders desired microstructural stability and uniformity to the capillary bridges that are spontaneously formed during liquid solution phase separation. This self-stabilization behavior is in contrast to conventional coarsening processes during phase separation. The volume fraction limit of the separated liquid phases as well as the adhesion strength and thermodynamic stability of the capillary bridges are discussed. Capillary bridge formations in various compact colloid assemblies are considered. The study sheds light on a promising route to in-situ (in-liquid) firming of fragile colloidal crystals and other compact colloidal microstructures via capillary bridges

Effect of surface modification on single-walled carbon nanotube retention and transport in saturated and unsaturated porous media

This work investigated the effect of different surface modification methods, including oxidization, surfactant coating, and humic acid coating, on single-walled carbon nanotube (SWNT) stability and their mobility in granular porous media under various conditions. Characterization and stability studies demonstrated that the three surface modification methods were all effective in solubilizing and stabilizing the SWNTs in aqueous solutions. Packed sand column experiments showed that although the three surface medication methods showed different effect on the retention and transport of SWNTs in the columns, all the modified SWNTs were highly mobile. Compared with the other two surface modification methods, the humic acid coating method introduced the highest mobility to the SWNTs. While reductions in moisture content in the porous media could promote the retention of the surface modified SWNTs in some sand columns, results from bubble column experiment suggested that only oxidized SWNTs were retention in unsaturated porous media through attachment on air–water interfaces. Other mechanisms such as grain surface attachment and thin-water film straining could also be responsible for the retention of the SWNTs in unsaturated porous media. An advection–dispersion model was successfully applied to simulate the experimental data of surface modified SWNT retention and transport in porous media

Holographic RG flow of thermo-electric transports with momentum dissipation

We construct the holographic renormalization group (RG) flow of thermo-electric conductivities when the translational symmetry is broken. The RG flow is probed by the intrinsic observers hovering on the sliding radial membranes. We obtain the RG flow by solving a matrix-form Riccati equation. The RG flow provides a high-efficient numerical method to calculate the thermo-electric conductivities of strongly coupled systems with momentum dissipation. As an illustration, we recover the AC thermo-electric conductivities in the Einstein-Maxwell-axion model. Moreover, in several homogeneous and isotropic holographic models which dissipate the momentum and have the finite density, it is found that the RG flow of a particular combination of DC thermo-electric conductivities does not run. As a result, the DC thermal conductivity on the boundary field theory can be derived analytically, without using the conserved thermal current.Comment: 27 pages, 6 figures, typo corrected, a ref adde