Role of Fe substitution on the anomalous magnetocaloric and magnetoresistance behavior in Tb(Ni1-xFex)2 compounds

We report the magnetic, magnetocaloric and magnetoresistance results obtained in Tb(Ni1-xFex)2 compounds with x=0, 0.025 and 0.05. Fe substitution leads to an increase in the ordering temperature from 36 K for x=0 to 124 K for x=0.05. Contrary to a single sharp MCE peak seen in TbNi2, the MCE peaks of the Fe substituted compounds are quite broad. We attribute the anomalous MCE behavior to the randomization of the Tb moments brought about by the Fe substitution. Magnetic and magnetoresistance results seem to corroborate this proposition. The present study also shows that the anomalous magnetocaloric and magnetoresistance behavior seen in the present compounds is similar to that of Ho(Ni,Fe)2 compounds

Equilibrium susceptibilities of superparamagnets: longitudinal & transverse, quantum & classical

The equilibrium susceptibility of uniaxial paramagnets is studied in a unified framework which permits to connect traditional results of the theory of quantum paramagnets, \Sm=1/2, 1, 3/2, ..., with molecular magnetic clusters, \Sm\sim5, 10, 20, all the way up, \Sm=30, 50, 100,... to the theory of classical superparamagnets. This is done using standard tools of quantum statistical mechanics and linear response theory (the Kubo correlator formalism). Several features of the temperature dependence of the susceptibility curves (crossovers, peaks, deviations from Curie law) are studied and their scalings with \Sm identified and characterized. Both the longitudinal and transverse susceptibilities are discussed, as well as the response of the ensemble with anisotropy axes oriented at random. For the latter case a simple approximate formula is derived too, and its range of validity assessed, so it could be used in modelization of experiments.Comment: 32 pages, 5 figures. Submitted to J.Phys.Condens.Matte

Magnetism, FeS colloids, and Origins of Life

A number of features of living systems: reversible interactions and weak bonds underlying motor-dynamics; gel-sol transitions; cellular connected fractal organization; asymmetry in interactions and organization; quantum coherent phenomena; to name some, can have a natural accounting via $physical$ interactions, which we therefore seek to incorporate by expanding the horizons of `chemistry-only' approaches to the origins of life. It is suggested that the magnetic 'face' of the minerals from the inorganic world, recognized to have played a pivotal role in initiating Life, may throw light on some of these issues. A magnetic environment in the form of rocks in the Hadean Ocean could have enabled the accretion and therefore an ordered confinement of super-paramagnetic colloids within a structured phase. A moderate H-field can help magnetic nano-particles to not only overcome thermal fluctuations but also harness them. Such controlled dynamics brings in the possibility of accessing quantum effects, which together with frustrations in magnetic ordering and hysteresis (a natural mechanism for a primitive memory) could throw light on the birth of biological information which, as Abel argues, requires a combination of order and complexity. This scenario gains strength from observations of scale-free framboidal forms of the greigite mineral, with a magnetic basis of assembly. And greigite's metabolic potential plays a key role in the mound scenario of Russell and coworkers-an expansion of which is suggested for including magnetism.Comment: 42 pages, 5 figures, to be published in A.R. Memorial volume, Ed Krishnaswami Alladi, Springer 201

Streets and pedestrian trajectories in an urban district: Bejan's constructal principle revisited

Bejan's (1996) analytical optimum for the average travel time between an arbitrary point in a rectangle and its "gravitating" vertex along a trajectory, consisting of a low-resistance side of the rectangle (street) and a high-resistance internal segment perpendicular to this side, is generalized in the following way: (a) our street length is shorter than the rectangle side; (b) our "internal" segment of the trajectory is tilted with respect to the street at an angle which is either constant (a middle zone of the district) or varies in two other zones where trajectories directly converge to either the vertex or the tip of the street, wherefrom a pedestrian embarks a bus transporting him to the vertex; (c) our double integrals in the criterion and the first-second derivative tests are more cumbersome for evaluation and require computer algebra for calculation. The total energy spent by a moving entity is assumed to be linearly dependent on the length of the walkway or street trajectory segments with two different resistance coefficients. This energy is minimized for an individual particle such that the tilt angle is determined and zonation is done. Then another minimum of the area-averaged " community" energy is searched with the total rectangle area as a constraint and the side ratio of the rectangle as a control variable. Explicit analytical expressions for double integrals and minima are presented. Alternative criteria, involving the travel time, non-constant specific bus fare and area-averaged tilt angle are discussed. © 2014 Elsevier B.V. All rights reserved

East versus West: Contrasts in phenological patterns?

Aim To examine whether change in the timing of a large number of phenological events and their response to temperature differs between trophic levels during the period 1988-2008.Location In the vicinity of Kazan, Tatarstan Republic, Russia (55°45' N, 49°08' E).Methods Observations of the dates of first events of 22 plant phases, 8 insect phases, 3 herpetofauna phases and 26 migrant bird phases were examined using regression to assess changes over time and response to temperature. Differences between trophic levels were assessed using ANOVA.Results In comparison to studies from western Europe, relatively few phenological series (15) revealed a significant advance over time, but a much larger number (37), including all the herpetofauna and nearly all the plants, showed a response to temperature. Trends in birds were, on average, twice as great as those for plants, but plants had a significantly greater temperature response. Over the study period local temperatures had not risen significantly but some phenological change was still evident.Main conclusions Phenological change has been less marked in the eastern edge of Europe than in western and central Europe. This is compatible with a lack of significant local warming during the study period. A large number of species show strong responses to temperature so will be expected to advance if/when local temperatures do increase. In contrast to results from elsewhere in Europe, early events were not the most temperature responsive, suggesting local adaptation preventing precocious behaviour and the consequent dangers of sub-zero temperatures. © 2010 Blackwell Publishing Ltd

The social aspects of the tree-ring analysis

The work presents a study of wooden beams from the Assumption Cathedral in the Island Town of Sviyazhsk. A total of five floating chronologies of different lengths were obtained as a result of tree-ring analysis. Cross-dating demonstrated that the trees were cut in a single time period in the 1560s.peer-reviewe

Prospects for industrial methane production in the mine n.a. V.M.Bazhanov using vertical surface wells

The estimated methane resources in the coal stratum of Donbass are 798.5 billion m3, including 119.5 billion m3 in the Donetsk-Makeevsky area. Such significant potential implies that methane can be used not only for industrial production and energy purposes but also as a commodity for the chemical industry. However, in practice, commercial production of methane from coal seams, as is done in the fields of the USA, Canada, India, and China, is not carried out, and methane, obtained as a by-product, is utilized for ensuring the safety of the main technological processes for coal mining. The main reasons for this are the difficult mining and geological conditions of bedding, low thickness and permeability, which does not allow to separate methane production into an independent type of activity due to its low profitability, especially with the use of new technologies based on hydraulic fracturing of coal seams. The assessment of the possibility of industrial methane production in the mine n.a. V.M.Bazhanov in the Donetsk-Makeevsky area of Donbass, which reserves equal to 23.7 billion m3, showed that a significant part of the methane reserves is concentrated in coal seams and interlayers with a gas content of 18.5-20.7 m3/m3. Moreover, in the host rocks, methane is practically in a liberated state. This circumstance makes possible the commercial production of methane for its utilization from the unloaded rock mass by wells drilled from the surface, without the use of hydraulic fracturing technology. The paper discusses the technology of methane extraction by a degassing well drilled from the surface into a coal-bearing stratum unloaded from rock pressure in a mining field of the 4th eastern face of the m3 seam of the mine n.a. V.M.Bazhanov and its subsequent use as the fuel of an electric generator. It is shown that over the entire period of operation of the pilot well, the volume of actually produced methane exceeded the design value by 23 %, and the cost of the gas produced amounted to 1535 rubles per 1000 m3, which is more than 3 times lower than the market price for natural gas for consumers in the Russian Federation. This made it possible to make a conclusion about the possibility of industrial extraction of mine methane using vertical surface wells for its subsequent utilization in power plants, which does not imply the usage of hydraulic fracturing technology

Ant mound as an optimal shape in constructal design: Solar irradiation and circadian brood/fungi-warming sorties

Sizes, shapes, ambient and in-dome temperature, incoming solar radiation and illumination are measured on a Formica rufa anthill in a mixed forest of the Volga-Kama National Reserve in Russia. These data are used in a conceptual model of insolation of a right conical surface by direct-beam, descending atmospheric and ascending ground-reflected radiation. Unlike a standard calculation of the energy flux intercepted by a solar panel, the anthill is a 3-D structure and double-integration of the cosine of the angle between the solar beams and normal to the surface is carried out for a "cozy trapezium", where the insects expose themselves and the brood to "morning" sunbathing pulses ( Jones and Oldroyd, 2007). Several constructal design problems are formulated with the criteria involving either a pure solar energy gained by the dome or this energy, as a mathematical criterion, penalized by additive terms of mechanical energy (potential and friction) lost by the ants in their diurnal forays from a "heartland" of the nest to the sun-basking zone on the surface. The unique and global optima are analytically found, with the optimal tilt angle of the cone explicitly expressed through the zenith angle of the Sun and meteorological constants for the isotropic sky model. © 2014 Elsevier Ltd

Measurement of pressure effects on the magnetic and the magnetocaloric properties of the intermetallic compounds R(Co1-xSix)2 [R=Dy and Er]

The effect of external pressure on the magnetic properties and magnetocaloric effect of R(Co1-xSix)2 [R= Er, Dy and x=0, 0.025 and 0.05] compounds has been studied. The ordering temperatures of both the parent as well as the Si substituted compounds are found to decrease with pressure. In all the compounds, the critical field for metamagnetic transition increases with pressure. It is seen that the magnetocaloric effect in the parent compounds is almost insensitive to pressure, while there is considerable enhancement in the case of Si substituted compounds. Spin fluctuations arising due to the magnetovolume effect play a crucial role in determining the pressure dependence of magnetocaloric effect in these compounds. Analysis of the magnetization data using the Landau theory has shown that the magnitude of the Landau coefficient (C3) decreases with Si concentration whereas it is found to increase with pressure. The isothermal magnetic entropy change is found to behave in the same manner as C3, both with Si concentration (at ambient pressure) as well as with the applied pressure.Comment: 15 pages, 5 figure