38 research outputs found
The Crystalline Sponge Method: A Systematic Study of the Reproducibility of Simple Aromatic Molecule Encapsulation and Guest–Host Interactions
No full textA systematic study detailing the uptake of a series of chemically related simple functionalized aromatic guest molecules into the pores of the crystalline sponge [{(ZnI2)3(tris(4-pyridyl)-1,3,5-triazine)2·x(solvent)}n] has been performed. The reproducible positioning of the guest molecules within the unit cell has been documented. Analysis of guest–host and guest–guest interactions has shown the dominant role of π···π and CH···π interactions in the ability of the crystalline sponge to render the guest molecules regularly ordered. Further interactions specific to guest functionality, such as weak hydrogen bonds, are seen to contribute to the particular orientation of the guests
A miracle, of miracles As fearefull as euer was seene or heard of in the memorie of man. Which lately happened at Dichet in Sommersetshire, and sent by diuers credible witnesses to be published in London. Also a prophesie reuealed by a poore countrey maide, who being dead the first of October last, 1613. 24. houres, reuiued againe, and lay fiue dayes weeping, and continued prophesying of strange euents to come, and so died the 5. day following. Witnessed by M. Nicholas Faber, parson of the towne, and diuers worthy gentlemen of the same countrey. 1613, withall, Lincolnshire teares. For a great deluge, in which fiue villages were lamentably drovvned this present month.
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