Nonlinear current-voltage characteristics due to quantum tunneling of phase slips in superconducting Nb nanowire networks

We report on the transport properties of an array of N about 30 interconnected Nb nanowires, grown by sputtering on robust porous Si substrates. The analyzed system exhibits a broad resistive transition in zero magnetic field, H, and highly nonlinear V(I) characteristics as a function of H which can be both consistently described by quantum tunneling of phase slips.Comment: accepted for publication on Appl. Phys. Let

Superconducting properties of Nb thin films deposited on porous silicon templates

Porous silicon, obtained by electrochemical etching, has been used as a substrate for the growth of nanoperforated Nb thin films. The films, deposited by UHV magnetron sputtering on the porous Si substrates, inherited their structure made of holes of 5 or 10 nm diameter and of 10 to 40 nm spacing, which provide an artificial pinning structure. The superconducting properties were investigated by transport measurements performed in the presence of magnetic field for different film thickness and substrates with different interpore spacing. Perpendicular upper critical fields measurements present peculiar features such as a change in the H_c2(T) curvature and oscillations in the field dependence of the superconducting resistive transition width at H=1 Tesla. This field value is much higher than typical matching fields in perforated superconductors, as a consequence of the small interpore distance.Comment: accepted for publication on Journal of Applied Physic

Optimizing MOF properties for seasonal heat storage: a machine learning approach

In the quest to enhance thermochemical energy storage using promising sorbents, this work presents a study on the optimization of Metal Organic Frameworks (MOFs) properties for gas sorption, with a focus on CO2 and H2O adsorption. Through the analysis of crystallographic descriptors, the study aims to streamline the selection of MOFs that could potentially exceed the performance of existing water sorbent pairs. A comprehensive comparison of sequential learning (SL) algorithms reveals a method for identifying the minimal set of descriptors that influence adsorption properties of MOFs. The protocol involves constructing and training machine learning (ML) models to determine the number of influential descriptors and utilizing SHAP analysis to evaluate their importance. Findings suggest that including only these critical descriptors in the exploration space reduces computational load. Notably, the COMBO and the FUELS algorithms consistently outshine random guessing, validating their efficacy in materials optimization. The challenge of accessing full adsorption properties across the entire coverage range is addressed by a computational screening procedure requiring minimal input data. This method suggests that some vanadium based MOFs, originally designed for different purposes, could surpass the current leading compounds for thermal energy storage, primarily due to their optimal Henry coefficient values for water adsorption

Ground water and surface water under stress

Presented at Ground water and surface water under stress: competition, interaction, solutions: a USCID water management conference on October 25-28, 2006 in Boise, Idaho.Includes bibliographical references.The METRIC evapotranspiration (ET) estimation model was applied using MODIS (Moderate Resolution Imaging Spectroradiometer) satellite images in New Mexico to evaluate the applicability of MODIS images to ET estimation and water resources management. With the coarse resolution of MODIS (approximately 1km thermal resolution), MODIS was not found to be suitable for field-scale applications. In project and regional scale applications, MODIS has potential to contribute to ET estimation and water resources management. MODIS based ET maps for New Mexico were compared with Landsat based results for 12 dates. Average ET calculations using MODIS and Landsat applications were similar, indicating that MODIS images can be useful as an ET estimation tool in project and regional scale applications

Influence of Landsat Revisit Frequency on Time-Integration of Evapotranspiration for Agricultural Water Management

The objective of this study was to explore the improvement in accuracy of estimates for evapotranspiration (ET) over complete growing seasons and monthly periods, when more frequent Landsat imagery is made available. Conversely, we explored the reduction in accuracy in ET estimates when frequency of Landsat imagery was reduced. The study was implemented by conducting a series of METRIC applications for two Landsat WRS path overlap areas, one in southern Idaho (paths 39 and 40) during 2000, and a second one in Nebraska (paths 29 and 30) during 2002, years when two fully functioning satellites, Landsat 5 and Landsat 7, were in orbit. The results indicated that high frequency imagery provided by two satellites covering a WRS path overlap was more able to capture the impacts of rapid crop development and harvest, and evaporation associated by wetting events. That data set simulated a nominal four-day revisit time. Three-simulated 16-day revisit data sets created using a single Landsat series for a single path were unable to produce monthly and growing season ET due to the lack of sufficient number of images to even begin the time-integration process. This emphasizes the need to maintain two Landsat satellites in orbit and the high value of four-day revisit times. Limiting the data set to one path and two satellites (eight-day revisit) underestimated growing season ET accordingly by about 8% on average. Error in monthly ET was relatively high when image availability was limited to that for an eight-day revisit. This is due to the importance of timing of images to identify key inflection points in the ETrF curves and to capture special events such as wetting events from irrigation and rain or from water stress or cuttings, as in the case of forage crops. Results suggest that a four-day revisit time as represented by the full-run (run 1) of our analysis provides robustness in the development of time-integrated ET estimates over months and growing seasons, and is a valuable backstop for mitigation of clouded images over extended periods

Electro-Thermal Parameters of Graphene Nano-Platelets Films for De-Icing Applications

This paper provides a study of some relevant electro-thermal properties of commercial films made by pressed graphene nano-platelets (GNPs), in view of their use as heating elements in innovative de-icing systems for aerospace applications. The equivalent electrical resistivity and thermal emissivity were studied, by means of models and experimental characterization. Macroscopic strips with a length on the order of tens of centimeters were analyzed, either made by pure GNPs or by composite mixtures of GNPs and a small percentage of polymeric binders. Analytical models are derived and experimentally validated. The thermal response of these graphene films when acting as a heating element is studied and discussed

Communication Impairments in Mice Lacking Shank1: Reduced Levels of Ultrasonic Vocalizations and Scent Marking Behavior

Autism is a neurodevelopmental disorder with a strong genetic component. Core symptoms are abnormal reciprocal social interactions, qualitative impairments in communication, and repetitive and stereotyped patterns of behavior with restricted interests. Candidate genes for autism include the SHANK gene family, as mutations in SHANK2 and SHANK3 have been detected in several autistic individuals. SHANK genes code for a family of scaffolding proteins located in the postsynaptic density of excitatory synapses. To test the hypothesis that a mutation in SHANK1 contributes to the symptoms of autism, we evaluated Shank1−/− null mutant mice for behavioral phenotypes with relevance to autism, focusing on social communication. Ultrasonic vocalizations and the deposition of scent marks appear to be two major modes of mouse communication. Our findings revealed evidence for low levels of ultrasonic vocalizations and scent marks in Shank1−/− mice as compared to wildtype Shank1+/+ littermate controls. Shank1−/− pups emitted fewer vocalizations than Shank1+/+ pups when isolated from mother and littermates. In adulthood, genotype affected scent marking behavior in the presence of female urinary pheromones. Adult Shank1−/− males deposited fewer scent marks in proximity to female urine than Shank1+/+ males. Call emission in response to female urinary pheromones also differed between genotypes. Shank1+/+ mice changed their calling pattern dependent on previous female interactions, while Shank1−/− mice were unaffected, indicating a failure of Shank1−/− males to learn from a social experience. The reduced levels of ultrasonic vocalizations and scent marking behavior in Shank1−/− mice are consistent with a phenotype relevant to social communication deficits in autism.National Institute of Mental Health (U.S.) (Intramural Research Program)Simons Foundatio

Operational Remote Sensing of ET and Challenges

Satellite imagery now provides a dependable basis for computational models that determine evapotranspiration (ET) by surface energy balance (EB). These models are now routinely applied as part of water and water resources management operations of state and federal agencies. They are also an integral component of research programs in land and climat

Sensitivity of evapotranspiration retrievals from the METRIC processing algorithm to improved radiometric resolution of Landsat 8 thermal data and to calibration bias in Landsat 7 and 8 surface temperature

We made an assessment on the use of 12-bit resolution of Landsat 8 (L8) on evapotranspiration (ET) retrievals via the METRIC process as compared to using 8-bit resolution imagery of previous Landsat missions. METRIC (Mapping Evapotranspiration at high Resolution using Internalized Calibration) is an ET retrieval system commonly used in water and water rights management where the surface energy balance process is coupled with an extreme- end point calibration process to remove most impacts of systematic bias in remotely sensed inputs. We degraded L8 thermal images by grouping sequential digital numbers to reduce the apparent numerical resolution and then recomputed ET using METRIC and compared to nondegraded ET products. The use of 8-bit thermal data did not substantially impair the accuracy of ET retrievals derived from METRIC, as compared to the use of 12-bit thermal data. The largest error introduced into ET was \u3c1%. We also compared ET retrieved from images processed during the L8 and Landsat 7 (L7) March 2013 underfly to assess differences in ET caused by differences in signal to noise ratio (SNR) and scaling of the two systems. We evaluated the impact of bias in land surface temperature (LST) retrievals on ET determination using the CIMEC calibration approach (Calibration using Inverse Modeling using Extreme Member Calibration) employed in METRIC by introducing globally systematic biases into LST retrievals from L7 and L8 and comparing to ET from non-biased retrievals. The impacts of the introduction of both additive and multiplicative biases into surface temperature on ET were small for the three regions of the US studied, and for both L7 and L8 satellite systems. An independent study showed that METRIC-produced ET compared to within 3% of measured ET for the California site. The study assessed the impact of the February 2014 recalibration of L8 thermal data that caused a 3 K downward shift in LST estimation and changed reflectance values by about 0.7%. We found that the use of the recalibrated LST and shortwave data sets in METRIC did not change the accuracy of ET retrievals due to the automatic compensation for systematic biases employed by METRIC

Dogs and humans respond to emotionally competent stimuli by producing different facial actions

The commonality of facial expressions of emotion has been studied in different species since Darwin, with most of the research focusing on closely related primate species. However, it is unclear to what extent there exists common facial expression in species more phylogenetically distant, but sharing a need for common interspecific emotional understanding. Here we used the objective, anatomically-based tools, FACS and DogFACS (Facial Action Coding Systems), to quantify and compare human and domestic dog facial expressions in response to emotionally-competent stimuli associated with different categories of emotional arousal. We sought to answer two questions: Firstly, do dogs display specific discriminatory facial movements in response to different categories of emotional stimuli? Secondly, do dogs display similar facial movements to humans when reacting in emotionally comparable contexts? We found that dogs displayed distinctive facial actions depending on the category of stimuli. However, dogs produced different facial movements to humans in comparable states of emotional arousal. These results refute the commonality of emotional expression across mammals, since dogs do not display human-like facial expressions. Given the unique interspecific relationship between dogs and humans, two highly social but evolutionarily distant species sharing a common environment, these findings give new insight into the origin of emotion expression