42,691 research outputs found

    An Ontological Basis for Design Methods

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    This paper presents a view of design methods as process artefacts that can be represented using the function-behaviour-structure (FBS) ontology. This view allows identifying five fundamental approaches to methods: black-box, procedural, artefact-centric, formal and managerial approaches. They all describe method structure but emphasise different aspects of it. Capturing these differences addresses common terminological confusions relating to methods. The paper provides an overview of the use of the fundamental method approaches for different purposes in designing. In addition, the FBS ontology is used for developing a notion of prescriptiveness of design methods as an aggregate construct defined along four dimensions: certainty, granularity, flexibility and authority. The work presented in this paper provides an ontological basis for describing, understanding and managing design methods throughout their life cycle. Keywords: Design Methods; Function-Behaviour-Structure (FBS) Ontology; Prescriptive Design Knowledge</p

    Stochastic thermodynamics of single enzymes and molecular motors

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    For a single enzyme or molecular motor operating in an aqueous solution of non-equilibrated solute concentrations, a thermodynamic description is developed on the level of an individual trajectory of transitions between states. The concept of internal energy, intrinsic entropy and free energy for states follows from a microscopic description using one assumption on time-scale separation. A first law energy balance then allows the unique identification of the heat dissipated in one transition. Consistency with the second law on the ensemble level enforces both stochastic entropy as third contribution to the entropy change involved in one transition and the local detailed balance condition for the ratio between forward and backward rates for any transition. These results follow without assuming weak coupling between the enzyme and the solutes, ideal solution behavior or mass action law kinetics. The present approach highlights both the crucial role of the intrinsic entropy of each state and the physically questionable role of chemiostats for deriving the first law for molecular motors subject to an external force under realistic conditions.Comment: 11 page

    Multi-terminal Thermoelectric Transport in a Magnetic Field: Bounds on Onsager Coefficients and Efficiency

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    Thermoelectric transport involving an arbitrary number of terminals is discussed in the presence of a magnetic field breaking time-reversal symmetry within the linear response regime using the Landauer-B\"uttiker formalism. We derive a universal bound on the Onsager coefficients that depends only on the number of terminals. This bound implies bounds on the efficiency and on efficiency at maximum power for heat engines and refrigerators. For isothermal engines pumping particles and for absorption refrigerators these bounds become independent even of the number of terminals. On a technical level, these results follow from an original algebraic analysis of the asymmetry index of doubly substochastic matrices and their Schur complements.Comment: 31 pages, 9 figures, New J. Phys., in pres

    Centering in-the-large: Computing referential discourse segments

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    We specify an algorithm that builds up a hierarchy of referential discourse segments from local centering data. The spatial extension and nesting of these discourse segments constrain the reachability of potential antecedents of an anaphoric expression beyond the local level of adjacent center pairs. Thus, the centering model is scaled up to the level of the global referential structure of discourse. An empirical evaluation of the algorithm is supplied.Comment: LaTeX, 8 page

    Fair Wages and Human Capital Accumulation in a Global Economy

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    This paper analyzes trade in an asymmetric 2×2×2 world, where the two countries, labelled America and Europe, differ in their attitudes towards wage inequality. In both America and Europe, fair wage considerations compress differentials between the wages for skilled and unskilled workers, leading to involuntary unemployment of unskilled workers in equilibrium. European workers are more averse to wage inequality than American workers though, and as a consequence Europe is characterised by lower wage differentials as well as higher unemployment. Allowing for endogenous skill formation in both countries, the effects of a globalization shock – modelled as the entry of newly industrializing countries into the trading world – on prices and employment levels are derived.globalization, globalisation, unemployment, fair wages, skill upgrading
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