Magnetoresistance Effects in SrFeO(3-x): Dependence on Phase Composition and Relation to Magnetic and Charge Order

Single crystals of iron(IV) rich oxides SrFeO(3-x) with controlled oxygen content have been studied by Moessbauer spectroscopy, magnetometry, magnetotransport measurements, Raman spectroscopy, and infrared ellipsometry in order to relate the large magnetoresistance (MR) effects in this system to phase composition, magnetic and charge order. It is shown that three different types of MR effects occur. In cubic SrFeO3 (x = 0) a large negative MR of 25% at 9 T is associated with a hitherto unknown 60 K magnetic transition and a subsequent drop in resistivity. The 60 K transition appears in addition to the onset of helical ordering at ~130 K. In crystals with vacancy-ordered tetragonal SrFeO(3-x) as majority phase (x ~0.15) a coincident charge/antiferromagnetic ordering transition near 70 K gives rise to a negative giant MR effect of 90% at 9 T. A positive MR effect is observed in tetragonal and orthorhombic materials with increased oxygen deficiency (x = 0.19, 0.23) which are insulating at low temperatures. Phase mixtures can result in a complex superposition of these different MR phenomena. The MR effects in SrFeO(3-x) differ from those in manganites as no ferromagnetic states are involved

Lombalgie chronique, COTOREP et reclassement professionnel en Moselle

Objectifs : Décrire les caractéristiques, la prise en charge, les résultats et le coût d\u27un reclassement professionnel concernant les assurés mosellans lombalgiques chroniques bénéficiant d’un accord de la Commission technique d\u27orientation et de reclassement professionnel (COTOREP). Méthodes : Etude descriptive menée entre août 2000 et mars 2001 dans le cadre d\u27un partenariat avec la COTOREP de Moselle intégrant 48 lombalgiques chroniques pour lesquels la COTOREP a donné en 1995 un accord de pré-orientation ou de reclassement professionnels. Résultats : Le lombalgique pris en charge était un homme jeune, de faible niveau scolaire et professionnel, en rupture avec le milieu du travail et souffrant d\u27une pathologie lombaire invalidante. Sur 32 formations suivies, 24 candidats ont réussi leur examen mais seuls dix diplômés ont trouvé un emploi. Huit diplômés ont trouvé un emploi conforme à la formation apprise. Le taux de reprise du travail était semblable pour les diplômés (10/24) et pour les autres lombalgiques (11/24). Le coût global pour l\u27assurance maladie variait de 25 000 en externat à 39 000 en internat. Conclusion : Devant la faible valeur ajoutée du reclassement professionnel que nous avons constatée, il paraît souhaitable de maintenir le lombalgique chronique dans son emploi en restaurant son rachis, en aménageant son poste de travail et, surtout, en gérant ses peurs et croyances liées au couple lombalgietravail

Fringe proteins modulate Notch-ligand cis and trans interactions to specify signaling states

The Notch signaling pathway consists of multiple types of receptors and ligands, whose interactions can be tuned by Fringe glycosyltransferases. A major challenge is to determine how these components control the specificity and directionality of Notch signaling in developmental contexts. Here, we analyzed same-cell (cis) Notch-ligand interactions for Notch1, Dll1, and Jag1, and their dependence on Fringe protein expression in mammalian cells. We found that Dll1 and Jag1 can cis-inhibit Notch1, and Fringe proteins modulate these interactions in a way that parallels their effects on trans interactions. Fringe similarly modulated Notch-ligand cis interactions during Drosophila development. Based on these and previously identified interactions, we show how the design of the Notch signaling pathway leads to a restricted repertoire of signaling states that promote heterotypic signaling between distinct cell types, providing insight into the design principles of the Notch signaling system, and the specific developmental process of Drosophila dorsal-ventral boundary formation

Universal Static and Dynamic Properties of the Structural Transition in Pb(Zn1/3Nb2/3)O3

The relaxors Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PZN) and Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) have very similar properties based on the dielectric response around the critical temperature $T_{c}$ (defined by the structural transition under the application of an electric field). It has been widely believed that these materials are quite different below $T_{c}$ with the unit cell of PMN remaining cubic while in PZN the low temperature unit cell is rhombohedral in shape. However, this has been clarified by recent high-energy x-ray studies which have shown that PZN is rhombohedral only in the skin while the shape of the unit cell in the bulk is nearly cubic. In this study we have performed both neutron elastic and inelastic scattering to show that the temperature dependence of both the diffuse and phonon scattering in PZN and PMN is very similar. Both compounds show a nearly identical recovery of the soft optic mode and a broadening of the acoustic mode below $T_{c}$. The diffuse scattering in PZN is suggestive of an onset at the high temperature Burns temperature similar to that in PMN. In contrast to PMN, we observe a broadening of the Bragg peaks in both the longitudinal and transverse directions below $T_{c}$. We reconcile this additional broadening, not observed in PMN, in terms of structural inhomogeneity in PZN. Based on the strong similarities between PMN and PZN, we suggest that both materials belong to the same universality class and discuss the relaxor transition in terms of the three-dimensional Heisenberg model with cubic anisotropy in a random field.Comment: 11 pages, 10 figures. Updated version after helpful referee comment

Ground State of Relaxor Ferroelectric Pb(Zn1/3Nb2/3)O3Pb(Zn_{1/3}Nb_{2/3})O_3

High energy x-ray diffraction measurements on Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN) single crystals show that the system does not have a rhombohedral symmetry at room temperature as previously believed. The new phase (X) in the bulk of the crystal gives Bragg peaks similar to that of a nearly cubic lattice with a slight tetragonal distortion. The Bragg profile remains sharp with no evidence of size broadening due to the polar micro crystals (MC). However, in our preliminary studies of the skin, we have found the expected rhombohedral (R) phase as a surface state. On the other hand, studies on an electric-field poled PZN single crystal clearly indicate a rhombohedral phase at room temperature.Comment: 11 pages with 3 figure

Double excitation transitions in Mn2+ -doped alkali halides

4 págs.; 4 figs.It is shown in this work that the room-temperature excitation spectra of as-grown crystals of LiF, NaF, NaCl, KCl, and KBr doped with Mn2+ reveal the existence of double excitation peaks. These peaks are related to the formation of precipitated phases containing Mn2+ in the alkali halide lattice. In the case of LiF:Mn2+ the position of the [A14(G), E4(G)] and T14(G) peaks suggests an anomalously small Mn2+- F- distance for the precipitated phase. © 1983 The American Physical Society.Financial support by the Comision Asesora para la Investigacion Cientifica y Tecnica, is gratefully acknowledged.Peer Reviewe

Broadband Dielectric Spectroscopy on Glass-Forming Propylene Carbonate

Dielectric spectroscopy covering more than 18 decades of frequency has been performed on propylene carbonate in its liquid and supercooled-liquid state. Using quasi-optic submillimeter and far-infrared spectroscopy the dielectric response was investigated up to frequencies well into the microscopic regime. We discuss the alpha-process whose characteristic timescale is observed over 14 decades of frequency and the excess wing showing up at frequencies some three decades above the peak frequency. Special attention is given to the high-frequency response of the dielectric loss in the crossover regime between alpha-peak and boson-peak. Similar to our previous results in other glass forming materials we find evidence for additional processes in the crossover regime. However, significant differences concerning the spectral form at high frequencies are found. We compare our results to the susceptibilities obtained from light scattering and to the predictions of various models of the glass transition.Comment: 13 pages, 9 figures, submitted to Phys. Rev.

Competing orders in PZN-xPT and PMN-xPT relaxor ferroelectrics

Neutron and x-ray scattering studies on relaxor ferroelectric systems Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN), Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ (PMN), and their solid solutions with PbTiO$_3$ (PT) have shown that inhomogeneities and disorder play important roles in the materials properties. Although a long-range polar order can be established at low temperature - sometimes with the help of an external electric field; short-range local structures called the ``polar nano-regions'' (PNR) still persist. Both the bulk structure and the PNR have been studied in details. The coexistence and competition of long- and short-range polar orders and how they affect the structural and dynamical properties of relaxor materials are discussed.Comment: Article submitted for JPSJ Special Topics (Novel States of Matter Induced by Frustration

Why did Swiss citizens vote to ban tobacco advertising?

In February 2022, Swiss citizens agreed to modify the Swiss Constitution to ban tobacco advertising reaching children and adolescents. This case study analyses the arguments used by both opponents and supporters of the constitutional amendment. Opponents argued that the proposed regulation went too far, threatened the economy, restricted personal freedom, was superfluous as the current law already protected youth and that it opened the door to marketing bans of other harmful products. Proponents focused on youth protection and invoked the burden of smoking on public health and the fact that advertising bans are an effective evidence-based measure. A comparison with previous campaigns to ban tobacco advertising that had failed suggests factors accounting for the positive vote in 2022. These include the strategic framing of youth protection, the separation of tobacco from other issues (such as alcohol advertising), the deteriorating image of the tobacco industry and the ability of the proponents to mobilise a broad coalition of health and youth organisations, with improved funding and communication. The lessons may be instructive for other campaigns seeking to regulate commercial determinants of health