Thermodynamics of gas–liquid colloidal equilibrium states: hetero-phase fluctuations

Following on from two previous JETC (Joint European Thermodynamics Conference) presentations, we present a preliminary report of further advances towards the thermodynamic description of critical behavior and a supercritical gas-liquid coexistence with a supercritical fluid mesophase defined by percolation loci. The experimental data along supercritical constant temperature isotherms (T >= T-c) are consistent with the existence of a two-state mesophase, with constant change in pressure with density, rigidity, (dp/d rho) (T), and linear thermodynamic state-functions of density. The supercritical mesophase is bounded by 3rd-order phase transitions at percolation thresholds. Here we present the evidence that these percolation transitions of both gaseous and liquid states along any isotherm are preceded by pre-percolation hetero-phase fluctuations that can explain the thermodynamic properties in the mesophase and its vicinity. Hetero-phase fluctuations give rise to one-component colloidal-dispersion states; a single Gibbs phase retaining 2 degrees of freedom in which both gas and liquid states with different densities percolate the phase volume. In order to describe the thermodynamic properties of two-state critical and supercritical coexistence, we introduce the concept of a hypothetical homo-phase of both gas and liquid, defined as extrapolated equilibrium states in the pre-percolation vicinity, with the hetero-phase fractions subtracted. We observe that there can be no difference in chemical potential between homo-phase liquid and gaseous states along the critical isotherm in mid-critical isochoric experiments when the meniscus disappears at T = T-c. For T > T-c, thermodynamic states comprise equal mole fractions of the homo-phase gas and liquid, both percolating the total phase volume, at the same temperature, pressure, and with a uniform chemical potential, stabilised by a positive finite interfacial surface tension.info:eu-repo/semantics/publishedVersio

Match Effects

We present an empirical model of earnings that controls for observable and unobservable characteristics of workers (person effects), unmeasured characteristics of their employers (firm effects), and unmeasured characteristics of worker-firm matches (match effects). We interpret these as the returns to general human capital, firm-specific human capital, and match-specific human capital, respectively. We stress the importance of match effects because the returns to match-specific human capital will be incorrectly attributed to general and/or firm-specific human capital when match effects are omitted, and because general and specific human capital have very different implications for the economic cost of job destruction. We find that slightly more than half of observed variation in log earnings is attributable to general human capital, 22 percent is attributable to firm-specific human capital, and 16 percent to match-specific human capital. Specifications that omit match effects over-estimate the returns to experience by as much as 50 percent, over-estimate the returns to a college education by as much as 8 percent, attribute too much variation to person effects, and too little to firm effects. Our results suggest that considerable earnings variation previously attributed to general human capital -- both observed and unobserved -- is in fact attributable to workers sorting into higher-paying firms and better worker-firm matches.human capital; fixed effects; mixed effects; person and firm effects; linked employer-employee data

Mars transfer vehicle studies

Earth-to-Mars distances vary from 60 to 400 million kilometers over a 14-year cycle. This complicates Mars mission design as a function of calendar time. Stay times at Mars are also strongly driven by opportunities for a return flight path which are within the limits of delta-V associated with practical space vehicles. The biggest difference between Mars and lunar transfer missions is mission time, which grows from a few days for the moon, to as much as a few hundred days for Mars missions. As a result, modules for similarly sized crews must be much larger for Mars missions that for transfer to lunar orbit. Technology challenges for one Mars mission scenario analyzed by Boeing include aerobrakes, propulsion, and life support systems. Mission performance is very sensitive to aerobrake weight fraction and, as a result, there is an incentive to use high performance materials such as advanced composites and thermal protection systems. Lander aerobrake would be used twice (for both planetary capture and descent to the Mars surface), and it would need to survive temperatures up to 3500 degrees

Wage Differentials in the Presence of Unobserved Worker, Firm, and Match Heterogeneity

We consider the problem of estimating and decomposing wage differentials in the presence of unobserved worker, firm, and match heterogeneity. Controlling for these unobservables corrects omitted variable bias in previous studies. It also allows us to measure the contribution of unmeasured characteristics of workers, firms, and worker-firm matches to observed wage differentials. An application to linked employer-employee data shows that decompositions of inter-industry earnings differentials and the male-female differential are misleading when unobserved heterogeneity is ignored.wage differentials; unobserved heterogeneity; employer-employee data

Non-linear Group Actions with Polynomial Invariant Rings and a Structure Theorem for Modular Galois Extensions

Let $G$ be a finite $p$-group and $k$ a field of characteristic $p>0$. We show that $G$ has a \emph{non-linear} faithful action on a polynomial ring $U$ of dimension $n=\mathrm{log}_p(|G|)$ such that the invariant ring $U^G$ is also polynomial. This contrasts with the case of \emph{linear and graded} group actions with polynomial rings of invariants, where the classical theorem of Chevalley-Shephard-Todd and Serre requires $G$ to be generated by pseudo-reflections. Our result is part of a general theory of "trace surjective $G$-algebras", which, in the case of $p$-groups, coincide with the Galois ring-extensions in the sense of \cite{chr}. We consider the \emph{dehomogenized symmetric algebra} $D_k$, a polynomial ring with non-linear $G$-action, containing $U$ as a retract and we show that $D_k^G$ is a polynomial ring. Thus $U$ turns out to be \emph{universal} in the sense that every trace surjective $G$-algebra can be constructed from $U$ by "forming quotients and extending invariants". As a consequence we obtain a general structure theorem for Galois-extensions with given $p$-group as Galois group and any prescribed commutative $k$-algebra $R$ as invariant ring. This is a generalization of the Artin-Schreier-Witt theory of modular Galois field extensions of degree $p^s$.Comment: 20 page

Earth-to-orbit transportation for solar power satellites

The cargo transport capability and the cost of space transportation operations for transportation of solar power satellites (SPS) to space are addressed. The history of SPS launch vehicle evolution is shown. Alternative vehicle designs developed include: (1) a parallel burn, crossfeed configuration; (2) single stage to orbit airbreathing/rocket runway takeoff vehicle concept; and (3) a smaller HLLV concept. The smaller HLLV was analyzed to compare the nonrecurring cost benefits of a less challenging development with the recurring cost increases expected due to losses in efficiency associated with smaller vehicle size. The vehicle payload bay size was selected to be adequate to accommodate the SPS transmitter subarrays fully assembled. The resulting vehicle design is compared with the shuttle, the Saturn V, and the reference SPS HLLV. A nonrecurring savings of at least five billion dollars was obtained with a recurring cost penalty of 3% per SPS. The environmental benefits of the small vehicle were deemed more important than the slight increase in upper atmosphere propellant deposition. It is recommended that the small HLLV be adopted as the SPS reference launch system

Considering the Smartphone Learner: developing innovation to investigate the opportunities for students and their interest

Ownership of mobile smartphones amongst the general consumer, professionals and students is growing exponentially. The potential for smartphones in education builds upon experience described in the extensive literature on mobile learning from the previous decade which suggests that the ubiquity, multi-functionality and connectivity of mobile devices offers a new and potentially powerful networked learning environment. This paper reports on a collaborative study conducted by an undergraduate student with the support of two members of academic staff. The research sought to establish the extent to which students are autonomously harnessing smartphone technology to support their learning and the nature of this use. Initial findings were explored through student interviews. The study found that students who own smartphones are largely unaware of their potential to support learning and, in general, do not install smartphone applications for that purpose. They are, however, interested in and open to the potential as they become familiar with the possibilities for a range of purposes. The paper proposes that more consideration needs to be given to smartphones as platforms to support formal, informal and autonomous learner engagement. The study also reflects on its collaborative methodology and the challenges associated with academic innovation

High voltage systems (tube-type microwave)/low voltage system (solid-state microwave) power distribution

SPS satellite power distribution systems are described. The reference Satellite Power System (SPS) concept utilizes high-voltage klystrons to convert the onboard satellite power from dc to RF for transmission to the ground receiving station. The solar array generates this required high voltage and the power is delivered to the klystrons through a power distribution subsystem. An array switching of solar cell submodules is used to maintain bus voltage regulation. Individual klystron dc voltage conversion is performed by centralized converters. The on-board data processing system performs the necessary switching of submodules to maintain voltage regulation. Electrical power output from the solar panels is fed via switch gears into feeder buses and then into main distribution buses to the antenna. Power also is distributed to batteries so that critical functions can be provided through solar eclipses