Electrical spin injection, transport, and detection in graphene-hexagonal boron nitride van der Waals heterostructures: progress and perspectives

The current research in graphene spintronics strives for achieving a long spin lifetime, and efficient spin injection and detection in graphene. In this article, we review how hexagonal boron nitride (hBN) has evolved as a crucial substrate, as an encapsulation layer, and as a tunnel barrier for manipulation and control of spin lifetimes and spin injection/detection polarizations in graphene spin valve devices. First, we give an overview of the challenges due to conventional SiO$_2$ substrate for spin transport in graphene followed by the progress made in hBN based graphene heterostructures. Then we discuss in detail the shortcomings and developments in using conventional oxide tunnel barriers for spin injection into graphene followed by introducing the recent advancements in using the crystalline single/bi/tri-layer hBN tunnel barriers for an improved spin injection and detection which also can facilitate two-terminal spin valve and Hanle measurements, at room temperature, and are of technological importance. A special case of bias induced spin polarization of contacts with exfoliated and chemical vapour deposition (CVD) grown hBN tunnel barriers is also discussed. Further, we give our perspectives on utilizing graphene-hBN heterostructures for future developments in graphene spintronics.Comment: Review, Author submitted manuscript - draft; 25 pages, 8 figure

Changes and factors in mental health functioning of adolescents in therapy : a thesis presented in partial fulfilment of the requirements for the degree of Master of Arts in Psychology at Massey University (Palmerston North), New Zealand

Appendix D is not availableTo explore factors that might contribute to changes in mental health functioning in adolescents with mental health problems seen at a Child, Adolescent, and Family Mental Health Service (CAFMHS), the present study examined changes in scores on the Clinical Outcomes of Routine Evaluation (CORE) and the Health of the Nation Outcome Scales for Children and Adolescents (HoNOSCA) over a 3 month period. Ten female and 5 male adolescents completed the CORE and 7 of their respective therapists assessed their mental health on HoNOSCA, before and after 3 months of intervention. Life events and factors within therapy during the period of the study were assessed through interviews with clients and their respective therapists. Analysis of the data indicated that overall the mental health of the participants did improve. No significant correlations between clients' and clinicians' assessment of therapeutic factors were found. The hypotheses that focused on factors that might have contributed to the changes were not supported, possibly due to the small number of participants. Limitations of the study and future directions were discussed

Separating spin and charge transport in single wall carbon nanotubes

We demonstrate spin injection and detection in single wall carbon nanotubes using a 4-terminal, non-local geometry. This measurement geometry completely separates the charge and spin circuits. Hence all spurious magnetoresistance effects are eliminated and the measured signal is due to spin accumulation only. Combining our results with a theoretical model, we deduce a spin polarization at the contacts of approximately 25 %. We show that the magnetoresistance changes measured in the conventional two-terminal geometry are dominated by effects not related to spin accumulation.Comment: Number of pages: 11 Number of figures:

Graphene-WS2_2 heterostructures for tunable spin injection and spin transport

We report the first measurements of spin injection in to graphene through a 20 nm thick tungsten disulphide (WS$_2$) layer, along with a modified spin relaxation time ({\tau}s) in graphene in the WS$_2$ environment, via spin-valve and Hanle spin-precession measurements, respectively. First, during the spin-injection into graphene through a WS$_2$-graphene interface, we can tune the interface resistance at different current bias and modify the spin injection efficiency, in a correlation with the conductivity-mismatch theory. Temperature assisted tunneling is identified as a dominant mechanism for the charge transport across the interface. Second, we measure the spin transport in graphene, underneath the WS$_2$ crystal and observe a significant reduction in the {\tau}s down to 17 ps in graphene in the WS$_2$ covered region, compared to that in its pristine state. The reduced {\tau}s indicates the WS$_2$-proximity induced additional dephasing of the spins in graphene.Comment: 7 Pages, 6 figure