Dark cloud chemistry in initially H-rich regions

The chemistry in dark regions of dense cores is explored as a function of the initial abundance ratio of H to H 2, on the assumption that some cores form on a timescale and are younger than the time required for the H :H 2 ratio to attain its equilibrium value. Observational diagnostics of non-equilibrium values of the initial H :H 2 ratio are identified. In initially H-rich material, the abundances of OH, NH 3, CN, and HNC are for some time higher than they are in initially H-poor material. In initially H-poor regions, the abundances of CO, species containing multiple carbon atoms in each molecule, and CS are larger for an (observationally significant) period than in initially H-rich material

First evidence for molecular interfaces between outflows and ambient clouds in high-mass star-forming regions?

We present new observations of the Cep A East region of massive star formation and describe an extended and dynamically distinct feature not previously recognized. This feature is present in emission from H2CS, OCS, CH3OH, and HDO at −5.5 km s−1 but is not traced by the conventional tracers of star-forming regions, H2S, SO2, SO, and CS. The feature is extended up to at least 0.1 pc. We show that the feature is neither a hot core nor a shocked outflow. However, the chemistry of the feature is consistent with predictions from a model of an eroding interface between a fast wind and a dense core; mixing between the two media occurs in the interface on a timescale of 10–50 yr. If these observations are confirmed by detailed maps and by detections in species also predicted to be abundant (e.g., HCO+, H2CO, and NH3), this feature would be the first detection of such an interface in regions of massive star formation. An important implication of the model is that a significant reservoir of sulfur in grain mantles is required to be in the form of OCS

Biotransformation of explosives by the old yellow enzyme family of flavoproteins

Several independent studies of bacterial degradation of nitrate ester explosives have demonstrated the involvement of flavin-dependent oxidoreductases related to the old yellow enzyme (OYE) of yeast. Some of these enzymes also transform the nitroaromatic explosive 2,4,6-trinitrotoluene (TNT). In this work, catalytic capabilities of five members of the OYE family were compared, with a view to correlating structure and function. The activity profiles of the five enzymes differed substantially; no one compound proved to be a good substrate for all five enzymes. TNT is reduced, albeit slowly, by all five enzymes. The nature of the transformation products differed, with three of the five enzymes yielding products indicative of reduction of the aromatic ring. Our findings suggest two distinct pathways of TNT transformation, with the initial reduction of TNT being the key point of difference between the enzymes. Characterization of an active site mutant of one of the enzymes suggests a structural basis for this difference

The molecular condensations ahead of Herbig-Haro objects. II: a theoretical investigation of the HH 2 condensation

Clumps of enhanced molecular emission are present close to a number of Herbig-Haro (HH) objects. These enhancements may be the consequence of an active photochemistry driven by the UV radiation originating from the shock front of the HH object. On the basis of this picture and as a follow up to a molecular line survey toward the quiescent molecular clump ahead of the HH object, HH 2 (Girart et al. 2002), we present a detailed time and depth dependent chemical model of the observed clump. Despite several difficulties in matching the observations, we constrain some of the physical and chemical parameters of the clump ahead of HH 2. In particular, we find that the clump is best described by more than one density component with a peak density of 3 × 105 cm-3 and a visual extinction of ≤3.5 mag; its lifetime can not be much higher than 100 years and the impinging radiation is enhanced with respect to the ambient one by probably no more than 3 orders of magnitude. Our models also indicate that carbon-bearing species should not completely hydrogenate as methane when freezing out on grains during the formation of the clump

Entanglement Dynamics in 1D Quantum Cellular Automata

Several proposed schemes for the physical realization of a quantum computer consist of qubits arranged in a cellular array. In the quantum circuit model of quantum computation, an often complex series of two-qubit gate operations is required between arbitrarily distant pairs of lattice qubits. An alternative model of quantum computation based on quantum cellular automata (QCA) requires only homogeneous local interactions that can be implemented in parallel. This would be a huge simplification in an actual experiment. We find some minimal physical requirements for the construction of unitary QCA in a 1 dimensional Ising spin chain and demonstrate optimal pulse sequences for information transport and entanglement distribution. We also introduce the theory of non-unitary QCA and show by example that non-unitary rules can generate environment assisted entanglement.Comment: 12 pages, 8 figures, submitted to Physical Review

Macroeconomic, international trade and sectoral policies in livestock development. An analysis with particular reference to low income countries

Following a general introduction Section 1 review regional trends in production, consumption and trade and highlights some related policy issues. Section 2 then considers in conceptual terms the importance of macroeconomic, trade and other economic policies to provide a basis for the remainder of the paper. Section 3 examines agricultural and livestock development in major developing regions in relation to macroeconomic and trade policies whereas Section 4 looks at livestock sector policies. Recent West African experiences in livestock production and trade against a background of changes in international and regional economic policies are the focus of Section 5. The concluding Section 6 focuses on appropriate economic policies for livestock development in low income countries

The genetic structure of Nautilus pompilius populations surrounding Australia and the Philippines.

Understanding the distribution of genetic diversity in exploited species is fundamental to successful conservation. Genetic structure and the degree of gene flow among populations must be assessed to design appropriate strategies to prevent the loss of distinct populations. The cephalopod Nautilus pompilius is fished unsustainably in the Philippines for the ornamental shell trade and has limited legislative protection, despite the species' recent dramatic decline in the region. Here, we use 14 microsatellite markers to evaluate the population structure of N. pompilius around Australia and the Philippines. Despite their relative geographical proximity, Great Barrier Reef individuals are genetically isolated from Osprey Reef and Shark Reef in the Coral Sea (FST =0.312, 0.229, respectively). Conversely, despite the larger geographical distances between the Philippines and west Australian reefs, samples display a small degree of genetic structure (FST =0.015). Demographic scenarios modelled using approximate Bayesian computation analysis indicate that this limited divergence is not due to contemporary gene flow between the Philippines and west Australia. Instead, present-day genetic similarity can be explained by very limited genetic drift that has occurred due to large average effective population sizes that persisted at both locations following their separation. The lack of connectivity among populations suggests that immigrants from west Australia would not facilitate natural recolonization if Philippine populations were fished to extinction. These data help to rectify the paucity of information on the species' biology currently inhibiting their conservation classification. Understanding population structure can allow us to facilitate sustainable harvesting, thereby preserving the diversity of genetically distinct stocks. This article is protected by copyright. All rights reserved

Lonely adatoms in space

There is a close relation between the problems of second layer nucleation in epitaxial crystal growth and chemical surface reactions, such as hydrogen recombination, on interstellar dust grains. In both cases standard rate equation analysis has been found to fail because the process takes place in a confined geometry. Using scaling arguments developed in the context of second layer nucleation, I present a simple derivation of the hydrogen recombination rate for small and large grains. I clarify the reasons for the failure of rate equations for small grains, and point out a logarithmic correction to the reaction rate when the reaction is limited by the desorption of hydrogen atoms (the second order reaction regime)

Bessel processes, the Brownian snake and super-Brownian motion

We prove that, both for the Brownian snake and for super-Brownian motion in dimension one, the historical path corresponding to the minimal spatial position is a Bessel process of dimension -5. We also discuss a spine decomposition for the Brownian snake conditioned on the minimizing path.Comment: Submitted to the special volume of S\'eminaire de Probabilit\'es in memory of Marc Yo

Proposed Global Stratotype Sections and Points for the bases of the Selandian and Thanetian stages (Paleocene Series)

Prepared for the International Subcommission on Paleogene Stratigraph